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Ethyl propiolate

Ethyl propiolate Structure
CAS No.
623-47-2
Chemical Name:
Ethyl propiolate
Synonyms
Ethyl prop-2-ynoate;EPL;Ethyl propargylate;Ethyl propynoate;Ethyl 2-propynoate;PropioL;HC≡CCO2C2H5;Ethyl propinate;ETHYL PROPIOLATE;EthylPropiolate>
CBNumber:
CB8116565
Molecular Formula:
C5H6O2
Molecular Weight:
98.1
MOL File:
623-47-2.mol
MSDS File:
SDS
Modify Date:
2024/4/8 13:48:25

Ethyl propiolate Properties

Melting point 9°C
Boiling point 120 °C (lit.)
Density 0.968 g/mL at 25 °C (lit.)
refractive index n20/D 1.412(lit.)
Flash point 74 °F
storage temp. 2-8°C
solubility Miscible with alcohol.
form Liquid
color Clear colorless to pale yellow
Specific Gravity 0.968
Water Solubility miscible
Merck 14,3846
BRN 878250
Dielectric constant 7.0
CAS DataBase Reference 623-47-2(CAS DataBase Reference)
NIST Chemistry Reference Ethyl propiolate(623-47-2)

SAFETY

Risk and Safety Statements

Symbol(GHS) 
GHS02,GHS07
Signal word  Warning
Hazard statements  H226-H315-H319-H335
Precautionary statements  P210-P302+P352-P305+P351+P338
Hazard Codes  Xi,F
Risk Statements  10-36/37/38-36-11
Safety Statements  26-36-37/39-16-33-29-24-23
RIDADR  UN 3272 3/PG 3
WGK Germany  3
Hazard Note  Irritant
HazardClass  3
PackingGroup  II
HS Code  29161980
NFPA 704
3
2 0

Ethyl propiolate price More Price(5)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich(India) E46607 Ethyl propiolate 99% 623-47-2 5G ₹3637.2 2022-06-14 Buy
Sigma-Aldrich(India) E46607 Ethyl propiolate 99% 623-47-2 25G ₹10430 2022-06-14 Buy
Sigma-Aldrich(India) E46607 Ethyl propiolate 99% 623-47-2 100G ₹26730 2022-06-14 Buy
TCI Chemicals (India) P0529 Ethyl Propiolate min. 98.0 % 623-47-2 5ML ₹2700 2022-05-26 Buy
TCI Chemicals (India) P0529 Ethyl Propiolate min. 98.0 % 623-47-2 25ML ₹8500 2022-05-26 Buy
Product number Packaging Price Buy
E46607 5G ₹3637.2 Buy
E46607 25G ₹10430 Buy
E46607 100G ₹26730 Buy
P0529 5ML ₹2700 Buy
P0529 25ML ₹8500 Buy

Ethyl propiolate Chemical Properties,Uses,Production

Chemical Properties

Ethyl propiolate is a clear colorless to pale yellow liquid that is soluble in ethanol, ether and chloroform. It an important organic chemical raw material and pharmaceutical intermediate. Ethyl propargylate is obtained by oxidation of propargyl alcohol to propargylic acid followed by esterification.

Uses

Halogenated derivatives were used as substrates for direct, asymmetric alkynylation of cyclic ?-ketoesters using chiral phase-transfer catalysts. Also employed in a one-pot , four-component synthesis of benzene-1,2,3,5-tetracarboxylates promoted by Ph3P.

Definition

ChEBI: Ethyl propiolate is the ethyl ester of prop-2-ynoic acid. It is a ynoate ester, a terminal acetylenic compound and an ethyl ester.

Hazard

Flammable; lachrymator.

Global( 403)Suppliers
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