ChemicalBook > Product Catalog >Flavors and fragrances >Synthetic fragrances >Carboxylic acids and esters >Aromatic carboxylic acid ester >Ethyl phenylacetate
Ethyl phenylacetate
- CAS No.
- 101-97-3
- Chemical Name:
- Ethyl phenylacetate
- Synonyms
- ethyl 2-phenylacetate;BENZENEACETIC ACID ETHYL ESTER;Ethyl benzeneacetate;PHENYLACETIC ACID ETHYL ESTER;Ethyl phenacetate;ethylbenzeneacetate;Natural Ethyl phenylacetate;FEMA 2452;ETHYL A-TOLUATE;Ethyl α-toluate
- CBNumber:
- CB6701512
- Molecular Formula:
- C10H12O2
- Molecular Weight:
- 164.2
- MOL File:
- 101-97-3.mol
- MSDS File:
- SDS
- Modify Date:
- 2024/9/13 19:17:58
| Melting point | -29 °C |
|---|---|
| Boiling point | 229 °C(lit.) |
| Density | 1.03 g/mL at 25 °C(lit.) |
| vapor pressure | 22.7Pa at 20℃ |
| refractive index |
n |
| FEMA | 2452 | ETHYL PHENYLACETATE |
| Flash point | 172 °F |
| storage temp. | Store below +30°C. |
| solubility | Chloroform (Slightly), Ethyl Acetate (Slightly) |
| color | Colourless |
| Odor | at 10.00 % in dipropylene glycol. sweet floral honey rose balsam cocoa |
| Odor Type | floral |
| Water Solubility | insoluble |
| Merck | 14,3840 |
| JECFA Number | 1009 |
| BRN | 509140 |
| Dielectric constant | 5.4（21℃） |
| InChIKey | DULCUDSUACXJJC-UHFFFAOYSA-N |
| LogP | 2.36 at 22℃ |
| CAS DataBase Reference | 101-97-3(CAS DataBase Reference) |
| NIST Chemistry Reference | Benzeneacetic acid, ethyl ester(101-97-3) |
| EPA Substance Registry System | Benzeneacetic acid, ethyl ester (101-97-3) |
SAFETY
Risk and Safety Statements
| Symbol(GHS) |  GHS07 |
|||||||||
|---|---|---|---|---|---|---|---|---|---|---|
| Signal word | Warning | |||||||||
| Hazard statements | H227-H303 | |||||||||
| Precautionary statements | P210e-P280a-P370+P378a-P403+P235-P501a | |||||||||
| Safety Statements | 23-24/25 | |||||||||
| WGK Germany | 2 | |||||||||
| RTECS | AJ2824000 | |||||||||
| TSCA | Yes | |||||||||
| HS Code | 29163500 | |||||||||
| Toxicity | The acute oral LD50 value in rats was reported as 3.30g/kg(2.52-4.08 g/kg) (Moreno,1973).The acute dermal LD50 in rabbits was reported as > 5g/kg(Moreno, 1973). | |||||||||
| NFPA 704 |
|
Ethyl phenylacetate price More Price(14)
| Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
|---|---|---|---|---|---|---|---|
| Sigma-Aldrich(India) | W245230 | Ethyl phenylacetate natural, 98%, FG | 101-97-3 | 1SAMPLE-K | ₹5196 | 2022-06-14 | Buy |
| Sigma-Aldrich(India) | W245230 | Ethyl phenylacetate natural, 98%, FG | 101-97-3 | 100G | ₹21217 | 2022-06-14 | Buy |
| Sigma-Aldrich(India) | W245230 | Ethyl phenylacetate natural, 98%, FG | 101-97-3 | 500G | ₹92802.73 | 2022-06-14 | Buy |
| Sigma-Aldrich(India) | W245208 | Ethyl phenylacetate ≥98%, FCC, FG | 101-97-3 | 1SAMPLE-K | ₹5141.88 | 2022-06-14 | Buy |
| Sigma-Aldrich(India) | W245208 | Ethyl phenylacetate ≥98%, FCC, FG | 101-97-3 | 1KG | ₹9233.73 | 2022-06-14 | Buy |
Ethyl phenylacetate Chemical Properties,Uses,Production
Chemical Properties
Ethyl Phenylacetate is a volatile aroma component of fruit and honey. It is a clear colourless to pale yellowish liquid with a pleasant, strong, sweet odor reminiscent of honey and a bittersweet flavor. Small amounts are used in flower perfumes and in fruit flavors.
Occurrence
Reported found in grapefruit juice, apple juice, figs, guava, pineapple, papaya, cognac, cider, grape wines and port wine.
Uses
Ethyl phenylacetate was used to study the solvent-based self-healing of epoxy materials. It is also used as a flavoring agent, flavor animal feeds, In perfumery.
Definition
ChEBI: Ethyl phenylacetate is a member of benzenes. It is a less toxic, greener solvent. It is non-mutagenic.
Preparation
Ethyl phenylacetate is prepared by heating at the boil phenylacetonitrile and sulfuric acid in alcohol solution; by esterification of the acid catalyzed by HCl or H2SO4.
General Description
Ethyl phenylacetate is a less toxic, greener solvent. It is non-mutagenic.
Safety Profile
Moderately toxic by ingestion. Combustible liquid. Mutation data reported. When heated to decomposition it emits acrid smoke and irritating fumes. See also ESTERS.
Purification Methods
Shake the ester with saturated aqueous Na2CO3 (three times), aqueous 50% CaCl2 (twice) and saturated aqueous NaCl (twice). Dry with CaCl2 and distil it under reduced pressure. [Beilstein 9 H 434, 9 IV 1618.]
Ethyl phenylacetate Preparation Products And Raw materials
Raw materials
Preparation Products
1-Phenyl-1-cyclopropanecarboxylic acid
ETHYL ALPHA-CHLOROPHENYLACETATE
Ethyl alpha-Formyl Benzeneacetic Acid Ester
ETHYL A-ETHOXYOXALYLPHENYL ACETATE
Diethyl 2-ethyl-2-phenylmalonate
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101-97-3
CH3C6H4COOC2H5
C6H5CH2COOC2H5
C6H5CH2CO2CH2CH3
Organic Building Blocks
Esters
ESTER
Building Blocks
Carbonyl Compounds
C10 to C11
C10 to C11