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ISOPROPENYLOXYTRIMETHYLSILANE

ISOPROPENYLOXYTRIMETHYLSILANE Structure
CAS No.
1833-53-0
Chemical Name:
ISOPROPENYLOXYTRIMETHYLSILANE
Synonyms
DK177;IPOTMS;(CH3)3SiOC(CH3)=CH2;2-(TRIMETHYLSILOXY)PROPENE;ISOPROPENOXYTRIMETHYLSILANE;2-(TRIMETHYLSILYLOXY)PROPENE;Trimethyl Isopropenoxysilane;Trimethyl lsopropenoxysilane;TRIMETHYLISOPROPENYLOXYSILANE;ISOPROPENYLOXYTRIMETHYLSILANE
CBNumber:
CB5326015
Molecular Formula:
C6H14OSi
Molecular Weight:
130.26
MOL File:
1833-53-0.mol
Modify Date:
2023/6/8 17:06:37

ISOPROPENYLOXYTRIMETHYLSILANE Properties

Melting point 40-45 °C
Boiling point 93-95 °C
Density 0.78 g/mL at 25 °C(lit.)
refractive index n20/D 1.395(lit.)
Flash point 45 °F
storage temp. -20°C
form clear liquid
color Colorless to Light orange to Yellow
Specific Gravity 0.786
Hydrolytic Sensitivity 7: reacts slowly with moisture/water
BRN 1849023
CAS DataBase Reference 1833-53-0(CAS DataBase Reference)
NIST Chemistry Reference CH2=(CH3)OSi(CH3)3(1833-53-0)
EPA Substance Registry System Silane, trimethyl[(1-methylethenyl)oxy]- (1833-53-0)

SAFETY

Risk and Safety Statements

Symbol(GHS) 
GHS02,GHS07
Signal word  Danger
Hazard statements  H225-H315-H319-H335
Precautionary statements  P210-P233-P240-P241-P303+P361+P353-P305+P351+P338
Hazard Codes  F,Xi
Risk Statements  11-36/37/38
Safety Statements  16-26-36-37/39
RIDADR  UN 1993 3/PG 2
WGK Germany  3
10-21
TSCA  Yes
HazardClass  3.1
PackingGroup  II
HS Code  2931900090
NFPA 704
3
2 0

ISOPROPENYLOXYTRIMETHYLSILANE price More Price(2)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich(India) 376078 (Isopropenyloxy)trimethylsilane ≥85% 1833-53-0 1G ₹7150 2022-06-14 Buy
Sigma-Aldrich(India) 376078 (Isopropenyloxy)trimethylsilane ≥85% 1833-53-0 5G ₹19510 2022-06-14 Buy
Product number Packaging Price Buy
376078 1G ₹7150 Buy
376078 5G ₹19510 Buy

ISOPROPENYLOXYTRIMETHYLSILANE Chemical Properties,Uses,Production

Chemical Properties

clear colorless liquid

General Description

(Isopropenyloxy)trimethylsilane is an enol silyl ether. It participates as nucleophile in Lewis acid-promoted C3-nucleophile substitution of tetracyclic bromide. It is reported to participate in the total synthesis of (±)-powelline. It is reported to participate in dityltin bis(triflate) catalyzed Michael addition reaction of enol silyl ethers.

Purification Methods

Purify it by fractional distillation using a very efficient column at atmospheric pressure. It usually contains 5% of hexamethyldisiloxalane which boils at 99-101o, but is generally non-reactive and need not be removed. [Hauser & Hance J Am Chem Soc 71 5091 1952.] It has been distilled under N2 through a 15cm column packed with glass helices. Fraction b 99-104o is further purified by gas chromatography through a Carbowax column (Autoprep A 700) at a column temperature of 87o, and has a retention time of 9.5minutes. [Krüger & Rochow J Organomet Chem 1 476 1963-4.]

ISOPROPENYLOXYTRIMETHYLSILANE Preparation Products And Raw materials

Global( 111)Suppliers
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Aravali Pharma And Lifesciences +91-9350857917 +91-9810502945 New Delhi, India 119 58 Inquiry
A.J Chemicals 91-9810153283 New Delhi, India 6124 58 Inquiry
Shanghai Daken Advanced Materials Co.,Ltd +86-371-66670886 China 18642 58 Inquiry
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Hebei Guanlang Biotechnology Co., Ltd. +8619930503259 China 18423 58 Inquiry
TRIMETHYLISOPROPENYLOXYSILANE ACETONE ENOL TRIMETHYLSILYL ETHER 2-(TRIMETHYLSILYLOXY)PROPENE 2-(TRIMETHYLSILOXY)PROPENE IPOTMS ISOPROPENOXYTRIMETHYLSILANE (CH3)3SiOC(CH3)=CH2 Silane, trimethyl[(1-methylethenyl)oxy]- trimethyl[(1-methylethenyl)oxy]-silan trimethyl[(1-methylethenyl)oxy]-Silane ISOPROPENYLOXYTRIMETHYLSILANE 2-(Trimethylsiloxy)propene, Acetone enol trimethylsilyl ether, IPOTMS trimethyl[(1-methylvinyl)oxy]silane 2-(TRIMETHYLSILYLOXY)PROPENE, 85+% isopropenyloxytrimethylsilane[trimethylsilylatingagent]90+% Isopropenyloxytrimethylsilane(2-Trimethylsiloxypropene) Isopropenyloxytrimethylsilane [Trimethylsilylating Agent] Isopropenyl(trimethylsilyl) ether 2-(Trimethylsilyloxy)propene,90% Trimethyl Isopropenoxysilane Trimethyl(prop-1-en-2-yloxy)silane (Isopropenyloxy)triMethylsilane >=85% Isopropenyloxytrimethylsilane[TrimethylsilylatingAgent]> rimethyl(prop-1-en-2-yloxy)silane 2- (trimethylsiloxyl) propylene DK177 Trimethyl lsopropenoxysilane 1833-53-0 CH3CCH2OSiCH33 Silicon Compounds (for Synthesis) Si (Classes of Silicon Compounds) Monoalkoxysilanes Vinylsilanes, Allylsilanes Si-O Compounds Building Blocks Organic Building Blocks Enol Ethers Oxygen Compounds Building Blocks Chemical Synthesis Enol Ethers Organic Building Blocks Oxygen Compounds Monoalkoxysilanes Si (Classes of Silicon Compounds) Silicon Compounds (for Synthesis) Si-O Compounds Synthetic Organic Chemistry Vinylsilanes, Allylsilanes