ChemicalBook > Product Catalog >Chemical Reagents >Silane reagent >1-METHOXY-3-TRIMETHYLSILOXY-1,3-BUTADIENE
1-METHOXY-3-TRIMETHYLSILOXY-1,3-BUTADIENE
- CAS No.
- 54125-02-9
- Chemical Name:
- 1-METHOXY-3-TRIMETHYLSILOXY-1,3-BUTADIENE
- Synonyms
- DK814;DKSI071;DANISHEFSKY'S DIENE;Danishefsky-Kitahara diene.;1-METHOXY-3-(TRIMETHYLSILOXY)BUTADIENE;TRANS-1-METHOXY-3-TRIMETHYLSILOXY- &;1-METHOXY-3-TRIMETHYLSILOXY-1,3-BUTADIENE;1-METHOXY-3-TRIMETHYLSILYLOXY-1,3-BUTADIENE;1-Methoxy-3-trimethylsiloxy-1,3-butadiene ,95%;1-METHOXY-3-TRIMETHYLSILOXY-1,3-BUTADIENE, 98+%
- CBNumber:
- CB2162111
- Molecular Formula:
- C8H16O2Si
- Molecular Weight:
- 172.3
- MOL File:
- 54125-02-9.mol
- MSDS File:
- SDS
- Modify Date:
- 2025/7/16 9:53:45
| Boiling point | 68-69 °C/14 mmHg (lit.) |
|---|---|
| Density | 0.885 g/mL at 25 °C (lit.) |
| refractive index |
n |
| Flash point | 113 °F |
| storage temp. | 2-8°C |
| form | liquid |
| Specific Gravity | 0.89 |
| Appearance | Colorless to light yellow Liquid |
| Water Solubility | Miscible with most organic solvents. Immiscible with water. |
| Hydrolytic Sensitivity | 8: reacts rapidly with moisture, water, protic solvents |
| Sensitive | Moisture Sensitive |
| Merck | 14,6001 |
| BRN | 1616761 |
| CAS DataBase Reference | 54125-02-9(CAS DataBase Reference) |
1-METHOXY-3-TRIMETHYLSILOXY-1,3-BUTADIENE price More Price(6)
| Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
|---|---|---|---|---|---|---|---|
| Sigma-Aldrich(India) | 212830 | trans-1-Methoxy-3-trimethylsiloxy-1,3-butadiene 95% | 54125-02-9 | 1G | ₹3160.9 | 2022-06-14 | Buy |
| Sigma-Aldrich(India) | 212830 | trans-1-Methoxy-3-trimethylsiloxy-1,3-butadiene 95% | 54125-02-9 | 5G | ₹10738.4 | 2022-06-14 | Buy |
| ALFA India | ALF-L14672-06 | 1-Methoxy-3-trimethylsiloxy-1,3-butadiene, 96% | 54125-02-9 | 5g | ₹9804 | 2022-05-26 | Buy |
| ALFA India | ALF-L14672-03 | 1-Methoxy-3-trimethylsiloxy-1,3-butadiene, 96% | 54125-02-9 | 1g | ₹4027 | 2022-05-26 | Buy |
| ALFA India | ALF-L06100-06 | 1-Methoxy-3-trimethylsiloxy-1,3-butadiene, 94% | 54125-02-9 | 5g | ₹10933 | 2022-05-26 | Buy |
1-METHOXY-3-TRIMETHYLSILOXY-1,3-BUTADIENE Chemical Properties,Uses,Production
Uses
1-Methoxy-3-trimethylsiloxy-1,3-butadiene is employed as a reagent in Mannich-Michael reaction for the synthesis of piperidinones and enaminones. As Diels-Alder diene, it is used in the synthesis of pyridones and pyranones, sulfone analogues of griseofulvin (sulfogriseofulvins) and 4H-1-aminopyrroles and 4, 5H-pyrazoles.
General Description
trans-1-methoxy-3-trimethylsiloxy-1,3-butadiene is a funtionalized Diels-Alder diene. Mukaiyama-Michael-type addition/heterocyclization of trans-1-methoxy-3-trimethylsiloxy-1,3-butadiene (Danishefsky′s diene) with 1,2-diaza-1,3-butadiene has been investigated. Asymmetric hetero-Diels-Alder cyclization of Danishefsky′s diene with benzaldehyde catalyzed by mesoporous inorganic/metalorganic hybrid materials has been reported.
Purification Methods
It may contain up to 1% of the precursor 4-methoxybut-4-ene-2-one. It is easily purified by distilling through a Vigreux column (p 11) in a vacuum and taking the middle fraction. [Danishefsky & Kitihara J Am Chem Soc 96 7807 1974, Danishefsky Acc Chem Res 14 400 1981.]
1-METHOXY-3-TRIMETHYLSILOXY-1,3-BUTADIENE Preparation Products And Raw materials
Raw materials
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Global( 107)Suppliers
| Supplier | Tel | Country | ProdList | Advantage | Inquiry |
|---|---|---|---|---|---|
| Alfa Aesar | 1 800 209 7001 | Maharashtra, India | 6905 | 58 | Inquiry |
| ZHENGZHOU JIUYI TIME NEW MATERIALS CO,.LTD | +86-13017695106 +86-13676922317 | China | 7006 | 58 | Inquiry |
| Shanghai Daken Advanced Materials Co.,Ltd | +86-2158073036 | China | 12828 | 58 | Inquiry |
| ATK CHEMICAL COMPANY LIMITED | +undefined-21-51877795 | China | 33024 | 60 | Inquiry |
| Jinan Carbotang Biotech Co.,Ltd. | +8615866703830 | China | 8497 | 58 | Inquiry |
| CONIER CHEM AND PHARMA LIMITED | +8618523575427 | China | 49733 | 58 | Inquiry |
| Career Henan Chemica Co | +86-0371-86658258 +8613203830695 | China | 30230 | 58 | Inquiry |
| Hefei TNJ Chemical Industry Co.,Ltd. | +86-0551-65418671 +8618949823763 | China | 34563 | 58 | Inquiry |
| Dayang Chem (Hangzhou) Co.,Ltd. | +86-0571-88938639 +8617705817739 | China | 52846 | 58 | Inquiry |
| Alfa Chemistry | +1-5166625404; | United States | 20405 | 58 | Inquiry |
54125-02-9(1-METHOXY-3-TRIMETHYLSILOXY-1,3-BUTADIENE)Related Search:
Triethoxysilane
Octamethylcyclotetrasiloxane
Vinyltrimethoxysilane
4-Methoxy-2-(trimethylsiloxy)-1,3-butadiene,1-METHOXY-3-TRIMETHYLSILOXY-1,3-BUTADIENE,TRANS-1-METHOXY-3-TRIMETHYLSILOXY-1,3-BUTADIENE
ALLYLOXYTRIMETHYLSILANE
Ethoxytrimethylsilane
2-(Trimethylsiloxy)-1,3-butadiene
METHOXYTRIMETHYLSILANE
DIMETHYLETHOXYSILANE
VINYLOXYTRIMETHYLSILANE
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TRANS-1-METHOXY-3-TRIMETHYLSILOXY-1,3-BUTADIENE
TRANS-1-METHOXY-3-(TRIMETHYLSILYLOXY)-1,3-BUTADIENE
DANISHEFSKY'S DIENE
1-METHOXY-3-TRIMETHYLSILOXY-1,3-BUTADIENE
1-METHOXY-3-(TRIMETHYLSILOXY)BUTADIENE
1-METHOXY-3-TRIMETHYLSILYLOXY-1,3-BUTADIENE
TRANS-1-METHOXY-3-TRIMETHYLSILOXY- &
1-Methoxy-3-(trimethylsiloxy)butadiene(Danishefsky`sDiene)
Silane, (2E)-3-methoxy-1-methylene-2-propenyloxytrimethyl-
Danishefsky-Kitahara diene.
1-METHOXY-3-TRIMETHYLSILOXY-1,3-BUTADIENE, 98+%
1-Methoxy-3-trimethylsiloxy-1,3-butadiene ,95%
(1E)-3-(Trimethylsilyloxy)-1-methoxy-1,3-butadiene
(E)-1-Methoxy-3-(trimethylsiloxy)-1,3-butadiene
(E)-1-Methoxy-3-[(trimethylsilyl)oxy]-1,3-butadiene
[[(E)-3-Methoxy-1-methylene-2-propenyl]oxy]trimethylsilane
Methyl[(1E)-3-(trimethylsiloxy)-1,3-butadienyl] ether
(E)-(4-methoxybuta-1,3-dien-2-yloxy)trimethylsilane
[(E)-3-Methoxy-1-methylene-allyloxy]-trimethyl-silane
trans-1-Methoxy-3-trimethylsilyloxy-1,3-butadiene for synthesis
trans-1-Methoxy-3-trimethylsiloxy-1,3-butadiene,Danishefsky’s diene
Silane, [[(2E)-3-Methoxy-1-Methylene-2-propen-1-yl]oxy]triMethyl-
[(4-Methoxybuta-1,3-dien-2-yl)oxy]triMethylsilane
trans-1-Methoxy-3-triMethylsiloxy-1,3-butadiene 95%
(2E)-3-Methoxy-1-methylene-2-propen-1-yl]oxy]trimethylsilane
DK814
DKSI071
trans-1-Methoxy-3-trimethylsiloxy-1,3-butadiene
54125-02-9
C8H16O2Si1
CH33SiOCCH2CHCHOCH3
Building Blocks
Enol Ethers
Organic Building Blocks
Oxygen Compounds
Si-O Compounds
Silicon Compounds (for Synthesis)
Monoalkoxysilanes
Si (Classes of Silicon Compounds)
Vinylsilanes, Allylsilanes