Lithium bromide
![Lithium bromide Structure](CAS/GIF/7550-35-8.gif)
- CAS No.
- 7550-35-8
- Chemical Name:
- Lithium bromide
- Synonyms
- LiBr;LITHIUM HALIDE;lithium bromide solution;Lithium bromide anhydrous;Anhydrous lithiuM broMide;Lithium bromide anhydrous, free-flowing, Redi-Dri, ReagentPlus, >=99%;thiuM broMide;Lithiumbromid;ithium bromide;Lithium bromide
- CBNumber:
- CB4302867
- Molecular Formula:
- BrLi
- Molecular Weight:
- 86.85
- MOL File:
- 7550-35-8.mol
- MSDS File:
- SDS
- Modify Date:
- 2024/6/21 13:10:12
Melting point | 550 °C (lit.) |
---|---|
Boiling point | 1265 °C |
Density | 1.57 g/mL at 25 °C |
Flash point | 1265°C |
storage temp. | Inert atmosphere,Room Temperature |
solubility | Methanol (Very Slightly, Heated), Water (Slightly) |
pka | 2.64[at 20 ℃] |
form | powder |
color | White |
Specific Gravity | 3.464 |
Odor | odorless |
Water Solubility | 61 g/100 mL (25 º C) |
Sensitive | Hygroscopic |
Merck | 14,5526 |
Stability | Stable. Anhydrous form is extremely hygroscopic. |
LogP | -0.37 at 25℃ |
CAS DataBase Reference | 7550-35-8(CAS DataBase Reference) |
NIST Chemistry Reference | Lithium bromide(7550-35-8) |
EPA Substance Registry System | Lithium bromide (7550-35-8) |
SAFETY
Risk and Safety Statements
Symbol(GHS) | ![]() GHS07 |
|||||||||
---|---|---|---|---|---|---|---|---|---|---|
Signal word | Warning | |||||||||
Hazard statements | H315-H317-H319 | |||||||||
Precautionary statements | P261-P264-P272-P280-P302+P352-P305+P351+P338 | |||||||||
Hazard Codes | Xi | |||||||||
Risk Statements | 32-40-43-36/37 -36/37/38 -36/38 | |||||||||
Safety Statements | 22-26-60-24/25-36/37-36/37/39 | |||||||||
WGK Germany | 2 | |||||||||
RTECS | OJ5755000 | |||||||||
F | 3 | |||||||||
TSCA | Yes | |||||||||
HS Code | 28275900 | |||||||||
NFPA 704 |
|
Lithium bromide price More Price(35)
Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
---|---|---|---|---|---|---|---|
Sigma-Aldrich(India) | 746479 | Lithium bromide anhydrous, free-flowing, Redi-Dri?, ReagentPlus?, ≥99% | 7550-35-8 | 100G | ₹2966.05 | 2022-06-14 | Buy |
Sigma-Aldrich(India) | 746479 | Lithium bromide anhydrous, free-flowing, Redi-Dri?, ReagentPlus?, ≥99% | 7550-35-8 | 500G | ₹6191.9 | 2022-06-14 | Buy |
Sigma-Aldrich(India) | 746479 | Lithium bromide anhydrous, free-flowing, Redi-Dri?, ReagentPlus?, ≥99% | 7550-35-8 | 1KG | ₹10695.1 | 2022-06-14 | Buy |
Sigma-Aldrich(India) | 746479 | Lithium bromide anhydrous, free-flowing, Redi-Dri?, ReagentPlus?, ≥99% | 7550-35-8 | 6X500G | ₹25958.35 | 2022-06-14 | Buy |
Sigma-Aldrich(India) | 746479 | Lithium bromide anhydrous, free-flowing, Redi-Dri?, ReagentPlus?, ≥99% | 7550-35-8 | 2.5KG | ₹46850.6 | 2022-06-14 | Buy |
Lithium bromide Chemical Properties,Uses,Production
Chemical Properties
White cubic crystals; hygroscopic; refractive index 1.784; density 3.464 g/cm3; melts at 550°C; vaporizes at 1,265°C; highly soluble in water (145g/100g at 4°C), much greater solubility in hot water (254g/100g at 90°C); soluble in methanol, ethanol and ether; slightly soluble in pyridine; vapor pressure of aqueous solutions at 52 and 68% concentrations at 25°C are 5 and 0.7 torr, respectively.
Physical properties
White cubic crystals; hygroscopic; refractive index 1.784; density 3.464 g/cm3; melts at 550°C; vaporizes at 1,265°C; highly soluble in water (145g/100g at 4°C), much greater solubility in hot water (254g/100g at 90°C); soluble in methanol, ethanol and ether; slightly soluble in pyridine; vapor pressure of aqueous solutions at 52 and 68% concentrations at 25°C are 5 and 0.7 torr, respectively.
Uses
As humectant, in air-conditioning systems. An aqueous solution of lithium bromide containing about 50 % lithium bromide is used as an absorbent in large-scale absorption air conditioning equipment. Lithium bromide is also used in limited amounts by the pharmaceutical industry for dehydrobromination of organic compounds to form olefins.
Preparation
Lithium bromide may be prepared by the reaction of lithium hydroxide monohydrate or lithium carbonate with hydrobromic acid. The resultant solution of lithium bromide may be evaporated and cooled to crystallize a hydrate of lithium bromide, the composition of which depends on the final temperature. The lithium bromide hydrate may be filtered from the mixture and carefully dried by the application of heat in a vacuum desiccator to avoid melting the hydrate.
Definition
ChEBI: A lithium salt in which the counterion is bromide. The anhydrous salt forms cubic crystals similar to common salt.
General Description
LiBr/Chlorotrimethylsilane reagent participates in the conversion of alcohols to bromides.
Purification Methods
Crystallise it several times from water or EtOH, then dry it under high vacuum for 2 days at room temperature, followed by drying at 100o. Its solubility in H2O is 167% at ~20o, and 250% at ~100o. It is deliquescent and should be stored in a tightly stoppered vessel.
Lithium bromide Preparation Products And Raw materials
Raw materials
Preparation Products
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Supplier | Advantage |
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GLR Innovations | 58 |
SYNGREEN LIFESCIENCES PVT.LTD | 58 |
ULTIMA CHEMICALS | 58 |
SUJALAM CHEMICALS | 58 |
PACIFIC ORGANICS PVT LTD | 58 |
BEE CHEMS | 58 |
JSK Chemicals | 58 |
Neogen Chemicals Ltd | 58 |
Bhavika Chemicals Corporation | 58 |
Rivashaa Agrotech Biopharma Pvt. Ltd. | 58 |
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