LEAD(II) BROMIDE
- CAS No.
- 10031-22-8
- Chemical Name:
- LEAD(II) BROMIDE
- Synonyms
- PbBr2;LEAD BROMIDE;dibromolead;Bleidibromid;LEAD DIBROMIDE;LEAD(+2)BROMIDE;LEAD(II) BROMIDE;Plumbous bromide;leadbromide(pbbr2);Lead(II) dibromide
- CBNumber:
- CB1483912
- Molecular Formula:
- Br2Pb
- Molecular Weight:
- 367.01
- MOL File:
- 10031-22-8.mol
- MSDS File:
- SDS
- Modify Date:
- 2023/12/22 17:53:22
| Melting point | 371 °C(lit.) |
|---|---|
| Boiling point | 892 °C(lit.) |
| Density | 6.66 g/mL at 25 °C(lit.) |
| storage temp. | Keep in dark place,Inert atmosphere,Room temperature |
| solubility | ethanol: insoluble(lit.) |
| form | Powder |
| color | White to off-white |
| Specific Gravity | 6.66 |
| Water Solubility | Soluble in water at 20°C 5g/L. Insoluble in ethanol. Solubility in N,N-DMF is almost transparent. |
| Merck | 14,5403 |
| Solubility Product Constant (Ksp) | pKsp: 6.82 |
| Exposure limits |
ACGIH: TWA 0.05 mg/m3 NIOSH: IDLH 100 mg/m3; TWA 0.050 mg/m3 |
| Stability | Stable. |
| InChIKey | ZASWJUOMEGBQCQ-UHFFFAOYSA-L |
| CAS DataBase Reference | 10031-22-8(CAS DataBase Reference) |
| EPA Substance Registry System | Lead(II) bromide (10031-22-8) |
SAFETY
Risk and Safety Statements
| Symbol(GHS) |    GHS07,GHS08,GHS09 |
|||||||||
|---|---|---|---|---|---|---|---|---|---|---|
| Signal word | Danger | |||||||||
| Hazard statements | H302+H332-H360Df-H373-H410 | |||||||||
| Precautionary statements | P201-P273-P301+P312+P330-P304+P340+P312-P308+P313 | |||||||||
| Hazard Codes | T,N | |||||||||
| Risk Statements | 61-20/22-33-50/53-62 | |||||||||
| Safety Statements | 53-45-60-61 | |||||||||
| RIDADR | UN 2291 6.1/PG 3 | |||||||||
| WGK Germany | 3 | |||||||||
| TSCA | Yes | |||||||||
| HazardClass | 6.1 | |||||||||
| PackingGroup | III | |||||||||
| HS Code | 28275900 | |||||||||
| NFPA 704 |
|
LEAD(II) BROMIDE price More Price(16)
| Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
|---|---|---|---|---|---|---|---|
| Sigma-Aldrich(India) | 398853 | Lead(II) bromide 99.999% trace metals basis | 10031-22-8 | 5G | ₹4340.83 | 2022-06-14 | Buy |
| Sigma-Aldrich(India) | 211141 | Lead(II) bromide ≥98% | 10031-22-8 | 100G | ₹5639.83 | 2022-06-14 | Buy |
| Sigma-Aldrich(India) | 211141 | Lead(II) bromide ≥98% | 10031-22-8 | 500G | ₹21227.83 | 2022-06-14 | Buy |
| ALFA India | ALF-A19406-36 | Lead(II) bromide, 98+% | 10031-22-8 | 500g | ₹7365 | 2022-05-26 | Buy |
| TCI Chemicals (India) | L0346 | Lead(II) Bromide (Low water content) [for Perovskite precursor] | 10031-22-8 | 1G | ₹3000 | 2022-05-26 | Buy |
LEAD(II) BROMIDE Chemical Properties,Uses,Production
Chemical Properties
white, ortho-rhomb crystal(s); -80 mesh with 99.999% purity; enthalpy of vaporization 133 kJ/mol; enthalpy of fusion 16.44 kJ/mol; obtained from PbO or PbCO3 and HBr; finds use as a photopolymerization catalyst and in photoduplication processes in the 365 nm region [KIR78] [CER91] [CRC10] [MER06]
Physical properties
White orthorhombic crystals; density 6.66 g/cm3; melts at 373°C; forms a horn-like mass on solidification; vaporizes at 916°C; decomposes slowly on exposure to light; sparingly soluble in cold water (4.55 g/L at 0°C and 8.44 g/L at 20°C, respectively); moderately soluble in boiling water (44.1g/L at 100°C); Ksp 6.60x10-6 at 25°C; insoluble in alcohol; slightly soluble in ammonia; soluble in alkalies and also in sodium or potassium bromide solutions.
Uses
It is used in the field of antirust, pigment and photograph. The molten lead(II) bromide acts as an electrolyte. Lead(II) bromide provides a high concentration of lead(II) ions and bromide ions to carry the current during the electrolysis process. The rare-earth-doped alkali-lead bromide crystals (potassium lead bromide (or) KPB; rubidium lead bromide or RPB) emerge as promising new low-phonon-energy host materials for mid-IR applications and are useful for solid state lasers. Hybrid organic/lead halide perovskites are promising materials for solar cell fabrication.
Purification Methods
Crystallise it from water containing a few drops of HBr (25mL of water per gram PbBr2) between 100o and 0o. A neutral solution is evaporated at 110o, and the crystals that separate are collected by rapid filtration at 70o and dried at 105o (to give the monohydrate). Its solubility in H2O is 0.5% (at ~10o) and 5% (at ~ 100o). To prepare the anhydrous bromide, the hydrate is heated for several hours at 170o and then in a Pt boat at 200o in a stream of HBr and H2. Finally it is fused [Clayton et al. J Chem Soc, Faraday Trans 1 76 2362 1980].
LEAD(II) BROMIDE Preparation Products And Raw materials
Raw materials
Preparation Products
| Supplier | Tel | Country | ProdList | Advantage | Inquiry |
|---|---|---|---|---|---|
| GLR Innovations | +91 9891111994 | New Delhi, India | 4542 | 58 | Inquiry |
| Nithyasri Chemicals (APURVA CHEMICALS) | +91-2512692130 +91-9323652199 | Maharashtra, India | 75 | 58 | Inquiry |
| Axiom Chemicals Pvt Ltd (Axiom Corporation) | +91-7433900100 +91-9727703500 | Gujarat, India | 68 | 58 | Inquiry |
| Techno Pharmchem | 91-9818265860 | Delhi, India | 173 | 58 | Inquiry |
| Rupali Fine Chemicals | 08068970604Ext 265 | Mumbai, India | 6 | 58 | Inquiry |
| Brisben Chemicals | 08048963750 | Mumbai, India | 509 | 58 | Inquiry |
| Loba Chemie Pvt., Ltd. | 91-22-66636663 | Maharashtra, India | 766 | 58 | Inquiry |
| Samir Chemicals | 09820131245 | Mumbai, India | 39 | 58 | Inquiry |
| Innovative | 07942565925 | Mumbai, India | 617 | 58 | Inquiry |
| Molychem | 08048372666Ext 559 | Mumbai, India | 577 | 58 | Inquiry |
| Supplier | Advantage |
|---|---|
| GLR Innovations | 58 |
| Nithyasri Chemicals (APURVA CHEMICALS) | 58 |
| Axiom Chemicals Pvt Ltd (Axiom Corporation) | 58 |
| Techno Pharmchem | 58 |
| Rupali Fine Chemicals | 58 |
| Brisben Chemicals | 58 |
| Loba Chemie Pvt., Ltd. | 58 |
| Samir Chemicals | 58 |
| Innovative | 58 |
| Molychem | 58 |