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ChemicalBook > Product Catalogue >Chemical Reagents >Silane reagent >1-METHOXY-3-TRIMETHYLSILOXY-1,3-BUTADIENE

1-METHOXY-3-TRIMETHYLSILOXY-1,3-BUTADIENE

1-METHOXY-3-TRIMETHYLSILOXY-1,3-BUTADIENE Structure
  • ₹3160.9 - ₹10933
  • Product name: 1-METHOXY-3-TRIMETHYLSILOXY-1,3-BUTADIENE
  • CAS: 54125-02-9
  • MF: C8H16O2Si
  • MW: 172.3
  • EINECS:629-035-5
  • MDL Number:MFCD00008498
  • Synonyms:TRANS-1-METHOXY-3-TRIMETHYLSILOXY-1,3-BUTADIENE;TRANS-1-METHOXY-3-(TRIMETHYLSILYLOXY)-1,3-BUTADIENE;DANISHEFSKY'S DIENE;1-METHOXY-3-TRIMETHYLSILOXY-1,3-BUTADIENE;1-METHOXY-3-(TRIMETHYLSILOXY)BUTADIENE;1-METHOXY-3-TRIMETHYLSILYLOXY-1,3-BUTADIENE;TRANS-1-METHOXY-3-TRIMETHYLSILOXY- &;1-Methoxy-3-(trimethylsiloxy)butadiene(Danishefsky`sDiene)
Price6 Properties Safety Information Description
6 prices
Selected condition：

Brand

  • Sigma-Aldrich(India)
  • ALFA India

Package

  • 1G
  • 5G
  • ManufacturerSigma-Aldrich(India)
  • Product number212830
  • Product descriptiontrans-1-Methoxy-3-trimethylsiloxy-1,3-butadiene 95%
  • Packaging5G
  • Price₹10738.4
  • Updated2022-06-14
  • Buy
  • ManufacturerSigma-Aldrich(India)
  • Product number212830
  • Product descriptiontrans-1-Methoxy-3-trimethylsiloxy-1,3-butadiene 95%
  • Packaging1G
  • Price₹3160.9
  • Updated2022-06-14
  • Buy
  • ManufacturerALFA India
  • Product numberALF-L06100-06
  • Product description1-Methoxy-3-trimethylsiloxy-1,3-butadiene, 94%
  • Packaging5g
  • Price₹10933
  • Updated2022-05-26
  • Buy
  • ManufacturerALFA India
  • Product numberALF-L14672-06
  • Product description1-Methoxy-3-trimethylsiloxy-1,3-butadiene, 96%
  • Packaging5g
  • Price₹9804
  • Updated2022-05-26
  • Buy
  • ManufacturerALFA India
  • Product numberALF-L14672-03
  • Product description1-Methoxy-3-trimethylsiloxy-1,3-butadiene, 96%
  • Packaging1g
  • Price₹4027
  • Updated2022-05-26
  • Buy
  • ManufacturerALFA India
  • Product numberALF-L06100-03
  • Product description1-Methoxy-3-trimethylsiloxy-1,3-butadiene, 94%
  • Packaging1g
  • Price₹3335
  • Updated2022-05-26
  • Buy
Manufacturer Product number Product description Packaging Price Updated Buy
Sigma-Aldrich(India) 212830 trans-1-Methoxy-3-trimethylsiloxy-1,3-butadiene 95% 5G ₹10738.4 2022-06-14 Buy
Sigma-Aldrich(India) 212830 trans-1-Methoxy-3-trimethylsiloxy-1,3-butadiene 95% 1G ₹3160.9 2022-06-14 Buy
ALFA India ALF-L06100-06 1-Methoxy-3-trimethylsiloxy-1,3-butadiene, 94% 5g ₹10933 2022-05-26 Buy
ALFA India ALF-L14672-06 1-Methoxy-3-trimethylsiloxy-1,3-butadiene, 96% 5g ₹9804 2022-05-26 Buy
ALFA India ALF-L14672-03 1-Methoxy-3-trimethylsiloxy-1,3-butadiene, 96% 1g ₹4027 2022-05-26 Buy
ALFA India ALF-L06100-03 1-Methoxy-3-trimethylsiloxy-1,3-butadiene, 94% 1g ₹3335 2022-05-26 Buy

Properties

Boiling point :68-69 °C/14 mmHg (lit.)
Density :0.885 g/mL at 25 °C (lit.)
refractive index :n20/D 1.454(lit.)
Flash point :113 °F
storage temp. :2-8°C
form :liquid
Specific Gravity :0.89
Water Solubility :Miscible with most organic solvents. Immiscible with water.
Hydrolytic Sensitivity :8: reacts rapidly with moisture, water, protic solvents
Sensitive :Moisture Sensitive
Merck :14,6001
BRN :1616761
CAS DataBase Reference :54125-02-9(CAS DataBase Reference)

Safety Information

Symbol(GHS): GHS hazard pictograms
Signal word: Warning
Hazard statements:
Code Hazard statements Hazard class Category Signal word Pictogram P-Codes
H226 Flammable liquid and vapour Flammable liquids Category 3 Warning
Precautionary statements:
P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking.
P233 Keep container tightly closed.
P240 Ground/bond container and receiving equipment.
P241 Use explosion-proof electrical/ventilating/lighting/…/equipment.
P242 Use only non-sparking tools.
P243 Take precautionary measures against static discharge.

Description

1-Methoxy-3-trimethylsiloxy-1,3-butadiene is employed as a reagent in Mannich-Michael reaction for the synthesis of piperidinones and enaminones. As Diels-Alder diene, it is used in the synthesis of pyridones and pyranones, sulfone analogues of griseofulvin (sulfogriseofulvins) and 4H-1-aminopyrroles and 4, 5H-pyrazoles.

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