Phenylselenenyl chloride
![Phenylselenenyl chloride Structure](CAS/GIF/5707-04-0.gif)
- CAS No.
- 5707-04-0
- Chemical Name:
- Phenylselenenyl chloride
- Synonyms
- enenyL;chloroselenobenzene;Phenylchloroselenium;Phenylseleno chloride;PHENYLSELENYL CHLORIDE;BENZENESELENYL CHLORIDE;PHENYLSELENIUM CHLORIDE;PHENYLSELENENYL CHLORIDE;BENZENESELENENYL CHLORIDE;phenyl selenohypochlorite
- CBNumber:
- CB6128896
- Molecular Formula:
- C6H5ClSe
- Molecular Weight:
- 191.52
- MOL File:
- 5707-04-0.mol
- MSDS File:
- SDS
- Modify Date:
- 2024/8/6 9:38:05
Melting point | 59-62 °C (lit.) |
---|---|
Boiling point | 120 °C/20 mmHg (lit.) |
Flash point | 120°C/20mm |
storage temp. | Store below +30°C. |
solubility | Soluble in methanol. |
form | crystal |
color | red |
Sensitive | Moisture Sensitive |
Hydrolytic Sensitivity | 7: reacts slowly with moisture/water |
BRN | 1237091 |
Exposure limits |
ACGIH: TWA 0.2 mg/m3 NIOSH: IDLH 1 mg/m3; TWA 0.2 mg/m3 |
Stability | Stable, but may be air or moisture sensitive. Incompatible with strong bases, strong oxidizing agents. |
InChI | InChI=1S/C6H5ClSe/c7-8-6-4-2-1-3-5-6/h1-5H |
InChIKey | WJCXADMLESSGRI-UHFFFAOYSA-N |
SMILES | C1([Se]Cl)=CC=CC=C1 |
CAS DataBase Reference | 5707-04-0(CAS DataBase Reference) |
SAFETY
Risk and Safety Statements
Symbol(GHS) | ![]() ![]() ![]() ![]() GHS05,GHS06,GHS08,GHS09 |
|||||||||
---|---|---|---|---|---|---|---|---|---|---|
Signal word | Danger | |||||||||
Hazard statements | H290-H301+H331-H373-H410 | |||||||||
Precautionary statements | P234-P260-P273-P301+P310-P304+P340+P311-P314 | |||||||||
Hazard Codes | T,N | |||||||||
Risk Statements | 23/25-33-50/53 | |||||||||
Safety Statements | 20/21-28-45-60-61 | |||||||||
RIDADR | UN 2928 6.1/PG 2 | |||||||||
WGK Germany | 3 | |||||||||
F | 10-21 | |||||||||
TSCA | No | |||||||||
HazardClass | 6.1 | |||||||||
PackingGroup | II | |||||||||
HS Code | 29319090 | |||||||||
NFPA 704 |
|
Phenylselenenyl chloride price More Price(7)
Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
---|---|---|---|---|---|---|---|
Sigma-Aldrich(India) | 183342 | Phenylselenyl chloride 98% | 5707-04-0 | 1G | ₹1634.58 | 2022-06-14 | Buy |
Sigma-Aldrich(India) | 183342 | Phenylselenyl chloride 98% | 5707-04-0 | 10G | ₹9645.08 | 2022-06-14 | Buy |
Sigma-Aldrich(India) | 183342 | Phenylselenyl chloride 98% | 5707-04-0 | 50G | ₹39500.43 | 2022-06-14 | Buy |
ALFA India | ALF-A12751-14 | Phenylselenenyl chloride, 98% | 5707-04-0 | 25g | ₹16217 | 2022-05-26 | Buy |
ALFA India | ALF-A12751-06 | Phenylselenenyl chloride, 98% | 5707-04-0 | 5g | ₹4710 | 2022-05-26 | Buy |
Phenylselenenyl chloride Chemical Properties,Uses,Production
Chemical Properties
crystalline solid
Uses
Phenylselenenyl chloride is used in the preparation of (cyclobut-1-enylselanyl)benzene. It is an important versatile reagent used in organic synthesis. Further, it serves as a useful synthon for 2-amino alcohols.
Application
Phenylselenenyl chloride as a reagent for the facile preparation of cyclic ethers from diolefins[1].
General Description
Phenylselenyl chloride is a synthon for 2-amino alcohols. It is a versatile reagent in organic synthesis.
Purification Methods
Purify it by distillation in a vacuum, and recrystallisation (orange needles) from hexane [Foster J Am Chem Soc 55 822 1933, Foster et al. Recl Trav Chim, Pays-Bas 53 405, 408 1934, Behaghel & Seibert Chem Ber 66 714 1933]. [Beilstein 6 III 1110.] HIGHLY TOXIC.
References
[1] S. Uemura. “Phenylselenenyl chloride as a reagent for the facile preparation of cyclic ethers from diolefins.” Tetrahedron Letters 21 1 (1980): 1533–1536.
Phenylselenenyl chloride Preparation Products And Raw materials
Raw materials
Preparation Products
Phenylselenenyl chloride Suppliers
Supplier | Tel | Country | ProdList | Advantage | Inquiry |
---|---|---|---|---|---|
TCI Chemicals (India) Pvt. Ltd. | 1800 425 7889 | New Delhi, India | 6778 | 58 | Inquiry |
Alfa Aesar | 1 800 209 7001 | Maharashtra, India | 6913 | 58 | Inquiry |
CLEARSYNTH LABS LTD. | +91-22-45045900 | Hyderabad, India | 6351 | 58 | Inquiry |
Laurice Labs | 08048372498Ext 403 | Mumbai, India | 58 | 58 | Inquiry |
Mala International | 08068442326Ext 398 | Mumbai, India | 165 | 58 | Inquiry |
Siddhi Specialities | 91-0-9742033800 | Bangalore, India | 162 | 58 | Inquiry |
Chiral Chemicals | 91-22-66332438 | Maharashtra, India | 143 | 58 | Inquiry |
Chongqing Chemdad Co., Ltd | +86-023-6139-8061 +86-86-13650506873 | China | 39916 | 58 | Inquiry |
Henan Tianfu Chemical Co.,Ltd. | +86-0371-55170693 +86-19937530512 | China | 21668 | 55 | Inquiry |
ATK CHEMICAL COMPANY LIMITED | +undefined-21-51877795 | China | 32760 | 60 | Inquiry |
Supplier | Advantage |
---|---|
TCI Chemicals (India) Pvt. Ltd. | 58 |
Alfa Aesar | 58 |
CLEARSYNTH LABS LTD. | 58 |
Laurice Labs | 58 |
Mala International | 58 |
Siddhi Specialities | 58 |
Chiral Chemicals | 58 |
Chongqing Chemdad Co., Ltd | 58 |
Henan Tianfu Chemical Co.,Ltd. | 55 |
ATK CHEMICAL COMPANY LIMITED | 60 |
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