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Diphenyl diselenide

Diphenyl diselenide Structure
CAS No.
1666-13-3
Chemical Name:
Diphenyl diselenide
Synonyms
1,2-Diphenyldiselane;PHENYL DISELENIDE;diseL;Two phenyltwo se;diphenyl-diselenid;Bis(phenylselenide);diphenyl disenenide;DIPHENYL DISELENIDE;Diselenide,diphenyl;Diphenyl perselenide
CBNumber:
CB8853190
Molecular Formula:
C12H10Se2
Molecular Weight:
312.13
MOL File:
1666-13-3.mol
MSDS File:
SDS
Modify Date:
2024/2/25 14:30:17

Diphenyl diselenide Properties

Melting point 60 °C
Boiling point 202 °C / 11mmHg
Density 1.5570
refractive index 1.7430
storage temp. Store below +30°C.
form Powder
color yellow
Specific Gravity 1.84
Water Solubility Insoluble
Hydrolytic Sensitivity 8: reacts rapidly with moisture, water, protic solvents
BRN 2047179
Exposure limits ACGIH: TWA 0.2 mg/m3
NIOSH: IDLH 1 mg/m3; TWA 0.2 mg/m3
CAS DataBase Reference 1666-13-3(CAS DataBase Reference)
NIST Chemistry Reference Diselenide, diphenyl(1666-13-3)
EPA Substance Registry System Diselenide, diphenyl (1666-13-3)

SAFETY

Risk and Safety Statements

Symbol(GHS) 
GHS06,GHS08,GHS09
Signal word  Danger
Hazard statements  H301+H331-H373-H410
Precautionary statements  P273-P301+P310+P330-P304+P340+P311-P314
Hazard Codes  T,N
Risk Statements  23/25-33-50/53
Safety Statements  20/21-28-45-60-61-28A
RIDADR  UN 3283 6.1/PG 2
WGK Germany  3
RTECS  JM9152500
TSCA  Yes
HS Code  2931 90 00
HazardClass  6.1
PackingGroup  II
NFPA 704
1
3 0

Diphenyl diselenide price More Price(16)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich(India) 8.18061 Diphenyl diselenide for synthesis 1666-13-3 5G ₹7050 2022-06-14 Buy
Sigma-Aldrich(India) 42944 Diphenyl diselenide purum, ≥97.0% (GC) 1666-13-3 10G ₹7415.13 2022-06-14 Buy
Sigma-Aldrich 180629 Diphenyl diselenide 98% 1666-13-3 5G ₹4081.03 2022-06-14 Buy
Sigma-Aldrich(India) 180629 Diphenyl diselenide 98% 1666-13-3 5G ₹4081.03 2022-06-14 Buy
Sigma-Aldrich(India) 42944 Diphenyl diselenide purum, ≥97.0% (GC) 1666-13-3 50G ₹17709.7 2022-06-14 Buy
Product number Packaging Price Buy
8.18061 5G ₹7050 Buy
42944 10G ₹7415.13 Buy
180629 5G ₹4081.03 Buy
180629 5G ₹4081.03 Buy
42944 50G ₹17709.7 Buy

Diphenyl diselenide Chemical Properties,Uses,Production

Chemical Properties

yellow crystalline powder

Uses

Diphenyl diselenide is used in the methoxyselenenylation of alkenes, dihydroxylation of double bonds, hydrothiolation of terminal alkynes. It is used in the synthesis of the unsymmetrical diorganyl selenides, 1-(phenylselenomethyl)vinyl selenides, allylic phenyl selenides.

General Description

Diphenyl diselenide (Ph2Se2) is an organoselenium compound. Its crystalline structure, toxicokinetic properties, antioxidant and anti-inflammatory activities have been investigated. Its ability to reverse the oxidative brain damage and mitochondrial dysfunction induced by acetaminophen has been studied in mice. It reacts with thallium (Tl) to form TI (SePh). It participates in a four-component radical coupling to form substituted cyclopentanes.

Purification Methods

Crystallise it twice from hexane [Kice & Purkiss J Org Chem 52 3448 1987]. [Beilstein 6 IV 1781.]

Diphenyl diselenide Preparation Products And Raw materials

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