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DIPHENYL DISULFIDE

DIPHENYL DISULFIDE Structure
CAS No.
882-33-7
Chemical Name:
DIPHENYL DISULFIDE
Synonyms
1,2-diphenyldisulfane;PHENYL DISULFIDE;FEMA 3225;DIPHENYL DISULPHIDE;Diphenyl disulfide ,99%;usafe-1;USAF e-1;AKOS 94361;Phenyl disulfid;Dithiobisbenzene
CBNumber:
CB3716625
Molecular Formula:
C12H10S2
Molecular Weight:
218.34
MOL File:
882-33-7.mol
MSDS File:
SDS
Modify Date:
2024/4/26 17:21:34

DIPHENYL DISULFIDE Properties

Melting point 58-60 °C (lit.)
Boiling point 191-192 °C (15 mmHg)
Density 1.353
refractive index 1,441-1,444
FEMA 3225 | PHENYL DISULFIDE
Flash point 310°C
storage temp. Sealed in dry,Room Temperature
solubility xylene: soluble3%, clear, colorless to yellow
form Crystalline Solid
Specific Gravity 1.353
color White to off-white
Odor at 0.10 % in propylene glycol. sulfurous earthy burnt
Odor Type sulfurous
Water Solubility Insoluble in water.
JECFA Number 578
BRN 639794
Stability Stable. Incompatible with strong oxidizing agents, strong bases.
InChIKey GUUVPOWQJOLRAS-UHFFFAOYSA-N
LogP 4.41
CAS DataBase Reference 882-33-7(CAS DataBase Reference)
NIST Chemistry Reference Disulfide, diphenyl(882-33-7)
EPA Substance Registry System Diphenyl disulfide (882-33-7)

SAFETY

Risk and Safety Statements

Symbol(GHS) 
GHS07,GHS09
Signal word  Warning
Hazard statements  H302-H410
Precautionary statements  P264-P270-P273-P301+P312-P391-P501
Hazard Codes  Xi,N
Risk Statements  36/37/38-50/53
Safety Statements  26-37/39-36-61-60
RIDADR  UN 3335
WGK Germany  3
RTECS  SS6825000
13
Hazard Note  Irritant
TSCA  T
HazardClass  IRRITANT, STENCH
PackingGroup  III
HS Code  29093090
NFPA 704
1
2 0

DIPHENYL DISULFIDE price More Price(8)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich(India) 169021 Phenyl disulfide 99% 882-33-7 10G ₹1948.5 2022-06-14 Buy
Sigma-Aldrich(India) 169021 Phenyl disulfide 99% 882-33-7 50G ₹4026.9 2022-06-14 Buy
Sigma-Aldrich(India) 92528 Phenyl disulfide analytical standard 882-33-7 100MG ₹6332.63 2022-06-14 Buy
Sigma-Aldrich 169021 Phenyl disulfide 99% 882-33-7 250G ₹13791.05 2022-06-14 Buy
Sigma-Aldrich(India) 169021 Phenyl disulfide 99% 882-33-7 250G ₹13791.05 2022-06-14 Buy
Product number Packaging Price Buy
169021 10G ₹1948.5 Buy
169021 50G ₹4026.9 Buy
92528 100MG ₹6332.63 Buy
169021 250G ₹13791.05 Buy
169021 250G ₹13791.05 Buy

DIPHENYL DISULFIDE Chemical Properties,Uses,Production

Chemical Properties

White to light yellow crystal.

Occurrence

Naturally occurring phytoalexin-like substan

Uses

Diphenyl disulfide is one of the most popular organic disulfides used in organic synthesis. It is used as a reagent for the α-phenylsulfenylation of carbonyl compounds. It participates in hydrothiolation of alkynes via amine-mediated single electron transfer mechanism. It is the hydrolysis product of dyfonate.

Preparation

By heating and passing a stream of air over an ammoniacal solution of thiophenol.

Purification Methods

Crystallise the disulfide from MeOH. [Alberti et al. J Am Chem Soc 108 3024 1986]. Also crystallise it repeatedly from hot Et2O, then dry it in a vacuum at 30o over P2O5, fuse it under N2 and re-dry it; the whole procedure being repeated, with a final drying under a vacuum for 24hours. Alternatively, recrystallise it from hexane/EtOH solution. [Burkey & Griller J Am Chem Soc 107 246 1985, Beilstein 6 H 323, 6 IV 1560.]

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PHENYL DISULPHIDE DIPHENYL DISULFIDE DIPHENYLDISULPIDE BIPHENYL DISULFIDE AKOS 94361 (Phenyldisulfanyl)benzene Disulfide,diphenyl disulfidediphenyl dlphenyldisulfide USAF e-1 Nelfinavir Related CoMpound E Phenyl disulfid Diphenyl disulfide (diphenyl disulfide) usafe-1 PHENYL DISULFIDE 98+% phenyldithiobenzene DIPHENTYL DISULFIDE 1,1'-Dithiobisbenzene 4,4'-Dithiobis(benzene) Diphenyl persulfide Dithiobisbenzene Phenyl disulfide,99% Phenyl disulfide, 99% 50GR Thiophenol DiMer (IMpurity E) 1,1'-Disulphanediyldibenzene, 1,1'-Dithiodibenzene 10gdiphenyldisulfide DiphenylDisulfide> Diphenyl disulfide, 99%, for synthesis TIANFUCHEM--882-33-7---DIPHENYL DISULFIDE Nelfinavir Related Compound E (Diphenyl disulfide) (1457957) PHENYL DISULFIDE DIPHENYL DISULPHIDE FEMA 3225 Diphenyl disulfide ,99% 1,2-diphenyldisulfane Diphenyl Disulphide (98%) 882-33-7 C12H10S2 C6H52S2 C6H5SSC6H5 Building Blocks Organic Building Blocks Sulfur Compounds Sulfides/Disulfides Biphenyl & Diphenyl ether bc0001 R00001