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Diphenylmethane

Diphenylmethane Structure
CAS No.
101-81-5
Chemical Name:
Diphenylmethane
Synonyms
diphenyl-methan;Ditan;DITANE;BENZYLPHENYL;BENZYLBENZENE;1,1’-methylenebis-benzen;ai3-00748;ai3-28021-x;Benaylbenzene;-Phenyltoluene
CBNumber:
CB3852608
Molecular Formula:
C13H12
Molecular Weight:
168.23
MOL File:
101-81-5.mol
MSDS File:
SDS
Modify Date:
2024/8/24 19:19:26

Diphenylmethane Properties

Melting point 22-24 °C (lit.)
Boiling point 264 °C (lit.)
Density 1.006 g/mL at 25 °C (lit.)
vapor density 5.79 (vs air)
vapor pressure <1 mm Hg ( 77 °C)
refractive index n20/D 1.577(lit.)
Flash point >230 °F
storage temp. Store below +30°C.
solubility Soluble in ethanol, ether, benzene and chloroform.
pka 33.5(at 25℃)
form Low Melting Solid
Specific Gravity 1.006
color Colorless to pale yellow
Odor at 10.00 % in dipropylene glycol. sweet green wet plastic geranium
Odor Type green
explosive limit 0.69-8.66%(V)
Water Solubility 14.1mg/L(25 ºC)
FreezingPoint 24.0 to 26.0 ℃
Merck 14,3328
BRN 1904982
Dielectric constant 2.6(26℃)
LogP 4.140
CAS DataBase Reference 101-81-5(CAS DataBase Reference)
NIST Chemistry Reference Diphenylmethane(101-81-5)
EPA Substance Registry System Diphenylmethane (101-81-5)

SAFETY

Risk and Safety Statements

Symbol(GHS) 
GHS09
Signal word  Warning
Hazard statements  H410
Precautionary statements  P273-P391-P501
Hazard Codes  Xn
Risk Statements  22
Safety Statements  24/25-58-54-44-29
RIDADR  UN3077
WGK Germany  2
RTECS  DA4976500
Autoignition Temperature 905 °F
TSCA  Yes
HazardClass  9
PackingGroup  III
HS Code  29029090
Toxicity LD50 orally in Rabbit: 2250 mg/kg LD50 dermal Rabbit > 5000 mg/kg
NFPA 704
1
1 0

Diphenylmethane price More Price(12)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich(India) D209317 Diphenylmethane 99% 101-81-5 25G ₹2168.03 2022-06-14 Buy
Sigma-Aldrich(India) D209317 Diphenylmethane 99% 101-81-5 1KG ₹4932 2022-06-14 Buy
Sigma-Aldrich(India) D209317 Diphenylmethane 99% 101-81-5 500G ₹7665.15 2022-06-14 Buy
ALFA India ALF-B21256-36 Diphenylmethane, 99+% 101-81-5 500g ₹3136 2022-05-26 Buy
ALFA India ALF-B21256-22 Diphenylmethane, 99+% 101-81-5 100g ₹2476 2022-05-26 Buy
Product number Packaging Price Buy
D209317 25G ₹2168.03 Buy
D209317 1KG ₹4932 Buy
D209317 500G ₹7665.15 Buy
ALF-B21256-36 500g ₹3136 Buy
ALF-B21256-22 100g ₹2476 Buy

Diphenylmethane Chemical Properties,Uses,Production

Chemical Properties

Colorless to pale yellow low melting solid

Occurrence

Has apparently not been reported to occur in nature.

Uses

Diphenylmethane, is used as an adhesive chemical composition for making flexible laminates for use in food packaging.

Preparation

By interaction of benzyl chloride and benzene in the presence of an acid cata lyst.

Definition

ChEBI: A diarylmethane that is methane substituted by two phenyl groups.

Metabolism

Diphenylmethane is hydroxylated in the rabbit and some 15% of the dose is excreted as 4-hydroxydiphenylmethane, which is largely (80-90%) in the free state. Neither the hydrocarbon nor its metabolite is oestrogenic. This reaction also occurs in the dog (Williams, 1959).

Purification Methods

Sublime it under vacuum, or distil it at 72-75o/0.4mm. Recrystallise it from cold EtOH. It has also been purified by fractional crystallisation from the melt. [Armarego Aust J Chem 13 95 1960, Beilstein 5 II 498, 5 IV 1841.]

Global( 462)Suppliers
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