PSEUDOJERVINE

PSEUDOJERVINE Structure
CAS No.
36069-05-3
Chemical Name:
PSEUDOJERVINE
Synonyms
PSEUDOJERVINE;Spiro[9H-benzo[a]fluorene-9,2'(3'H)-furo[3,2-b]pyridin]-11(1H)-one, 3-(β-D-glucopyranosyloxy)-2,3,3'a,4,4',5',6,6',6a,6b,7,7',7'a,8,11a,11b-hexadecahydro-3',6',10,11b-tetramethyl-, (2'R,3S,3'R,3'aS,6'S,6aS,6bS,7'aR,11aS,11bR)-
CBNumber:
CB61424850
Molecular Formula:
C33H49NO8
Molecular Weight:
587.749
MOL File:
36069-05-3.mol
Modify Date:
2023/9/4 15:51:00

PSEUDOJERVINE Properties

Melting point 300-301° (dec)
alpha D25 -133° (c = 0.48 in 1:3 ethanol-chloroform)
Boiling point 643.44°C (rough estimate)
Density 1.1485 (rough estimate)
refractive index 1.5960 (estimate)
pka 12.91±0.70(Predicted)

PSEUDOJERVINE Chemical Properties,Uses,Production

Description

This alkaloid has been found in both Veratrum album and V. viride Ait. It crystallizes from EtOH in hexagonal tablets and has [α]20D - 139° (CHC13). The hydrochloride dihydrate has m.p. 254-6°C (dry, dec.); the sulphate is also crystalline but the aurichloride is amorphous. Poethke has shown that the alkaloid is a secondary base, gives a nitro so derivative, m.p. 261°C, and contains five replaceable hydrogen atoms. On boiling with dilute HCl it is hydrolyzed to (+)- glucose and isojervine, an isomer of jervine. This latter base crystallizes with solvent, e.g. the CHC13 adduct softens at 135-1500 C; the crystallizate with EtOH has m.p. 114-6°C (dec.) and that with Me2CO has m.p. 110-4°C; [α]20D - 32° (EtOH).

References

Wright, Luff., J. Chem. Soc., 35,405,421 (1879)
Salzberger., Arch. Pharm., 228,462 (1890)
Poethke., ibid, 275,357,571 (1937)
Poethke., ibid, 276, 170 (1938)
Jacobs, Craig.,J. Biol. Chem., 155,564 (1944)

PSEUDOJERVINE Preparation Products And Raw materials

Raw materials

Preparation Products

PSEUDOJERVINE Suppliers

Global( 35)Suppliers
Supplier Tel Country ProdList Advantage Inquiry
Chengdu Biopurify Phytochemicals Ltd. +8618080483897 China 3772 58 Inquiry
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Chengdu Biopurify Phytochemicals Ltd. +86-028-82633397 18982077548 China 2376 60 Inquiry
Chengdu Push Bio-Technology Co., Ltd. 18080489829 China 9209 58 Inquiry
Shanghai Taopu Industrial Co., LTD 18018507602 15900573766 China 3017 58 Inquiry
Chengdu Push Bio-Technology Co., Ltd. 028-85370565-229 18080489829 China 8879 60 Inquiry
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Wuhan Huangzhen Biochemical Co., Ltd 13795480948 13795480948 China 4958 58 Inquiry
Shanghai Zhiyun Biotechnology Co., Ltd 13119135307 China 2768 58 Inquiry
Hubei CuiRan Biotechnology Co., Ltd. 18162791556 China 4351 58 Inquiry

PSEUDOJERVINE Spectrum

PSEUDOJERVINE Spiro[9H-benzo[a]fluorene-9,2'(3'H)-furo[3,2-b]pyridin]-11(1H)-one, 3-(β-D-glucopyranosyloxy)-2,3,3'a,4,4',5',6,6',6a,6b,7,7',7'a,8,11a,11b-hexadecahydro-3',6',10,11b-tetramethyl-, (2'R,3S,3'R,3'aS,6'S,6aS,6bS,7'aR,11aS,11bR)- 36069-05-3