ChemicalBook > Product Catalog >Chemical Reagents >Organic reagents >Phosphine ligand >(4S)-(-)-4,5-DIHYDRO-2-[2'-(DIPHENYLPHOSPHINO)PHENYL]-4-ISOPROPYLOXAZOLE

(4S)-(-)-4,5-DIHYDRO-2-[2'-(DIPHENYLPHOSPHINO)PHENYL]-4-ISOPROPYLOXAZOLE

CAS No.: 148461-14-7

Chemical Name:: (4S)-(-)-4,5-DIHYDRO-2-[2'-(DIPHENYLPHOSPHINO)PHENYL]-4-ISOPROPYLOXAZOLE

Synonyms: (S)-iPr-Phox;Diphenylphosphinophenylmethylethyldihydrooxazole;(S)-(-)-2-[2-(Diphenylphosphino)phenyl]-4-isopropyl-2-;)-2-[2-(Diphenylphosphino)phenyl]-4-isopropyl-2-oxazoline;(S)-2-(2-(Diphenylphosphino)phenyl)-4-isopropyl-4,5-dihydroo;(-)(4S)-2-[2-(DIPHENYLPHOSPHINO)PHENYL]-4-(2-PROPYL)OXAZOLINE;(S)-(-)-2-[2-(DIPHENYLPHOSPHINO)PHENYL]-4-ISOPROPYL-2-OXAZOLINE;2-(2-Diphenylphosphanyl-phenyl)-4-isopropyl-4,5-dihydro-oxazole;(-)(4S)-2-[2-(Diphenylphosphino)phenyl]-4-(2-propyl)oxazoline 97%;(S)-2-(2-(Diphenylphosphino)phenyl)-4-isopropyl-4,5-dihydrooxazole

CBNumber:: CB6159670

Molecular Formula:: C24H24NOP

Molecular Weight:: 373.43

MOL File:: 148461-14-7.mol

Modify Date:: 2024/3/22 17:12:53

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(4S)-(-)-4,5-DIHYDRO-2-[2'-(DIPHENYLPHOSPHINO)PHENYL]-4-ISOPROPYLOXAZOLE Properties

Melting point	85-90 °C
alpha	-44° (c 1.4, CHCl3)
Boiling point	492.7±28.0 °C(Predicted)
storage temp.	under inert gas (nitrogen or Argon) at 2-8°C
pka	4.31±0.70(Predicted)
form	Powder
color	white
optical activity	[α]20/D 48±3°, c = 1% in chloroform
Sensitive	air sensitive
BRN	5879302

SAFETY

Risk and Safety Statements

Symbol(GHS)	GHS07
Signal word	Warning
Hazard statements	H302-H315-H319-H335
Precautionary statements	P261-P280-P301+P312-P302+P352-P305+P351+P338
Hazard Codes	Xi
Risk Statements	36/37/38
Safety Statements	37/39-26-24/25
WGK Germany	3
F	10-23
Hazard Note	Irritant
HS Code	29349990

(4S)-(-)-4,5-DIHYDRO-2-[2'-(DIPHENYLPHOSPHINO)PHENYL]-4-ISOPROPYLOXAZOLE Chemical Properties,Uses,Production

Chemical Properties

White crystalline powder

Reactions

Chiral ligand used in the asymmetric reduction of highly substituted olefins.
Chiral ligand used in the enantioselective Heck reaction. The success of the reaction is due to the fact that the catalytic system does not promote double bond isomerization.
Chiral ligand used in the entantioselective palladium-catalyzed allylic substitution of sodium benzotriazole.
Decarboxylative allylic alkylation.

(4S)-(-)-4,5-DIHYDRO-2-[2'-(DIPHENYLPHOSPHINO)PHENYL]-4-ISOPROPYLOXAZOLE Preparation Products And Raw materials

Raw materials

Preparation Products

(4S)-(-)-4,5-DIHYDRO-2-[2'-(DIPHENYLPHOSPHINO)PHENYL]-4-ISOPROPYLOXAZOLE Suppliers

Global( 88)Suppliers

Supplier	Tel	Country	ProdList	Advantage	Inquiry
career henan chemical co	+86-0371-86658258 +8613203830695	China	29896	58	Inquiry
Chongqing Chemdad Co., Ltd	+86-023-6139-8061 +86-86-13650506873	China	39916	58	Inquiry
SHANGHAI T&W PHARMACEUTICAL CO., LTD.	+86-021-61551413 +8618813727289	China	5738	58	Inquiry
Dayang Chem (Hangzhou) Co.,Ltd.	571-88938639 +8617705817739	China	52861	58	Inquiry
Zhuoer Chemical Co., Ltd	02120970332; +8613524231522	China	2905	58	Inquiry
XINXIANG RUNYU MATERIAL CO., LTD.	+86-13592593621; +8613592593621	China	432	58	Inquiry
PT CHEM GROUP LIMITED	+86-85511178 +86-85511178	China	35426	58	Inquiry
GIHI CHEMICALS CO.,LIMITED	+8618058761490	China	49999	58	Inquiry
Shaoxin Catsyn Co., Ltd.	+undefined-0575-82040869 +86-0575-82040869;	China	6116	58	Inquiry
LEAPCHEM CO., LTD.	+86-852-30606658	China	43348	58	Inquiry

Supplier	Advantage
career henan chemical co	58
Chongqing Chemdad Co., Ltd	58
SHANGHAI T&W PHARMACEUTICAL CO., LTD.	58
Dayang Chem (Hangzhou) Co.,Ltd.	58
Zhuoer Chemical Co., Ltd	58
XINXIANG RUNYU MATERIAL CO., LTD.	58
PT CHEM GROUP LIMITED	58
GIHI CHEMICALS CO.,LIMITED	58
Shaoxin Catsyn Co., Ltd.	58
LEAPCHEM CO., LTD.	58

148461-14-7((4S)-(-)-4,5-DIHYDRO-2-[2'-(DIPHENYLPHOSPHINO)PHENYL]-4-ISOPROPYLOXAZOLE)Related Search:

Phenyl phosphine Oxazoline (4S)-(-)-4,5-DIHYDRO-2-[2'-(DIPHENYLPHOSPHINO)PHENYL]-4-ISOPROPYLOXAZOLE (4R)-(+)-4,5-DIHYDRO-2-(2'-(DIPHENYLPHOSPHINO)PHENYL)-4-ISOPROPYLOXAZOLE (4S)-(-)-4,5-DIHYDRO-2-[2'-(DIPHENYLPHOSPHINO)PHENYL]-4-ISOPROPYLOXAZOLE

DIPHENYL(P-TOLYL)PHOSPHINE

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(S)-(-)-2-[(DIPHENYLPHOSPHINO)PHENYL]-4-(1-METHYLETHYL)-4,5-DIHYDROOXAZOLE (S)-(-)-2-[2-(DIPHENYLPHOSPHINO)PHENYL]-4-(1-ISOPROPYL)-4,5-DIHYDROOXAZOLE (S)-(-)-2-[2-(DIPHENYLPHOSPHINO)PHENYL]-4-(1-METHYLETHYL)-4,5-DIHYDROOXAZOLE (S)-(-)-2-[2-(DIPHENYLPHOSPHINO)PHENYL]-4,5-DIHYDRO-4-ISOPROPYLOXAZOLE (S)-(-)-2-[2-(DIPHENYLPHOSPHINO)PHENYL]-4-ISOPROPYL-2-OXAZOLINE (-)(4S)-2-[2-(DIPHENYLPHOSPHINO)PHENYL]-4-(2-PROPYL)OXAZOLINE (4S)-(-)-4,5-DIHYDRO-2-[2'-(DIPHENYLPHOSPHINO)PHENYL]-4-ISOPROPYLOXAZOLE (S)-(-)-2-[2-(Diphenylphosphino)phenyl]-4-isopropyl-2- (4S)-2-(2-(Diphenylphosphino)phenyl)-4-isopropyl-4,5-dihydrooxazole Diphenylphosphinophenylmethylethyldihydrooxazole (4S)-(-)-4,5-Dihydro-2-[2'-(diphenylphosphino)phenyl]-4-isopropyloxazole,98% (S)-(-)-2-[2-(Diphenylphosphino)phenyl]-4-(1-methylethyl)-4,5-dihydrooxazole,98% (-)(4S)-2-[2-(Diphenylphosphino)phenyl]-4-(2-propyl)oxazoline 97% 2-(2-Diphenylphosphanyl-phenyl)-4-isopropyl-4,5-dihydro-oxazole (S)-(-)-2-[(2-(DIPHENYLPHOSPHINO)PHENYL]-4-(1-METHYLETHYL)-4,5-DIHYDROOXAZOLE,98%(S)-IPR-PHOX (4S)-2-[2-(diphenylphosphino)phenyl]-4,5-dihydro-4-(1-Methylethyl)-Oxazole (4S)-(-)-2-(2-Diphenylphosphanyl-phenyl)-4-isopropyl-4,5-dihydro-oxazole )-2-[2-(Diphenylphosphino)phenyl]-4-isopropyl-2-oxazoline (S)-(-)-2-[2-(Diphenylphosphino)phenyl]-4-isopropyl-2-oxazoline >=97.0% (CHN) [2-[(4S)-4-isopropyl-4,5-Dihydrooxazol-2-yl]phenyl]-diphenyl-phosphane Oxazole,2-[2-(diphenylphosphino)phenyl]-4,5-dihydro-4-(1-Methylethyl)-, (4S)- (4S)-2-[2-(Diphenylphosphino)phenyl]-4,5-dihydro-4-(1-methylethyl)oxazole,99%e.e. (S)-2-(2-(Diphenylphosphino)phenyl)-4-isopropyl-4,5-dihydrooxazole (S)-2-(2-(diphenylphosphanyl)phenyl)-4-isopropyl-4,5-dihydrooxazole (S)-iPr-Phox (S)-2-(2-(Diphenylphosphino)phenyl)-4-isopropyl-4,5-dihydroo 148461-14-7 C24H24NOP PHOX Privileged Ligands Chiral Catalysts, Ligands, and Reagents Asymmetric Synthesis Chiral Phosphine PHOX Series organophosphine ligand