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(-)-P-MENTHA-1,5-DIENE

CAS No.: 4221-98-1

Chemical Name:: (-)-P-MENTHA-1,5-DIENE

Synonyms: ALPHA-PHELLANDRENE;(R)-α-Phellandrene;P-MENTHA-1,5-DIENE;L-ALPHA-PHELLANDRENE;Carylene;65.0%(GC);1-phellandrene;PHELLANDRENE, R-;(-)-α-phellandrene;(-)-α-Phellandrene

CBNumber:: CB6240491

Molecular Formula:: C10H16

Molecular Weight:: 136.23

MOL File:: 4221-98-1.mol

MSDS File:: SDS

Modify Date:: 2023/6/8 17:06:38

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(-)-P-MENTHA-1,5-DIENE Properties

alpha	D20 -217°
Boiling point	171-174 °C(lit.)
Density	0.844 g/mL at 20 °C(lit.)
vapor pressure	2.35hPa at 20℃
refractive index	n20/D 1.475
Flash point	49 °C
storage temp.	2-8°C
solubility	Benzene (Sparingly), Ethyl Acetate (Slightly)
form	clear liquid
color	Colorless to Light yellow to Light orange
Odor	at 100.00 %. terpene spicy medicinal
Odor Type	terpenic
optical activity	[α]20/D 225±5°, c = 10% in diethyl ether
Water Solubility	4.37mg/L at 20℃
Merck	14,7200
BRN	2497824
LogP	5.74 at 21.6℃
CAS DataBase Reference	4221-98-1(CAS DataBase Reference)
EPA Substance Registry System	1,3-Cyclohexadiene, 2-methyl-5-(1-methylethyl)-, (5R)- (4221-98-1)

SAFETY

Risk and Safety Statements

Symbol(GHS)

GHS02

Signal word

Warning

Hazard statements

H226

Precautionary statements

P210

Risk Statements

RIDADR

UN 2319 3/PG 3

WGK Germany

HS Code

2902.19.0050

HazardClass

PackingGroup

III

NFPA 704

	2
0		0

(-)-P-MENTHA-1,5-DIENE price More Price(4)

Manufacturer	Product number	Product description	CAS number	Packaging	Price	Updated	Buy
Sigma-Aldrich(India)	77429	(R)-(−)-α-Phellandrene ≥95.0% (sum of enantiomers, GC)	4221-98-1	1ML	₹10700	2022-06-14	Buy
Sigma-Aldrich(India)	77429	(R)-(−)-α-Phellandrene ≥95.0% (sum of enantiomers, GC)	4221-98-1	5ML	₹23840	2022-06-14	Buy
TCI Chemicals (India)	M0051	(-)-α-Phellandrene min. 65.0 %	4221-98-1	5ML	₹9000	2022-05-26	Buy
TCI Chemicals (India)	M0051	(-)-α-Phellandrene min. 65.0 %	4221-98-1	25ML	₹16300	2022-05-26	Buy

Product number	Packaging	Price	Buy
77429	1ML	₹10700	Buy
77429	5ML	₹23840	Buy
M0051	5ML	₹9000	Buy
M0051	25ML	₹16300	Buy

(-)-P-MENTHA-1,5-DIENE Chemical Properties,Uses,Production

Chemical Properties

(?)-α-Phellandrene is a colorless liquid with a citrus odor and a slight peppery note. It is isolated, for example, from Eucalyptus dives oil. Pinenes are widespread, naturally occurring terpene hydrocarbons. The α- and β-forms occur in varying ratios in essential oils.

Uses

(R)-(-)-α-Phellandrene undergoes [4+2] cycloaddition with 2-naphthyl acetylenecarboxylate to form a chiral diene, which can act as a ligand for the rhodium-catalyzed asymmetric addition reactions. It may be used to synthesize (1S,5R)-5-(1-methylethyl)-2-methylidene-3-cyclohexen-1-yl hydroperoxide, which on reduction forms trans-yabunikkeol.

General Description

(R)-(-)-α-Phellandrene is a monoterpene derivative.

Purification Methods

Purify it by gas chromatography on an Apiezon column. Also purify it by steam distillation (with 0.5% hydroquinone), then re-distil it through a 50 plate bubble cap column b 72-72.5o/22mm [Pines & Eschinazi J Am Chem Soc 77 6318 1955]. UV: max 263nm ( 3,345) in octane. [Read & Storey J Chem Soc 2770 1930, Beilstein 5 III 341, 5 IV 436.]

(-)-P-MENTHA-1,5-DIENE Preparation Products And Raw materials

Raw materials

Preparation Products

(-)-P-MENTHA-1,5-DIENE Suppliers

Global( 100)Suppliers

Supplier	Tel	Country	ProdList	Advantage	Inquiry
SRI ANAGHA BIOSCIENCES PVT LTD	+91-9959644262 +91-9959644262	Telangana, India	25	58	Inquiry
TCI Chemicals (India) Pvt. Ltd.	1800 425 7889	New Delhi, India	6778	58	Inquiry
SynZeal Research Pvt Ltd	+1 226-802-2078	Gujarat, India	6522	58	Inquiry
Career Henan Chemica Co	+86-0371-86658258 +8613203830695	China	30253	58	Inquiry
TargetMol Chemicals Inc.	+1-781-999-5354	United States	19973	58	Inquiry
ZHEJIANG JIUZHOU CHEM CO., LTD	+86-0576225566889 +86-13454675544	China	19947	58	Inquiry
LEAPCHEM CO., LTD.	+86-852-30606658	China	43348	58	Inquiry
Shanghai Acmec Biochemical Technology Co., Ltd.	+undefined18621343501	China	33350	58	Inquiry
Aladdin Scientific	+1-+1(833)-552-7181	United States	57511	58	Inquiry
Suzhou ARTK Medchem Co., Ltd.	+8618168183658	China	39009	58	Inquiry

Supplier	Advantage
SRI ANAGHA BIOSCIENCES PVT LTD	58
TCI Chemicals (India) Pvt. Ltd.	58
SynZeal Research Pvt Ltd	58
Career Henan Chemica Co	58
TargetMol Chemicals Inc.	58
ZHEJIANG JIUZHOU CHEM CO., LTD	58
LEAPCHEM CO., LTD.	58
Shanghai Acmec Biochemical Technology Co., Ltd.	58
Aladdin Scientific	58
Suzhou ARTK Medchem Co., Ltd.	58

4221-98-1((-)-P-MENTHA-1,5-DIENE)Related Search:

P-MENTHA-3,6-DIENE-2,5-DIONE P-MENTHA-6,8-DIENE-2-ONE β-sesquiphellandrene 3,9-Epoxy-p-mentha-3,8-diene,p-Mentha-3,8-diene, 3,9-epoxy- DL-Limonene

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(-)-P-MENTHA-1,5-DIENE Α-PHELLANDRENE p-Mentha-1,8-diene, (±,Mentha-1,8-diene (dl) P-MENTHA-1,8-DIENE DIOXIDE (+)-TRANS-P-MENTHA-1,8-DIENE 1,2-EPOXIDE

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(R)-5-isopropyl-2-methylcyclohexa-1,3-diene 1,3-Cyclohexadiene, 2-methyl-5-(1-methylethyl)-, (5R)- R-(-)-A-PHELLANDRENE WITH GC (-)-α-phellandrene (R)-2-methyl-5-(1-methylethyl)-1,3-cyclohexadiene (-)-p-Mentha-1,5-diene, (R)-5-Isopropyl-2-methyl-1,3-cyclohexadiene PETUNIDIN CHLORIDE(SH) (R)-()-α-Phellandrene,()-p-Mentha-1,5-diene, (R)-5-Isopropyl-2-methyl-1,3-cyclohexadiene (-)-5-Isopropyl-2-methyl-1,3-cyclohexadiene (-)-p-Mentha-1,5-diene (R)-(-)-alpha-Phellandrene >=95.0% (sum of enantiomers, GC) 1,3-cyclohexadiene,2-methyl-5-(1-methylethyl)-,(R)- 1-phellandrene 2-methyl-5-(1-methylethyl)-3-cyclohexadien(theta)- 3-Cyclohexadiene,2-methyl-5-(1-methylethyl)-,(R)-1 p-mentha-1,5-diene,(R)-(-)- α-phellandrene,(-)- (-)-5-ISOPROPYL-2-METHYL-1,3-CYCLOHEXADIENE (-)-2-METHYL-5-ISOPROPYL-1,3-CYCLOHEXADIENE R(-)-ALPHA-PHELLANDRENE (R)-5-ISOPROPYL-2-METHYL-1,3-CYCLOHEXADIENE (-)-P-MENTHA-1,5-DIENE PHELLANDRENE, R-(-)-ALPHA- (5R)-2-methyl-5-propan-2-ylcyclohexa-1,3-diene 65.0%(GC) (-)-α-Phellandrene> (-)-alpha-Phellandrene Carylene (-)-α-Phellandrene (-)-P-MENTHA-1,5-DIENE L-ALPHA-PHELLANDRENE ALPHA-PHELLANDRENE P-MENTHA-1,5-DIENE (R)-α-Phellandrene (-)-5-Isopropyl-2-Methyl-1,3-Cyclohexadiene )-p-Mentha-1,5-diene, (R)-5-Isopropyl-2-methyl-1,3-cyclohexadiene PHELLANDRENE, R- 4221-98-1 221-98-1 Terpenes Monocyclic Monoterpenes Organic Building Blocks Chiral Building Blocks Asymmetric Synthesis Alkenes Biochemistry Monocyclic Monoterpenes Terpenes