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Chloro[(R)-(+)-5,5'-bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole](p-cymene)ruthenium(II) chloride [RuCl(p-cymene)((R)-segphos)]Cl

Chloro[(R)-(+)-5,5'-bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole](p-cymene)ruthenium(II) chloride [RuCl(p-cymene)((R)-segphos)]Cl Structure
CAS No.
944451-28-9
Chemical Name:
Chloro[(R)-(+)-5,5'-bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole](p-cymene)ruthenium(II) chloride [RuCl(p-cymene)((R)-segphos)]Cl
Synonyms
Reaxys ID: 11782476;[RuCl(p-cymene)((R)-segphos;oro[(R)-(+)-5,5'-bis(diphenyL;(R)RuCl[(pcyMene)(SEGPHOS)]Cl;RuCl(p-cymene)((R)-segphos)]C;[RUCL(P-CYMENE)((R)-SEGPHOS)]CL;[RuCl(p-cymene)((R)-segphos[R])]Cl;[RuCl(p-cymene)((R)-segphos(regR))]Cl;(R)?RuCl[(p?cymene)(SEGPHOS?)]Cl;Chloro[(R)-(+)-5,5'-bis(diphenylphosphino)-4,4'-bi-1,3-benzo...
CBNumber:
CB62521020
Molecular Formula:
C48H40Cl2O4P2Ru
Molecular Weight:
914.76
MOL File:
944451-28-9.mol
MSDS File:
SDS
Modify Date:
2025/1/27 9:38:02
Request For Quotation

Chloro[(R)-(+)-5,5'-bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole](p-cymene)ruthenium(II) chloride [RuCl(p-cymene)((R)-segphos)]Cl Properties

Melting point >100°C
storage temp. 2-8°C
Water Solubility Insoluble in water
form Powder
color yellow
Sensitive air sensitive

SAFETY

Risk and Safety Statements

Symbol(GHS) 
GHS07
Signal word  Warning
Hazard statements  H335-H319-H315
Precautionary statements  P264-P280-P305+P351+P338-P337+P313P-P264-P280-P302+P352-P321-P332+P313-P362
WGK Germany  3
HS Code  2843.90.0000

Chloro[(R)-(+)-5,5'-bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole](p-cymene)ruthenium(II) chloride [RuCl(p-cymene)((R)-segphos)]Cl price More Price(4)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich(India) 692522 (R)−RuCl[(p−cymene)(SEGPHOS®)]Cl 944451-28-9 50MG ₹1431.9 2022-06-14 Buy
Sigma-Aldrich(India) 692522 (R)−RuCl[(p−cymene)(SEGPHOS®)]Cl 944451-28-9 100MG ₹3629.7 2022-06-14 Buy
TCI Chemicals (India) R0154 [RuCl(p-cymene)((R)-segphos®)]Cl 944451-28-9 200MG ₹5100 2022-05-26 Buy
TCI Chemicals (India) R0154 [RuCl(p-cymene)((R)-segphos®)]Cl 944451-28-9 1G ₹11000 2022-05-26 Buy
Product number Packaging Price Buy
692522 50MG ₹1431.9 Buy
692522 100MG ₹3629.7 Buy
R0154 200MG ₹5100 Buy
R0154 1G ₹11000 Buy

Chloro[(R)-(+)-5,5'-bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole](p-cymene)ruthenium(II) chloride [RuCl(p-cymene)((R)-segphos)]Cl Chemical Properties,Uses,Production

Uses

Takasago Ligands and Complexes for Asymmetric Reactions

Reactions

1. Highly active highly enantioselective catalyst for hydrogenation of functionalized ketones. Slightly higher temperature is necessary to activate the cymene complexes.
2. Asymmetric hydrogenation of α-substituted-β-alkyl-β-ketoesters accompanied by dynamic kinetic resolution.
Reactions of 944451-28-9

Chloro[(R)-(+)-5,5'-bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole](p-cymene)ruthenium(II) chloride [RuCl(p-cymene)((R)-segphos)]Cl Preparation Products And Raw materials

Raw materials

Preparation Products

Chloro[(R)-(+)-5,5'-bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole](p-cymene)ruthenium(II) chloride [RuCl(p-cymene)((R)-segphos)]Cl Suppliers

Global( 59)Suppliers
Supplier Tel Country ProdList Advantage Inquiry
TCI Chemicals (India) Pvt. Ltd. 1800 425 7889 New Delhi, India 6768 58 Inquiry
career henan chemical co +86-0371-86658258 +8613203830695 China 29858 58 Inquiry
SHANGHAI T&W PHARMACEUTICAL CO., LTD. +86-021-61551413 +8618813727289 China 5738 58 Inquiry
Alfa Chemistry United States 2344 58 Inquiry
Bio Connect Life Sciences United States 261 58 Inquiry
Hefei TNJ Chemical Industry Co.,Ltd. +86-0551-65418684 +8618949823763 China 25356 58 Inquiry
Shaoxin Catsyn Co., Ltd. +undefined-0575-82040869 +86-0575-82040869; China 6114 58 Inquiry
Aladdin Scientific United States 57505 58 Inquiry
Anhuyan (Hainan) Biotechnology Co., LTD +8618163349544 China 2764 58 Inquiry
Chongqing Chemdad Co., Ltd +86-023-6139-8061 +86-86-13650506873 China 39927 58 Inquiry
Supplier Advantage
TCI Chemicals (India) Pvt. Ltd. 58
career henan chemical co 58
SHANGHAI T&W PHARMACEUTICAL CO., LTD. 58
Alfa Chemistry 58
Bio Connect Life Sciences 58
Hefei TNJ Chemical Industry Co.,Ltd. 58
Shaoxin Catsyn Co., Ltd. 58
Aladdin Scientific 58
Anhuyan (Hainan) Biotechnology Co., LTD 58
Chongqing Chemdad Co., Ltd 58

944451-28-9(Chloro[(R)-(+)-5,5'-bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole](p-cymene)ruthenium(II) chloride [RuCl(p-cymene)((R)-segphos)]Cl)Related Search:

Dimethylammonium dichlorotri(chloro)bis{(R)-(+)-5,5'-bis[di(3,5-xylyl)phosphino]-4,4'-bi-1,3-benzodioxole}diruthenate(II) [NH2Me2][{RuCl((R)-dm-segphos)}2(Cl)3] Dimethylammoniumdichlorotri(mu-chloro)bis[(S)-(-)-5,5'-bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole]diruthenate(II) Diacetato[(R)-(+)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl]ruthenium(II) Chloro[tri(p-tolyl)phosphine]gold(I),97% XantPhos-Pd-G2
Chloro[(S)-(-)-2,2'-bis(di-p-tolylphosphino)-1,1'-binaphthyl](p-cymene)ruthenium(II)chloride (2-BIPHENYL)DI-TERT-BUTYLPHOSPHINE GOLD& BrettPhosPalladacycle Chloro[(tri-tert-butylphosphine)-2-(2-aMinobiphenyl)]palladiuM(II) Chloro[tri(o-tolyl)phosphine]gold(I)
Chloro{[(1R,2R)-(-)-2-amino-1,2-diphenylethyl](4-toluenesulfonyl)amido}(mesitylene)ruthenium(II), min. 90% RuCl[(R,R)-Tsdpen(mesitylene) (1,3-Bis(2,6-diisopropylphenyl)-1H-imidazol-2(3H)-ylidene)chloro(cinnamyl)palladate(II) CHLORO(TRIS(PARA-TRIFLUOROMETHYLPHENYL)& Chloro{(S)-(+)-5,5'-bis[di(3,5-di-t-butyl-4-methoxyphenyl)phosphino]-4,4'-bi-1,3-benzodioxole}(p-cymene)ruthenium(II)chloride[RuCl(p-cymene) ((S)-dtbm-segphos)]Cl　 Chloro{(S)-(-)-5,5'-bis[di(3,5-xylyl)phosphino]-4,4'-bi-1,3-benzodioxole} (p-cymene)ruthenium(II)chloride[RuCl(p-cymene)((S)-dm-segphos)]Cl
Chloro{(R)-(-)-5,5'-bis[di(3,5-di-t-butyl-4-methoxyphenyl)phosphino]-4,4'-bi-1,3-benzodioxole}(p-cymene)ruthenium(II)chloride[RuCl(p-cymene) ((R)-dtbm-segphos)]Cl　 Chloro{(R)-(+)-5,5'-bis[di(3,5-xylyl)phosphino]-4,4'-bi-1,3-benzodioxole} (p-cymene)ruthenium(II)chloride[RuCl(p-cymene)((R)-dm-segphos)]Cl　 Chloro[(S)-(-)-5,5'-bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole](p-cymene)ruthenium(II)chloride[RuCl (p-cymene)((S)-segphos)]Cl　
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Chloro[(R)-(+)-5,5'-bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole](p-cymene)ruthenium(II) chloride [RuCl(p-cymene)((R)-segphos)]Cl (R)RuCl[(pcyMene)(SEGPHOS)]Cl [RuCl(p-cymene)((R)-segphos(regR))]Cl CHLORO[(R)-(+)-5,5'-BIS(DIPHENYLPHOSPHINO)-4,4'-BI-1,3-BENZODIOXOLE](P-CYMENE)RUTHENIUM(II) CHLORIDE,[RUCL(P-CYMENE)((R)-SEGPHOS [RUCL(P-CYMENE)((R)-SEGPHOS)]CL -bi-1,3-benzodioxole](p-cymene)ruthenium(II) chloride,[RuCl(p-cymene)((R)-segphos Reaxys ID: 11782476 Chloro[(R)-(+)-5,5'-bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole](p-cymene)ruthenium(II) chloride [RuCl(p-cymene)((R)-segphos(R))]Cl [RuCl(p-cymene)((R)-segphos[R])]Cl chlororuthenium(1+):[4-(5-diphenylphosphanyl-1,3-benzodioxol-4-yl)-1,3-benzodioxol-5-yl]-diphenylphosphane:1-methyl-4-propan-2-ylbenzene:chloride oro[(R)-(+)-5,5'-bis(diphenyL Chloro[(R)-(+)-5,5'-bis(diphenylphosphino)-4,4'-bi-1,3-benzo... [RuCl(p-cymene)((R)-segphos RuCl(p-cymene)((R)-segphos)]C Chloro[(R)-(+)-5,5'-bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole](p-cymene)ruthenium(II) Chloride (R)?RuCl[(p?cymene)(SEGPHOS?)]Cl 944451-28-9 C48H42Cl2O4P2Ru C48H42ClO4P2RuCl Ru