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Chloro[(tri-tert-butylphosphine)-2-(2-aMinobiphenyl)]palladiuM(II)

CAS No.: 1375325-71-5

Chemical Name:: Chloro[(tri-tert-butylphosphine)-2-(2-aMinobiphenyl)]palladiuM(II)

Synonyms: P(tBu)3 Pd G2;tBu3PPdG2 catalyst;P(t-Bu)3 Palladacycle Gen.2;Chloro[(tri-t-butylphosphine)-2-(2-aminobiphenyl)]palladium(II);Chloro(tri-t-butylphosphine)(2'-amino-1,1'-biphenyl-2-yl)pal...;Chloro(tri-tert-butylphosphine)(2'-aminobiphenylyl)palladium(II);Chloro[(tri-tert-butylphosphine)-2-(2-aMinobiphenyl)]palladiuM(II);Chloro[(tri-tert-butylphosphine)(2-aminobiphenyl-2-yl)palladium(II);Chloro[(tri-tert-butylphosphine)-2-(2-aminobiphenyl)]palladium(II)>Chloro(tri-t-butylphosphine)(2'-amino-1,1'-biphenyl-2-yl)palladium(II)

CBNumber:: CB42673226

Molecular Formula:: C24H37ClNPPd

Molecular Weight:: 512.41

MOL File:: 1375325-71-5.mol

Modify Date:: 2024/4/28 19:50:54

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Chloro[(tri-tert-butylphosphine)-2-(2-aMinobiphenyl)]palladiuM(II) Properties

Melting point	158-160°C
form	Powder
color	yellow
InChI	InChI=1S/C12H9N.C12H27P.ClH.Pd/c13-12-9-5-4-8-11(12)10-6-2-1-3-7-10;1-10(2,3)13(11(4,5)6)12(7,8)9;;/h1-6,8-9,13H;1-9H3;1H;/q-2;;;+2
InChIKey	CCFGXRYKSYUWKT-UHFFFAOYSA-N
SMILES	P([Pd+2]1(NC2=CC=CC=C2C2=CC=CC=[C-]12)[Cl-])(C(C)(C)C)(C(C)(C)C)C(C)(C)C

SAFETY

Risk and Safety Statements

Symbol(GHS)	GHS07
Signal word	Warning
Hazard statements	H315-H319
Precautionary statements	P264-P280-P302+P352+P332+P313+P362+P364-P305+P351+P338+P337+P313
WGK Germany	3
HS Code	2931.90.6000

Chloro[(tri-tert-butylphosphine)-2-(2-aMinobiphenyl)]palladiuM(II) price More Price(5)

Manufacturer	Product number	Product description	CAS number	Packaging	Price	Updated	Buy
Sigma-Aldrich(India)	756482	P(t-Bu)3 Pd G2	1375325-71-5	250MG	₹5472.3	2022-06-14	Buy
Sigma-Aldrich(India)	756482	P(t-Bu)3 Pd G2	1375325-71-5	500MG	₹10977.9	2022-06-14	Buy
Sigma-Aldrich(India)	756482	P(t-Bu)3 Pd G2	1375325-71-5	2G	₹35808.6	2022-06-14	Buy
Sigma-Aldrich(India)	756482	P(t-Bu)3 Pd G2	1375325-71-5	5G	₹70418.4	2022-06-14	Buy
TCI Chemicals (India)	C2734	Chloro[(tri-tert-butylphosphine)-2-(2-aminobiphenyl)]palladium(II)	1375325-71-5	1G	₹20100	2022-05-26	Buy

Product number	Packaging	Price	Buy
756482	250MG	₹5472.3	Buy
756482	500MG	₹10977.9	Buy
756482	2G	₹35808.6	Buy
756482	5G	₹70418.4	Buy
C2734	1G	₹20100	Buy

Chloro[(tri-tert-butylphosphine)-2-(2-aMinobiphenyl)]palladiuM(II) Chemical Properties,Uses,Production

Uses

P(t-Bu)₃ Pd G2 (Chloro[(tri-tert-butylphosphine)-2-(2-aminobiphenyl)] palladium(II), Pd/P(t-Bu)₃) may be used as catalyst in the following studies:

Synthesis of sterically hindered biaryls (tetra-ortho-substituted), via cross-coupling reactions of aryl chlorides.
Stille cross-couplings reactions of aryl chloride.
Synthesis of chloropeptin I, via Stille cross-coupling reaction.
Heck reaction.
Negishi cross-coupling reactions.

Application

Catalyst for the Suzuki Coupling of brominated 2,1-borazaronaphthalenes and potassium organotrifluoroborates.

General Description

P(t-Bu)₃ Pd G2 (Chloro[(tri-tert-butylphosphine)-2-(2-aminobiphenyl)] palladium(II)) is a second generation (G2) precatalyst containing a biphenyl-based ligand. Product participates in various palladium catalyzed cross-coupling reactions, C-C, C-N and C-O bond formation reactions, and Suzuki-Miyaura coupling reactions. It generates active Pd catalyst at room temperature in the presence of weak phosphate or carbonate bases. It has been proposed as an active catalyst for use in Stille reactions of aryl halides (bromides and chlorides).

Chloro[(tri-tert-butylphosphine)-2-(2-aMinobiphenyl)]palladiuM(II) Preparation Products And Raw materials

Raw materials

Preparation Products

Chloro[(tri-tert-butylphosphine)-2-(2-aMinobiphenyl)]palladiuM(II) Suppliers

Global( 120)Suppliers

Supplier	Tel	Country	ProdList	Advantage	Inquiry
CLEARSYNTH LABS LTD.	+91-22-45045900	Hyderabad, India	6351	58	Inquiry
A.J Chemicals	91-9810153283	New Delhi, India	6124	58	Inquiry
TCI Chemicals (India) Pvt. Ltd.	1800 425 7889	New Delhi, India	6778	58	Inquiry
Wuhan Huahan Dingcheng New Material Technology Co., Ltd	+undefined-027-81388558 +undefined086-1878077615	China	342	58	Inquiry
XINXIANG RUNYU MATERIAL CO., LTD.	+86-13592593621; +8613592593621	China	432	58	Inquiry
Henan Fengda Chemical Co., Ltd	+86-371-86557731 +86-13613820652	China	20296	58	Inquiry
Shanghai Daken Advanced Materials Co.,Ltd	+86-371-66670886	China	16853	58	Inquiry
career henan chemical co	+86-0371-86658258 +8613203830695	China	29898	58	Inquiry
Shanghai Worldyang Chemical Co.,Ltd.	+86-021-56795779 +8613651600618	China	1080	58	Inquiry
SHANGHAI T&W PHARMACEUTICAL CO., LTD.	+86-021-61551413 +8618813727289	China	5738	58	Inquiry

Supplier	Advantage
CLEARSYNTH LABS LTD.	58
A.J Chemicals	58
TCI Chemicals (India) Pvt. Ltd.	58
Wuhan Huahan Dingcheng New Material Technology Co., Ltd	58
XINXIANG RUNYU MATERIAL CO., LTD.	58
Henan Fengda Chemical Co., Ltd	58
Shanghai Daken Advanced Materials Co.,Ltd	58
career henan chemical co	58
Shanghai Worldyang Chemical Co.,Ltd.	58
SHANGHAI T&W PHARMACEUTICAL CO., LTD.	58

1375325-71-5(Chloro[(tri-tert-butylphosphine)-2-(2-aMinobiphenyl)]palladiuM(II))Related Search:

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Chloro(tri-t-butylphosphine)(2'-amino-1,1'-biphenyl-2-yl)palladium(II) Chloro[(tri-tert-butylphosphine)-2'-amino[1,1'-biphenyl]-2-yl]palladium(II) Chloro[(tri-t-butylphosphine)-2-(2-aminobiphenyl)]palladium(II) Chloro[(tri-tert-butylphosphine)-2-(2-aminobiphenyl)]palladium(II) tBu3PPdG2 catalyst Chloro[(tri-tert-butylphosphine)-2-(2-aMinobiphenyl)]palladiuM(II) Chloro(tri-t-butylphosphine)(2'-amino-1,1'-biphenyl-2-yl)palladium(II), min. 98% P(t-Bu)3 Palladacycle Gen.2 [2'-(Amino-κN)[1,1'-biphenyl]-2-yl-κC]chloro[tris(1,1-dimethylethyl)phosphine]palladium Chloro(tri-tert-butylphosphine)(2'-aminobiphenylyl)palladium(II) Chloro[(tri-tert-butylphosphine)-2-(2-aMinobiphenyl)]palladiuM(II) in stock Factory Chloro[(tri-tert-butylphosphine)(2-aminobiphenyl-2-yl)palladium(II) Chloro[(tri-tert-butylphosphine)-2-(2-aminobiphenyl)]palladium(II)> Chloro[(tri-tert-butylphosphine)(2-aminobiphenyl-2-yl)palladium(II) / P(tBu)3 Pd G2 Palladium, [2'-(amino-κN)[1,1'-biphenyl]-2-yl-κC]chloro[tris(1,1-dimethylethyl)phosphine]- Chloro[(tri-tert-butylphosphine)-2-(2-aMinobiphenyl)]palladiuM(II) ISO 9001：2015 REACH Palladium, [2'-(amino-kN)[1,1'-biphenyl]-2-yl-kC]chloro[tris(1,1-dimethylethyl)phosphine)- Chloro(tri-t-butylphosphine)(2'-amino-1,1'-biphenyl-2-yl)pal... (2'-Amino-2-biphenylyl)(chloro)palladium - tris(2-methyl-2-propanyl)phosphine (1:1) P(tBu)3 Pd G2 / Chloro[(tri-tert-butylphosphine)(2-aminobiphenyl-2-yl)palladium(II) P(tBu)3 Pd G2 Chloro[(tri-tert-butylphosphine)-2-(2-aminobiphenyl)]palladium(II) [P(tbu)3 PD g2] Chloro(tri-t-butylphosphine)(2'-amino-1,1'-biphenyl-2-yl)palladium(II) 1375325-71-5 C24H37ClNPPd Pd