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Polyvinylidene fluoride

Polyvinylidene fluoride Structure
CAS No.
24937-79-9
Chemical Name:
Polyvinylidene fluoride
Synonyms
PVDF;POLY(VINYLIDENE FLUORIDE);poly(1,1-difluoroethylene);PVF2;MW~180000;MW~534000;MW~530000;PVDF/PVF2;PVDF resin;PVDF Powder
CBNumber:
CB6313270
Molecular Formula:
C2H2F2
Molecular Weight:
64.0340864
MOL File:
24937-79-9.mol
Modify Date:
2024/7/2 17:04:22

Polyvinylidene fluoride Properties

Melting point 166-170°C
Tg -38
Density 1.78 g/mL at 25 °C
vapor pressure 15 mm Hg ( 32 °C)
refractive index n20/D 1.42
storage temp. Sealed in dry,Room Temperature
solubility some polar solvents such as organic esters and amines: soluble
form powder
color White
Water Solubility Soluble in organic esters, dimethylacetamide and amines. Insoluble in water.
Stability Stable. Incompatible with strong oxidizing agents, silica.
EPA Substance Registry System Ethene, 1,1-difluoro-, homopolymer (24937-79-9)

SAFETY

Risk and Safety Statements

Symbol(GHS) 
GHS07
Signal word  Warning
Hazard statements  H315-H319-H335
Precautionary statements  P261-P305+P351+P338
Hazard Codes  C,T
Safety Statements  22-24/25
WGK Germany  3
TSCA  Yes
HS Code  3904698081
NFPA 704
1
0 0

Polyvinylidene fluoride price More Price(20)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich(India) P2563 Immobilon®-P Polyvinylidene difluoride membranes size 15?cm × 15?cm 24937-79-9 10EA ₹40370.7 2022-06-14 Buy
Sigma-Aldrich(India) 427152 Poly(vinylidene fluoride) average Mw ~180,000 by GPC, average Mn ~71,000, beads or pellets 24937-79-9 100G ₹13275.6 2022-06-14 Buy
Sigma-Aldrich(India) 427144 Poly(vinylidene fluoride) average Mw ~275,000 by GPC, average Mn ~107,000, pellets 24937-79-9 100G ₹13308.9 2022-06-14 Buy
Sigma-Aldrich(India) 182702 Poly(vinylidene fluoride) average Mw ~534,000 by GPC, powder 24937-79-9 5G ₹5440 2022-06-14 Buy
Sigma-Aldrich 347078 Poly(vinylidene fluoride) average Mw ~530,000, pellets 24937-79-9 100G ₹11577.3 2022-06-14 Buy
Product number Packaging Price Buy
P2563 10EA ₹40370.7 Buy
427152 100G ₹13275.6 Buy
427144 100G ₹13308.9 Buy
182702 5G ₹5440 Buy
347078 100G ₹11577.3 Buy

Polyvinylidene fluoride Chemical Properties,Uses,Production

Chemical Properties

Polyvinylidene fluoride (PVDF) is one of the most rigid and abrasion resistant of the melt-processible fluoropolymers. It has good chemical resistance, though hot sulfuric acid and hot amines can attack it. Like most fluoropolymers, PVDF is inherently flame retardant. It retains useful mechanical properties until 300 degrees F (149 degrees C).

Uses

Coatings, film, filter cloth, instrument linings, filtration membranes, pump parts and linings and valves.

Production Methods

PVDF, the addition polymer of 1,1,difluoroethene, is prepared by high-pressure free-radical polymerization in aqueous systems. It has applications in electric and electronic devices, as weather-resistant binders for exterior architectural finishes, and in a number of areas of the chemicalprocessing industry. The lack of additives and thus the exceedingly low contamination levels make the polymer useful in ultrapure water systems, for example, where high purity is necessary for construction materials.

Definition

ChEBI: A polymer composed of repeating 1,1-difluoroethyl units.

General Description

Poly(vinylidene fluoride) PVDF is a semi crystalline non-centrosymmetric polymer which exhibits piezo-, pyro- and ferroelectric properties. It is a linear polymer that shows permanent electric dipoles perpendicular to the direction of the molecular chain. These dipoles result from the difference in electronegativity between the atoms of hydrogen and fluorine with respect to carbon. Depending on the processing conditions, PVDF exhibits several different crystalline phases (α,β,γ,δ). The β phase of PVDF is the phase that exhibits the best ferroelectric and piezoelectric properties.

Industrial uses

The properties are generally similar to those ofthe other fluorinated resins: relative inertness,low dielectric constant, and thermal stability(up to about 150°C). The resins (PVF2 resins)are, however, stronger and less susceptible tocreep and abrasion than TFE and CTFE resins.
Applications of polyvinylidene fluoride aremainly as electrical insulation, piping, processequipment, and as a protective coating in theform of a liquid dispersion.

Polyvinylidene fluoride Preparation Products And Raw materials

Global( 237)Suppliers
Supplier Tel Country ProdList Advantage Inquiry
Otto Chemie Pvt. Ltd. +91 9820041841 Mumbai, India 5873 58 Inquiry
Alfa Aesar 1 800 209 7001 Maharashtra, India 6913 58 Inquiry
Sonata Impex 08048250476Ext 374 Mumbai, India 1 58 Inquiry
Swami Plast Industries 08048372485Ext 685 Ahmedabad, India 1 58 Inquiry
Nanochemazone Inc. 08048616195 Haryana, India 79 58 Inquiry
Plastic Abhiyanta 08048959010 Kolkata, India 1 58 Inquiry
Hebei Mojin Biotechnology Co., Ltd +86 13288715578 +8613288715578 China 12459 58 Inquiry
Hebei Yanxi Chemical Co., Ltd. +86-17531190177; +8617531190177 China 6011 58 Inquiry
Shaanxi Haibo Biotechnology Co., Ltd +undefined18602966907 China 1000 58 Inquiry
Hebei Jingbo New Material Technology Co., Ltd +8619931165850 China 1000 58 Inquiry

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