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4-Bromomethyl-7-methoxycoumarin

4-Bromomethyl-7-methoxycoumarin Structure
CAS No.
35231-44-8
Chemical Name:
4-Bromomethyl-7-methoxycoumarin
Synonyms
BMC;BR-MMC;BMC, Br-Mmc;-7-methoxy-2H-chromen-2-one;4-BROMOETHYL-7-METHOXYCOUMARIN;4-Bromomethyl-7-methoxycoumain;4-bromomethyl-7-hydroxycoumarin;7-Methoxy-4-bromomethylcoumarin;4-BROMOMETHYL-7-METHOXYCOUMARIN;4-BroMoMethyl-7-MethoxycouMarine
CBNumber:
CB6345309
Molecular Formula:
C11H9BrO3
Molecular Weight:
269.09
MOL File:
35231-44-8.mol
Modify Date:
2023/5/25 18:01:15

4-Bromomethyl-7-methoxycoumarin Properties

Melting point 213-215 °C (lit.)
Boiling point 385.3±42.0 °C(Predicted)
Density 1.552±0.06 g/cm3(Predicted)
storage temp. Keep in dark place,Inert atmosphere,2-8°C
solubility chloroform: soluble20mg/mL, clear, colorless to faintly yellow
form Powder and/or Chunks
color Off-white to light yellow or beige
Water Solubility insoluble
λmax 330 nm (MeOH)
BRN 187211
Stability Stable, but moisture and light-sensitive. Combustible. Incompatible with strong oxidizing agents.
Major Application Detection of nitrated explosives; measuring ultraviolet ray power; photoacid generators; polyurethane foams; photoresists silica nanoparticles
Biological Applications Analyzing/detecting carboxylic acids;analyzing/labeling fatty acids; detecting nitric oxide; detecting/separating bile acids; labeling pyrimidine nucleobases; anticancer agents; biomedical trace analysis; herbicides; as a substrate for measuring histone acetyltransferases (HATs) activity, peptidases activity, sirtuin activity
LogP 2.730 (est)
CAS DataBase Reference 35231-44-8(CAS DataBase Reference)

SAFETY

Risk and Safety Statements

Symbol(GHS) 
GHS07
Signal word  Warning
Hazard statements  H302-H315-H319-H335
Precautionary statements  P261-P264-P270-P301+P312-P302+P352-P305+P351+P338
Hazard Codes  Xi,Xn
Risk Statements  36/37/38-22
Safety Statements  26-36-37/39
RIDADR  1759
WGK Germany  3
HazardClass  8
PackingGroup  III
HS Code  29322090
NFPA 704
0
1 0

4-Bromomethyl-7-methoxycoumarin price More Price(4)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich(India) 235202 4-Bromomethyl-7-methoxycoumarin 97% 35231-44-8 1G ₹9780 2022-06-14 Buy
Sigma-Aldrich(India) 235202 4-Bromomethyl-7-methoxycoumarin 97% 35231-44-8 5G ₹37960 2022-06-14 Buy
TCI Chemicals (India) A5551 Br-Mmc (=4-Bromomethyl-7-methoxycoumarin) [for HPLC Labeling] 35231-44-8 1G ₹7400 2022-05-26 Buy
TCI Chemicals (India) A5551 Br-Mmc (=4-Bromomethyl-7-methoxycoumarin) [for HPLC Labeling] 35231-44-8 5G ₹16300 2022-05-26 Buy
Product number Packaging Price Buy
235202 1G ₹9780 Buy
235202 5G ₹37960 Buy
A5551 1G ₹7400 Buy
A5551 5G ₹16300 Buy

4-Bromomethyl-7-methoxycoumarin Chemical Properties,Uses,Production

Chemical Properties

Light Green-Yellow Crystals

Uses

4-Bromomethyl-7-methoxycoumarin can be used as fluorescent label for fatty acids. For derivatization, TLC and HPLC separation, and fluorometric analysis of a wide range of naturally occurring acids, including bile and thromboxane B2.

Purification Methods

The coumarin crystallises from boiling AcOH; the crystals are washed with AcOH, EtOH and dried in a vacuum; 1HNMR (TFA) 3.97s, 4.57s, 6.62s, 6.92-7.19m and 7.80d. [Secrist et al. Biochem Biophys Res Commun 45 1262 1971, Dünges Anal Chem 49 442 1977, Beilstein 18 III/IV 348.]

4-Bromomethyl-7-methoxycoumarin Preparation Products And Raw materials

Raw materials

Preparation Products

Global( 165)Suppliers
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chromsynth pvt ltd +919704220374 Hyderabad, India 244 58 Inquiry
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Chongqing Chemdad Co., Ltd +86-023-6139-8061 +86-86-13650506873 China 39916 58 Inquiry
Br-Mmc (=4-Bromomethyl-7-methoxycoumarin) [for HPLC Labeling] BR-MMC (=4-BROMOETHYL-7-METHOXYCOUMARIN) 4-BROMOMETHYL-7-METHOXYCOUMARIN [FOR HPLC LABELING] BMC, Br-Mmc 2H-1-Benzopyran-2-one, 4-(bromomethyl)-7-methoxy- 4-(Bromomethyl)-7-methoxychromen-2-one 4-(Bromomethyl)-7-methoxy-2H-1-benzopyran-2-one 7-Methoxy-4-bromomethylcoumarin 4-bromomethyl-7-hydroxycoumarin 4-(Bromomethyl)-7-methoxycoumarin,99% 4-(Bromomethyl)-7-methoxycoumarin,97% Br-Mmc (=4-Bromomethyl-7-methoxycoumarin) 4-Bromomethyl-7-methoxycoumarin,BMC, Br-Mmc 4-Bromomethyl-7-methoxycoumarin (BrMMC) [for HPLC Labeling] BROMOMETHYL-7-METHOXYCOUMARIN, 4-(RG) 4-(BroMoMethyl)-7-MethoxycouMarin, 97% 1GR 4-BroMoMethyl-7-MethoxycouMarine 4-BroMoMethyl-7-MethoxycouMarin 97% 4-(BroMoMethyl)-7-Methoxy-2H-chroMen-2-one BR-MMC 4-BROMOMETHYL-7-METHOXYCOUMARIN 4-BROMOETHYL-7-METHOXYCOUMARIN 4-BROMOMETHYL-7-METHOXYCOUMARIN, FOR FLU ORESCENCE 4-Bromomethyl-7-methoxycoumain 4-BROMOMETHYL-7-METHOXYCOUMARIN (BR-MMC) Br-Mmc (=4-Bromomethyl-7-methoxycoumarin)[for HPLC Labeling]> 4-Bromomethyl-7-methoxycoumarin ISO 9001:2015 REACH 4-(bromomethyl)-7-methoxy-2H-chromene-2-one -7-methoxy-2H-chromen-2-one BMC Br-Mmc (=4-Bromomethyl-7-methoxycoumarin), for HPLC,≥ 98.0% 35231-44-8 C11H9BrO3 ESTER HPLC Labeling Reagents Fluorescence Detection (HPLC Labeling Reagents) Carboxyl Group Labeling Reagents for Fluorescence HPLC Detection Fluorescent Labels Fluorescent Probes, Labels, Particles and Stains Other Fluorescent Labels Biochemicals and Reagents BioChemical Carboxyl Group Labeling Reagents for Fluorescence HPLC Fluorescence Detection (HPLC Labeling Reagents) HPLC Labeling Reagents Fluorescent Labels & Indicators Fluorescent Labels and Indicators Coumarins Analytical Chemistry