DIOXATHION

DIOXATHION Structure
CAS No.
78-34-2
Chemical Name:
DIOXATHION
Synonyms
co-nav;Delnav;Deltic;AC 528;Delcar;Kavadel;Navadel;Delnatex;Delnav I;Delnav II
CBNumber:
CB6355100
Molecular Formula:
C12H26O6P2S4
Molecular Weight:
456.54
MOL File:
78-34-2.mol
Modify Date:
2024/3/14 15:18:27

DIOXATHION Properties

Melting point -20°
Boiling point 240°C (estimate)
Density d426 1.257
refractive index nD20 1.5420
storage temp. 0-6°C
form liquid
Stability Stable. Incompatible with strong acids, alkalies. May react with iron or tin.
EPA Substance Registry System Dioxathion (78-34-2)

SAFETY

Risk and Safety Statements

Symbol(GHS) 
GHS06,GHS09
Signal word  Danger
Hazard statements  H300-H311-H330-H410
Precautionary statements  P264-P270-P301+P310-P321-P330-P405-P501-P280-P302+P352-P312-P322-P361-P363-P405-P501-P260-P271-P284-P304+P340-P310-P320-P403+P233-P405-P501-P273-P391-P501
Hazard Codes  T+,N
Risk Statements  24-26/28-50/53
Safety Statements  28-36/37-45-60-61
RIDADR  3018
OEB C
OEL TWA: 0.2 mg/m3 [skin]
RTECS  TE3350000
HazardClass  6.1(a)
PackingGroup  I
HS Code  29329990
Toxicity LD50 in female, male rats (mg/kg): 23, 43 orally; 63, 235 dermally (Gaines)

DIOXATHION Chemical Properties,Uses,Production

Chemical Properties

dark amber viscous liquid

Uses

Dioxathion is an organophosphate pesticide. It is used as an insecticide on livestock and acaricide on citrus fruits.

General Description

Tan liquid (technical grade is brown). Used for the control of insects and mites on grapes, citrus, walnuts, ornamentals, apples, pears, and quince. Also used as a spray or dip for the control of ticks, lice, hornfly, and sheep ked on cattle, goats, sheep, and hogs.

Air & Water Reactions

Insoluble in water. DIOXATHION is stable in water at a neutral pH.

Reactivity Profile

DIOXATHION is heat sensitive. DIOXATHION may react with iron or tin surfaces. DIOXATHION may be hydrolyzed by strong acids or alkalis. . Organophosphates are susceptible to formation of highly toxic and flammable phosphine gas in the presence of strong reducing agents such as hydrides. Partial oxidation by oxidizing agents may result in the release of toxic phosphorus oxides.

Health Hazard

Very toxic. Probable oral lethal dose for humans is 50-500 mg/kg or between 1 teaspoonful and 1 oz. for a 70 kg (150 lb.) person. It is a cholinesterase inhibitor. Death is primarily due to respiratory arrest arising from failure of the respiratory center, paralysis of respiratory muscles, intense bronchoconstriction, or all three.

Fire Hazard

Shock can shatter container, releasing contents. (Non-Specific -- Organophosphorus Pesticide, Liquid, n.o.s.) Container may explode in heat of fire. Fire may produce irritating or poisonous gases. Runoff from fire control water may give off poisonous gases. Runoff from fire control or dilution water may cause pollution. When heated to decomposition, DIOXATHION emits highly toxic fumes of oxides of nitrogen, phosphorus, and sulfur. Avoid alkali materials and heat. DIOXATHION is unstable to iron or tin surfaces and when mixed with certain carriers.

Safety Profile

Poison by ingestion, inhalation, skin contact, and intraperitoneal routes. Mutation data reported. A cholinesterase inhibitor. When heated to decomposition it emits very toxic fumes of POx, and SOx,. See also PARATHION

DIOXATHION Preparation Products And Raw materials

Raw materials

Preparation Products

2,3-p-Dioxane S,S-bis(O,O-diethylphosphoroithioate) 2,3-p-Dioxanedithiol S,S-bis(O,O-diethyl phosphorodithioate) 2,3-p-dioxanedithiols,s-bis(o,o-diethylphosphorodithioate) 2,3-p-dioxanes,s-bis(o,o-diethylphosphorodithioate) 2,3-p-dioxan-s,s’-bis(o,o-diaethyldithiophosphat) 2,3-P-Dioxan-S,S'-bis(O,O-diaethyldithiophosphat) A mixture consisting essentially of cis- and trans-S,S'-5,5'-p-dioxane-2,3-diyl bis(O,O-diethyl phosphorodithioate) Bis(dithiophosphate de O,O-diethyle) de S,S'-(1,4-dioxanne-2,3-diyle) bis(dithiophosphatedeo,o-diethyle)des,s’-(1,4-dioxanne-2,3-diyle) bis(dithiophosphatedeo,o-diethyle)des,s’-(dioxanne-1,4diyle-2,3) bis(dithiophosphatedeo,o-diethyle)des-s’(1,4-dioxanne-2,3-diyle)[french] co-nav Delnatex Delnav Delnav I Delnav II Deltic Dioxane phosphate dioxanephosphate Dioxation Dioxothion ENT 22,897 ENT 22897 ent22,897 Hercules ac528 herculesac528 Kavadel Navadel NCI-C00395 p-Dioxane-2,3-dithiol, S,S-diester with O,O-diethyl phosphorodithioate 1,4-dioxane-2,3-diyl O,O,O,O-tetraethyl di(phosphorodithioate) Dioxathion (ISO) dioxathion (ISO) 1,4-dioxan-2,3-diyl-O,O,O',O'-tetraethyl di(phosphorodithioate) p-dioxane-2,3-dithiol,s,s-diesterwitho,o-diethylphosphorodithioate p-Dioxane-2,3-diyl ethyl phosphorodithioate p-dioxane-2,3-diylethylphosphorodithioate Phosphorodithioic acid, S,S'-1,4-dioxane-2,3-diyl O,O,O',O'-tetraethyl ester Phosphorodithioic acid, S,S'-p-dioxane-2,3-diyl O,O,O',O'-tetraethyl ester phosphorodithioicacid,s,s’-1,4-dioxane-2,3-diylo,o,o’,o’-tetraethylester phosphorodithioicacid,s,s’-p-dioxane-2,3-diylo,o,o’,o’-tetraethylester phosphorodithioicacids,s’-1,4-dioxane-2,3-diylo,o,o’o’-tetraethylester DIOXATHIONE DIOXATHION, 100MG, NEAT delnav (former ussr,turkey) dioxathion (ansi,bsi,iso,esa) 1,4-Diossan-2,3-diyl-bis(O,O-dietil-ditiofosfato) 1,4-Dioxaan-2,3-diyl-bis(O,O-diethyl-dithiofosfaat) 1,4-dioxaan-2,3-diyl-bis(o,o-diethyl-dithiofosfaat)[dutch] 1,4-Dioxan-2,3-diyl bis(O,O-diethyl phosphorodithioate) 1,4-Dioxan-2,3-Diyl bis(O,O-diethyl phosphorothiolothionate) 1,4-Dioxan-2,3-diyl O,O,O',O'-tetraethyl di(phosphoromithioate) 1,4-Dioxan-2,3-diyl-bis(O,O-diaethyl-dithiophosphat) S,S'-P-DIOXANE-2,3-BIS[O,O-DIETHYL PHOSPHORODITHIOATE] S,S'-(P-DIOXANE-2,3-DIYL)O,O,O',O'-TETRAETHYL DI(PHOSPHORODITHIOATE) S,S'-(1,4-DIOXANE-2,3-DIYL)O,O,O',O'-TETRAETHYL DI(PHOSHORODITHIOATE) NAVADEL(R) Dioxathion Solution, 100ppm [(1,4-Dioxane-2,3-diyl)bisthio]bis(thiophosphonic acid O,O-diethyl)