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ChemicalBook > Product Catalog >Chemical Reagents >Organic reagents >Phosphine ligand >R(+)-2 2'-BIS-(DIPHENYLPHOSPHINO)-6 6'-&

R(+)-2 2'-BIS-(DIPHENYLPHOSPHINO)-6 6'-&

R(+)-2 2'-BIS-(DIPHENYLPHOSPHINO)-6 6'-& Structure
CAS No.
133545-16-1
Chemical Name:
R(+)-2 2'-BIS-(DIPHENYLPHOSPHINO)-6 6'-&
Synonyms
SL-A101-1;(R)-(+)-MeO-BIPHEP;97% (R)-MeO-BIPHEP;(R)-(6,6'-Dimethoxy-[1,1'-biphenyl];R(+)-2 2'-BIS-(DIPHENYLPHOSPHINO)-6 6'-&;R(+)-2 2'-BIS-(DIPHENYLPHOSPHINO)-6 6'-&(6,6'-Dimethoxy-2,2'-biphenyldiyl)bis(diphenylphosphine);(R)-2,2'-Bis(diphenylphosphino)-6,6'-dimethoxy-1,1'- bipheny;(R)-(+)-(6,6'-Dimethoxybiphenyl-2,2'-diyl)bis(diphenylphosph...;(R)-(+)-(6,6'-Dimethoxybiphenyl-2,2'-diyl)bis(diphenylphosphine)
CBNumber:
CB6502935
Molecular Formula:
C38H32O2P2
Molecular Weight:
582.62
MOL File:
133545-16-1.mol
MSDS File:
SDS
Modify Date:
2025/1/27 9:38:02
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R(+)-2 2'-BIS-(DIPHENYLPHOSPHINO)-6 6'-& Properties

Melting point 213-216 °C
alpha 101 º (C=0.3 IN TOLUENE)
Boiling point 651.1±55.0 °C(Predicted)
storage temp. under inert gas (nitrogen or Argon) at 2-8°C
form crystal
color off-white

SAFETY

Risk and Safety Statements

WGK Germany  3
F  8-10-23
HS Code  29319090

R(+)-2 2'-BIS-(DIPHENYLPHOSPHINO)-6 6'-& price More Price(7)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich(India) 29510 (R)-(+)-(6,6′-Dimethoxybiphenyl-2,2′-diyl)bis(diphenylphosphine) ≥97%, optical purity ee: ≥99% 133545-16-1 100MG ₹10153.85 2022-06-14 Buy
Sigma-Aldrich(India) 29510 (R)-(+)-(6,6′-Dimethoxybiphenyl-2,2′-diyl)bis(diphenylphosphine) ≥97%, optical purity ee: ≥99% 133545-16-1 500MG ₹31728.08 2022-06-14 Buy
Sigma-Aldrich(India) 29510 (R)-(+)-(6,6′-Dimethoxybiphenyl-2,2′-diyl)bis(diphenylphosphine) ≥97%, optical purity ee: ≥99% 133545-16-1 1G ₹95065.15 2022-06-14 Buy
Sigma-Aldrich(India) 29510 (R)-(+)-(6,6′-Dimethoxybiphenyl-2,2′-diyl)bis(diphenylphosphine) ≥97%, optical purity ee: ≥99% 133545-16-1 5G ₹274673.55 2022-06-14 Buy
Sigma-Aldrich(India) 29510 (R)-(+)-(6,6′-Dimethoxybiphenyl-2,2′-diyl)bis(diphenylphosphine) ≥97%, optical purity ee: ≥99% 133545-16-1 50G ₹1022193.93 2022-06-14 Buy
Product number Packaging Price Buy
29510 100MG ₹10153.85 Buy
29510 500MG ₹31728.08 Buy
29510 1G ₹95065.15 Buy
29510 5G ₹274673.55 Buy
29510 50G ₹1022193.93 Buy

R(+)-2 2'-BIS-(DIPHENYLPHOSPHINO)-6 6'-& Chemical Properties,Uses,Production

Chemical Properties

White powder

Uses

Ligand for ruthenium-catalyzed greener amine synthesis by enamine reduction with hydrogen gas.

Asymmetric Synthesis of (S)-3-Amino-4-methoxy-butan-1-ol by Way of Reductive Amination

Reactions

In many respects the catalytic profile of the MeOBIPHEP ligands is similar to that of other atropisomeric diphosphines such as binap and its many analogs. The nature of the PR2 group strongly influences the catalytic performance of the metal complexes. The rhodium and ruthenium MeO-BIPHEP catalysts are highly effective for the hydrogenation of various C=O, C=C and C=N bonds and several synthetically useful C-C coupling reactions.
Ru and Ir catalyzed dynamic kinetic resolution for the synthesis of hydroxy, amino acid derivatives.

  1. 1.Ru-catalyzed asymmetric hydrogenation of ketones and alkenes.
  2. Ir catalyzed enantioselective hydrogenation of heteroaromatic compounds.
  3. Conjugate addition using 2-heteroaryl titanates and zinc reagents.
  4. Enantio- and regioselective heck-type reaction of aryl boronic acids with 2,3-dihydrofuran
  5. Rhodium-catalyzed carbonyl Z-dienylation.
  6. Rhodium-catalyzed asymmetric 1,4 addition of arylboronic acids to maleimides and enones. Reactions of 133545-16-1

General Description

We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced for catalytic efficiency. Click here for more information.

R(+)-2 2'-BIS-(DIPHENYLPHOSPHINO)-6 6'-& Preparation Products And Raw materials

Raw materials

Preparation Products

R(+)-2 2'-BIS-(DIPHENYLPHOSPHINO)-6 6'-& Suppliers

Global( 79)Suppliers
Supplier Tel Country ProdList Advantage Inquiry
career henan chemical co +86-0371-86658258 +8613203830695 China 29858 58 Inquiry
Accela ChemBio Inc. +1-858-6993322 United States 19825 58 Inquiry
CONIER CHEM AND PHARMA LIMITED +8618523575427 China 49732 58 Inquiry
SHANGHAI T&W PHARMACEUTICAL CO., LTD. +86-021-61551413 +8618813727289 China 5738 58 Inquiry
Wuhan Fortuna Chemical Co., Ltd +86-027-59207850 China 5975 58 Inquiry
XINXIANG RUNYU MATERIAL CO., LTD. +86-13592593621; +8613592593621 China 410 58 Inquiry
changzhou huayang technology co., ltd +8615250961469 China 9691 58 Inquiry
Labnetwork lnc. +86-27-50766799 +8618062016861 China 19987 58 Inquiry
Hefei TNJ Chemical Industry Co.,Ltd. +86-0551-65418684 +8618949823763 China 25356 58 Inquiry
Hangzhou MolCore BioPharmatech Co.,Ltd. +86-057181025280; +8617767106207 China 49734 58 Inquiry
Supplier Advantage
career henan chemical co 58
Accela ChemBio Inc. 58
CONIER CHEM AND PHARMA LIMITED 58
SHANGHAI T&W PHARMACEUTICAL CO., LTD. 58
Wuhan Fortuna Chemical Co., Ltd 58
XINXIANG RUNYU MATERIAL CO., LTD. 58
changzhou huayang technology co., ltd 58
Labnetwork lnc. 58
Hefei TNJ Chemical Industry Co.,Ltd. 58
Hangzhou MolCore BioPharmatech Co.,Ltd. 58

133545-16-1(R(+)-2 2'-BIS-(DIPHENYLPHOSPHINO)-6 6'-&)Related Search:

R(+)-2 2'-BIS-(DIPHENYLPHOSPHINO)-6 6'-& (S)-(-)-5,5'-Bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole,min.98%(S)-SEGPHOS (R)-5,5'-Bis(diphenylphosphino)-2,2,2',2'-tetrafluoro-4,4'-bi-1,3-benzodioxole (R)-(6,6'-Dimethoxybiphenyl-2,2'-diyl)bis[bis(3,5-di-tert-butyl-4-methoxypheny (R)-CYCLOHEXYL SONIPHOS
(R)-C3-TUNEPHOS-RUTHENIUM COMPLEX (R)-(+)-2,2'-Bis(di-p-tolylphosphino)-6,6'-dimethoxy-1,1'-biphenyl,min.97% R-(+)-N,N'-DIMETHYL-7,7'-BIS(DI(3,5-XYLYL)PHOSPHINO)-3,3',4,4'-TETRAHYDRO-8,8'-BI-2H-1,4-BENZOXAZINE ISOPROPANOL ADDUCT (R)-(+)-5,5'-DICHLORO-6,6'-DIMETHOXY-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BIPHENYL (S)-(-)-2,2'-Bis[di(3,5-di-t-butylphenyl)phosphino]-6,6'-dimethoxy-1,1'-biphenyl,min.97%
(R)-C3-TUNEPHOS (S)-(+)-5,5'-Bis[di(3,5-di-t-butyl-4-methoxyphenyl)phosphino]-4,4'-bi-1,3-benzodioxole,min.98%(S)-DTBM-SEGPHOS (S)-(-)-2,2'-Bis[di(3,4,5-trimethoxyphenyl)phosphino]-6,6'-dimethoxy-1,1'-biphenyl,min.97% R-(+)-6,6'-BIS(DIPHENYLPHOSPHINO)-2,2',3,3'-TETRAHYDRO-5,5'-BI-1,4-BENZODIOXIN SOLPHOS SL-A001-1
(R)-METHYL SONIPHOS CHLORO[(R)-(+)-5,5'-DICHLORO-6,6'-DIMETHOXY-2,2'-BIS(DIPHENYL-PHOSPHINO)-1,1'-BIPHENYL](P-CYMENE)RUTHENIUM(II) CHLORIDE CH2CL2 ADDUCT (S)-(-)-2,2'-BIS[3'',4''-METHYLENEOXYPHENYLPHOSPHINO]-5,6-5',6'-DIMETHYLENEOXY-BIPHENYL
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R(+)-2 2'-BIS-(DIPHENYLPHOSPHINO)-6 6'-& (R)-(+)-(6,6'-Dimethoxybiphenyl-2,2'-diyl)bis(diphenylphosphine) (R)-(+)-2,2'-Bis(diphenylphosphino)-6,6'-dimethoxy-1,1'-biphenyl,min.97%(R)-MeO-BIPHEP (R)-(+)-MeO-BIPHEP, SL-A101-1, (R)-(+)-2,2μ-Bis(diphenylphosphino)-6,6μ-dimethoxy-1,1μ-biphenyl 97% (R)-MeO-BIPHEP (R)-(+)-2,2'-Bis(diphenylphosphino)-6,6'-diMethoxy-1,1'-biphenyl,(R)-MeO-BIPHEP (R)-(+)-MeO-BIPHEP SL-A101-1 (R)-(+)-(6,6'-Dimethoxybiphenyl-2,2'-diyl)bis(diphenylphosphine) >=97%, optical purity ee: >=99% (S)-(6,6,-dimethoxy-[1,1,-biphenyl]-2,2,-diyl)bis(diphenylphosphine) (R)-(+)-2,2'-Bis(diphenylphosphino)-6,6'-dimethoxy-1,1'-biphenyl,97% (R)-MeO-BIPHEP (6,6'-Dimethoxy-2,2'-biphenyldiyl)bis(diphenylphosphine) 1,1'-[(1R)-6,6'-Dimethoxy[1,1'-biphenyl]-2,2'-diyl]bis(1,1-diphenyl)-phosphine Phosphine, 1,1'-[(1R)-6,6'-dimethoxy[1,1'-biphenyl]-2,2'-diyl]bis[1,1-diphenyl- (R)-2,2'-Bis(diphenylphosphino)-6,6'-dimethoxy-1,1'- bipheny (R)-(+)-(6,6'-Dimethoxybiphenyl-2,2'-diyl)bis(diphenylphosph... R(+)-2 2'-BIS-(DIPHENYLPHOSPHINO)-6 6'-& (R)-(+)-2,2'-Bis(diphenylphosphino)-6,6'-dimethoxy-1,1'-biphenyl (R)-(+)-(6,6’-Dimethoxybiphenyl-2,2’-diyl)bis(diphenylphosphine) (R)-(6,6'-Dimethoxy-[1,1'-biphenyl]-2,2'-diyl)bis(diphenylphosphine) (6,6'-dimethoxy-[1,1'-biphenyl]-2,2'-diyl)bis(diphenylphosphine) (R)-(6,6'-Dimethoxy-[1,1'-biphenyl] (R)-(+)-(6,6′-Dimethoxybiphenyl-2,2′-diyl)bis(diphenylphosphine) 133545-16-1 C38H32O2P2 Chiral Phosphine MeOBIPHEP Series