(S)-(+)-5,5'-Bis[di(3,5-di-t-butyl-4-methoxyphenyl)phosphino]-4,4'-bi-1,3-benzodioxole,min.98%(S)-DTBM-SEGPHOS

(S)-(+)-5,5'-Bis[di(3,5-di-t-butyl-4-methoxyphenyl)phosphino]-4,4'-bi-1,3-benzodioxole,min.98%(S)-DTBM-SEGPHOS Structure
CAS No.
210169-40-7
Chemical Name:
(S)-(+)-5,5'-Bis[di(3,5-di-t-butyl-4-methoxyphenyl)phosphino]-4,4'-bi-1,3-benzodioxole,min.98%(S)-DTBM-SEGPHOS
Synonyms
(S)-DTBM-SEGPHOS;-4-methoxyphenyL;(S)-DTBM-SEGPHOS(R);(S)-(+)-DTBM-SEPGHOS;(S)-DTBM-SEGPHOS(R) >=94%;(S)-(+)-DTBM-SEGPHOS(regR);(S)-(+)-DTBM-SEGPHOS 200MG;)phosphino]-4,4'-bi-1,3-benzodioxoL;(S)-(+)-5,5'-Bis[di(3,5-di-tert-butyL;(S)-(+)-DTBM-SEGPHOS(regR)(S)-(+)-DTBM-SEGPHOS(regR)
CBNumber:
CB11181002
Molecular Formula:
C74H100O8P2
Molecular Weight:
1179.53
MOL File:
210169-40-7.mol
MSDS File:
SDS
Modify Date:
2023/10/19 17:32:03

(S)-(+)-5,5'-Bis[di(3,5-di-t-butyl-4-methoxyphenyl)phosphino]-4,4'-bi-1,3-benzodioxole,min.98%(S)-DTBM-SEGPHOS Properties

Melting point 126-128°C
Boiling point 987.3±65.0 °C(Predicted)
storage temp. under inert gas (nitrogen or Argon) at 2-8°C
form Powder
color off-white
CAS DataBase Reference 210169-40-7

SAFETY

Risk and Safety Statements

Symbol(GHS) 
GHS07
Signal word  Warning
Hazard statements  H302-H315-H319-H335
Precautionary statements  P261-P305+P351+P338
WGK Germany  3
HS Code  2932.99.7000

(S)-(+)-5,5'-Bis[di(3,5-di-t-butyl-4-methoxyphenyl)phosphino]-4,4'-bi-1,3-benzodioxole,min.98%(S)-DTBM-SEGPHOS price More Price(5)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich(India) 692980 (S)-DTBM-SEGPHOS® ≥94% 210169-40-7 50MG ₹2024.28 2022-06-14 Buy
Sigma-Aldrich(India) 692980 (S)-DTBM-SEGPHOS® ≥94% 210169-40-7 100MG ₹2662.95 2022-06-14 Buy
Sigma-Aldrich(India) 692980 (S)-DTBM-SEGPHOS® ≥94% 210169-40-7 1G ₹12243.08 2022-06-14 Buy
TCI Chemicals (India) D4500 (S)-(+)-DTBM-SEGPHOS® 210169-40-7 200MG ₹4400 2022-05-26 Buy
TCI Chemicals (India) D4500 (S)-(+)-DTBM-SEGPHOS® 210169-40-7 1G ₹9700 2022-05-26 Buy
Product number Packaging Price Buy
692980 50MG ₹2024.28 Buy
692980 100MG ₹2662.95 Buy
692980 1G ₹12243.08 Buy
D4500 200MG ₹4400 Buy
D4500 1G ₹9700 Buy

(S)-(+)-5,5'-Bis[di(3,5-di-t-butyl-4-methoxyphenyl)phosphino]-4,4'-bi-1,3-benzodioxole,min.98%(S)-DTBM-SEGPHOS Chemical Properties,Uses,Production

Uses

Catalytic ligand for:

  • Enantioselective synthesis of secondary allylic alcohols via enantioselective reductions of α,β-unsaturated ketones
  • Stereoselective preparation of cyclohexanone derivatives via rhodium-catalyzed rearrangement of allyl or allenic cyclobutanols
  • Cu-catalyzed asymmetric conjugate reduction of beta-substituted unsaturated phosphonates to give optically active beta-stereogenic alkylphosphonates
  • Asymmetric synthesis of cyclohexenones via Rh-catalyzed desymmetrization through enantioselective C-C bond activation and ring expansion of allenyl cyclobutanols
  • Enantioselective synthesis and crystal structure of P-stereogenic alkynylphosphine oxides by Rh-catalyzed [2+2+2] cycloaddition

(S)-(+)-5,5'-Bis[di(3,5-di-t-butyl-4-methoxyphenyl)phosphino]-4,4'-bi-1,3-benzodioxole,min.98%(S)-DTBM-SEGPHOS Preparation Products And Raw materials

Raw materials

Preparation Products

Global( 83)Suppliers
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TCI Chemicals (India) Pvt. Ltd. 1800 425 7889 New Delhi, India 6778 58 Inquiry
XINXIANG RUNYU MATERIAL CO., LTD. +86-13592593621; +8613592593621 China 428 58 Inquiry
Hebei Guanlang Biotechnology Co., Ltd. +86-19930503282 China 8828 58 Inquiry
Zhengzhou Alfa Chemical Co.,Ltd +8618530059196 China 12922 58 Inquiry
Labnetwork lnc. +86-27-50766799 +8618062016861 China 19994 58 Inquiry
Hebei Duling International Trade Co. LTD +8617333973358 China 15437 58 Inquiry
Weifang Wehibest Supply Chain Co.,Ltd +8613583620690 China 926 58 Inquiry
Zibo Hangyu Biotechnology Development Co., Ltd +86-0533-2185556 +8617865335152 China 10978 58 Inquiry
LEAPCHEM CO., LTD. +86-852-30606658 China 43348 58 Inquiry
Aladdin Scientific +1-+1(833)-552-7181 United States 57511 58 Inquiry
(S)-(+)-5,5'-Bis[di(3,5-di-t-butyl-4-methoxyphenyl)phosphino]-4,4'-bi-1,3-benzodioxole,min.98%(S)-DTBM-SEGPHOS (S)-(+)-5,5μ-Bis[di(3,5-di-tert-butyl-4-methoxyphenyl)phosphino]-4,4μ-bi-1,3-benzodioxole (S)-DTBM-SEGPHOS(R) (S)-DTBM-SEGPHOS (S)-5,5'-Bis[bis(3,5-di-tert-butyl-4-methoxyphenyl)phosphino]-4,4'-bibenzodioxole (S)-DTBM-SEGPHOS(R) >=94% Phosphine,[(4S)-[4,4'-bi-1,3-benzodioxole]-5,5'-diyl]bis[bis[3,5-bis(1,1-diMethylethyl)-4-Methoxyphenyl]- (S)-(+)-5,5'-Bis[di(3,5-di-t-butyl-4-methoxyphenyl)phosphino]-4,4'-bi-1,3-benzodioxole, min. 98% (S)-(+)-DTBM-SEGPHOS 200MG (S)-(+)-DTBM-SEGPHOS(regR) (S)-(+)-5,5'-Bis[di(3,5-di-t-butyl-4-methoxyphenyl)phosphino]-4,4'-bi-1,3-benzodioxole (S)-(+)-5,5'-Bis[di(3,5-di-t-butyl-4-methoxyphenyl)phosphino]-4,4'-bi-1,3-benzodioxole, min. 98% (S)-(+)-DTBM-SEGPHOS(R) 1,1'-(4S)-[4,4'-Bi-1,3-benzodioxole]-5,5'-diylbis[1,1-bis[3,5-bis(tert-butyl)-4-methoxyphenyl]phosphine] (S)-(+)-5,5'-Bis[di(3,5-di-t-butyl-4-Methoxyphenyl)phosphino]-4,4'-bi-1,3-benzodioxole (S)-(+)-DTBM-SEGPHOS (S)-(+)-4,4'-Bis[di(3,5-di-tert-butyl-4-methoxyphenyl)phosphino]-3,3'-bi(1,2-methylenedioxybenzene) (S)-(+)-DTBM-SEGPHOS(regR)(S)-(+)-DTBM-SEGPHOS(regR) (S)-(+)-5,5'-Bis[di(3,5-di-tert-butyL )phosphino]-4,4'-bi-1,3-benzodioxoL (S)-(+)-DTBM-SEPGHOS Phosphine, 1,1'-(4S)-[4,4'-bi-1,3-benzodioxole]-5,5'-diylbis[1,1-bis[3,5-bis(1,1-dimethylethyl)-4-methoxyphenyl]- -4-methoxyphenyL (S)-DTBM-SEGPHOS/(S)-(+)-5,5'-Bis[di(3,5-di-t-butyl-4-methoxyphenyl)phosphino]-4,4'-bi-1,3-benzodioxole (S)-5,5’-Bis[bis(3,5-di-tert-butyl-4-methoxyphenyl)phosphino]-4,4’-bibenzo[d][1,3]dioxole (S)-5,5'-Bis[di(3,5-di-tert-butyl-4-methoxyphenyl)phosphino]-4,4'-bi-1,3-benzodioxole 210169-40-7 Chiral Phosphine Segphos Series