ChemicalBook > Product Catalog >Chemical Reagents >Organic reagents >The polycyclic compound >(S)-(-)-2,2'-BIS(DI-P-TOLYLPHOSPHINO)-1,1'-BINAPHTHYL

(S)-(-)-2,2'-BIS(DI-P-TOLYLPHOSPHINO)-1,1'-BINAPHTHYL

CAS No.: 100165-88-6

Chemical Name:: (S)-(-)-2,2'-BIS(DI-P-TOLYLPHOSPHINO)-1,1'-BINAPHTHYL

Synonyms: (S)-T-BINAP;(S)-(−(R)-TOL-BINAP;(S)-TOL-BINAP;(S)-4-Me-BINAP;98% (S)-TolBINAP;(S)-(-)-2,2'-Bis(di-p-toL;BisdiptolylphosphinobinaphthylSTolBI;(S)-2,2'-BIS(DI-P-TOLYLPHOSPHINO)-1,1'-&;5-Bromo-37-fluorobenzylamine&hydrochloride

CBNumber:: CB0334534

Molecular Formula:: C48H40P2

Molecular Weight:: 678.78

MOL File:: 100165-88-6.mol

MSDS File:: SDS

Modify Date:: 2023/8/17 18:11:45

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(S)-(-)-2,2'-BIS(DI-P-TOLYLPHOSPHINO)-1,1'-BINAPHTHYL Properties

Melting point	252-256 °C
alpha	-160° (c 0.5, C6H6)
Boiling point	754.4±60.0 °C(Predicted)
storage temp.	Inert atmosphere,Room Temperature
form	Powder
color	White
optical activity	[α]20/D -156°, c = 0.5 in benzene
Water Solubility	Insoluble in water.
InChIKey	IOPQYDKQISFMJI-UHFFFAOYSA-N
CAS DataBase Reference	100165-88-6(CAS DataBase Reference)

SAFETY

Risk and Safety Statements

Symbol(GHS)

GHS07

Signal word

Warning

Hazard statements

H315-H319-H335

Precautionary statements

P261-P280a-P304+P340-P305+P351+P338-P405-P501a

Risk Statements

36/37/38

Safety Statements

26-36/37/39

WGK Germany

TSCA

HS Code

29333990

NFPA 704

	1
2		0

(S)-(-)-2,2'-BIS(DI-P-TOLYLPHOSPHINO)-1,1'-BINAPHTHYL price More Price(9)

Manufacturer	Product number	Product description	CAS number	Packaging	Price	Updated	Buy
Sigma-Aldrich(India)	668974	(S)-(−)-2,2′-Bis(di-p-tolylphosphino)-1,1′-binaphthyl 97%	100165-88-6	250MG	₹4643.93	2022-06-14	Buy
Sigma-Aldrich(India)	693030	(S)-T-BINAP	100165-88-6	500MG	₹5574.88	2022-06-14	Buy
Sigma-Aldrich(India)	668974	(S)-(−)-2,2′-Bis(di-p-tolylphosphino)-1,1′-binaphthyl 97%	100165-88-6	1G	₹18705.6	2022-06-14	Buy
ALFA India	ALF-042120-MC	(S)-(-)-2,2'-Bis(di-p-tolylphosphino)-1,1'-binaphthyl, 98%	100165-88-6	100mg	₹1463	2022-05-26	Buy
TCI Chemicals (India)	T3153	(S)-(-)-TolBINAP	100165-88-6	1G	₹3700	2022-05-26	Buy

Product number	Packaging	Price	Buy
668974	250MG	₹4643.93	Buy
693030	500MG	₹5574.88	Buy
668974	1G	₹18705.6	Buy
ALF-042120-MC	100mg	₹1463	Buy
T3153	1G	₹3700	Buy

(S)-(-)-2,2'-BIS(DI-P-TOLYLPHOSPHINO)-1,1'-BINAPHTHYL Chemical Properties,Uses,Production

Chemical Properties

White powder

Uses

(S)-(-)-2,2'-Bis(di-p-tolylphosphino)-1,1'-binaphthyl is chiral ligand widely used in asymmetric synthesis. It also used as excellent catalysts for asymmetric hydrogenation of alkenes and some cyclic anhydrides. BINAP is used in organic synthesis for enantioselective transformations catalyzed by its complexes of ruthenium, rhodium, and palladium

(S)-(-)-2,2'-BIS(DI-P-TOLYLPHOSPHINO)-1,1'-BINAPHTHYL Preparation Products And Raw materials

Raw materials

Nickel(II) chloride hexahydrate Ethanol N,N-Dimethylformamide (R)-(+)-1,1'-Bi-2-naphthol Toluene

Trichlorosilane Sodium Trifluoromethanesulfonic anhydride Triethylamine (S)-(-)-1,1'-Bi-2-naphthol

4-Bromotoluene Tetrahydrofuran Ethyl acetate 1,2-Dichloroethane Diethyl phosphite

Triphenylphosphine Pyridine Triethylenediamine Magnesium

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Preparation Products

(S)-(-)-2,2'-BIS(DI-P-TOLYLPHOSPHINO)-1,1'-BINAPHTHYL Suppliers

Global( 160)Suppliers

Supplier	Tel	Country	ProdList	Advantage	Inquiry
Evans Fine Chem	+91-9821340302 +91-9821340302	Maharashtra, India	286	58	Inquiry
Synthesis with Catalysts Pvt. Ltd.	+91-8920370240 +91-8527533338	Uttar Pradesh, India	5	58	Inquiry
SOLFYN INTERNATIONAL LLP	+91-9321772608 +91-9321772608	Mumbai, India	105	58	Inquiry
TCI Chemicals (India) Pvt. Ltd.	1800 425 7889	New Delhi, India	6778	58	Inquiry
Alfa Aesar	1 800 209 7001	Maharashtra, India	6913	58	Inquiry
XINXIANG RUNYU MATERIAL CO., LTD.	+86-13592593621; +8613592593621	China	431	58	Inquiry
Hebei Mojin Biotechnology Co., Ltd	+8613288715578	China	12458	58	Inquiry
Shanghai Daken Advanced Materials Co.,Ltd	+86-371-66670886	China	16209	58	Inquiry
Henan Tianfu Chemical Co.,Ltd.	+86-0371-55170693 +86-19937530512	China	21669	55	Inquiry
ATK CHEMICAL COMPANY LIMITED	+undefined-21-51877795	China	32760	60	Inquiry

Supplier	Advantage
Evans Fine Chem	58
Synthesis with Catalysts Pvt. Ltd.	58
SOLFYN INTERNATIONAL LLP	58
TCI Chemicals (India) Pvt. Ltd.	58
Alfa Aesar	58
XINXIANG RUNYU MATERIAL CO., LTD.	58
Hebei Mojin Biotechnology Co., Ltd	58
Shanghai Daken Advanced Materials Co.,Ltd	58
Henan Tianfu Chemical Co.,Ltd.	55
ATK CHEMICAL COMPANY LIMITED	60

(S)-(-)-2,2'-BIS(DI-P-TOLYLPHOSPHINO)-1,1'-BINAPHTHYL Spectrum

(S)-(-)-2,2'-BIS(DI-P-TOLYLPHOSPHINO)-1,1'-BINAPHTHYL(100165-88-6)¹HNMR (S)-(-)-2,2'-BIS(DI-P-TOLYLPHOSPHINO)-1,1'-BINAPHTHYL(100165-88-6)³¹PNMR

100165-88-6((S)-(-)-2,2'-BIS(DI-P-TOLYLPHOSPHINO)-1,1'-BINAPHTHYL)Related Search:

(R)-(+)-TolBINAP Bis(diphenylphosphino)methane 2,2'-BIS(DI-P-TOLYLPHOSPHINO)-1,1'-BINAPHTHYL,rac-2,2'-Bis(di-p-tolylphosphino)-1,1'-binaphthyl Chloro[(S)-(-)-2,2'-bis(di-p-tolylphosphino)-1,1'-binaphthyl](p-cymene)ruthenium(II)chloride (S)-(-)-2,2'-BIS(DI-P-TOLYLPHOSPHINO)-1,1'-BINAPHTHYL

(S)-(-)-2,2'-Bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl (R)-(+)-2,2'-Bis(diphenylphosphino)-1,1'-binaphthyl 1,1'-BINAPHTHYL Dichloro{(S)-(-)-2,2'-bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl}[(1S,2S)-(-)-1,2-diphenylethylenediamine]ruthenium(II) Dimethylammoniumdichlorotri(mu-chloro)bis[(S)-(-)-2,2'-bis(di-p-tolylphosphino)-1,1'-binaphthyl]diruthenate(II)

Diacetato[(S)-(-)-2,2'-bis(di-p-tolylphosphino)-1,1'-binaphthyl]ruthenium(II) Dichloro{(R)-(+)-2,2'-bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl}[(1R,2R)-(+)-1,2-diphenylethylenediamine]ruthenium(II) Diacetato{(S)-(-)-2,2'-bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl}ruthenium(II) Chloro{(R)-(+)-2,2'-bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl}(p-cymene)ruthenium(II)chloride Dichloro{(R)-(+)-2,2'-bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl}[(2R)-(-)-1,1-bis(4-methoxyphenyl)-3-methyl-1,2-butanediamine]ruthenium(II)

Dichloro{(S)-(-)-2,2'-bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl}[(2S)-(+)-1,1-bis(4-methoxyphenyl)-3-methyl-1,2-butanediamine]ruthenium(II) Chloro[(R)-(+)-2,2'-bis(di-p-tolylphosphino)-1,1'-binaphthyl](p-cymene)ruthenium(II)chloride Dimethylammoniumdichlorotri(mu-chloro)bis[(R)-(+)-2,2'-bis(di-p-tolylphosphino)-1,1'-binaphthyl]diruthenate(II)

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(S)-TOL-BINAP (R)-TOL-BINAP (S)-(-)-2,2'-BIS(DI-P-TOLYLPHOSPHINO)-1,1'-BINAPHTHYL (R)-(+)-2,2'-BIS(DI-P-TOLYLPHOSPHINO)1,1-BINAPHTHYL (S)-2,2'-BIS(DI-P-TOLYLPHOSPHINO)-1,1'-& (S)-(-)-2,2'-Bis(di-p-tolylphosphino)-1,1'-binaphthyl, 98+% (S)-(-)-2,2'-Bis(di-p-tolylphosphino)-1,1'-binaphthyl,98%(S)-Tol-BINAP (S)-(-)-2,2''-BIS(DI-P-TOLYLPHOSPHINO)-1,1''-BINAPHTHYL (S)-TOL-BINAP (S)-(-)-2,2''-Bis-[bis-(p-tolylphosphino)]-1,1''-binaphthyl PHOSPHINE, 1,1''-(1S)-[1,1''-BINAPHTHALENE]-2,2''-DIYLBIS[1,1-BIS(4-METHYLPHENYL)- (S)-T-BINAP (S)-Tol-BINAP, (S)-(-)-2,2μ-p-tolyl-phosphino)-1,1μ-binaphthyl BisdiptolylphosphinobinaphthylSTolBI (S)-(-)-2,2'-Bis(di-p-tolylphosphino)-1,1'-binaphthyl, (S)-p-Tol-BINAP (S)-(-)-2,2'-Bis(di-p-tolylphosphino)-1,1'-binaphthyl, 99% (S)-p-Tol-BINAP (S)-2,2'-Bis[bis(4-methylphenyl)phosphino]-1,1'-binaphthyl (S)-4-Me-BINAP 1,1'-(1S)-[1,1'-Binaphthalene]-2,2'-diylbis[1,1-bis(4-methylphenyl)phosphine 98% (S)-TolBINAP (S)-(-)-2,2'-Bis(di-p-tolylphosphino)-1,1'-binaphthyl 97% (R)-2,2,-bis(di-p-tolylphosphino)-1,1,-binaphthalene 1,1'-(1S)-[1,1'-Binaphthalene]-2,2'-diylbis[bis(4- methylphenyl)phosphine] (S)-2,2'-Bis(di-p-tolylphosphino)-1,1'-binaphthalene (S)-(-)-2,2'-Bis(di-p-toL Phosphine, (1S)-[1,1'-binaphthalene]-2,2'-diylbis[bis(4-methylphenyl)- High purity CAS 100165-88-6 (S)-(-)-2,2'-BIS(DI-P-TOLYLPHOSPHINO)-1,1'-BINAPHTHYL in stock 5-Bromo-37-fluorobenzylamine&hydrochloride (S)-(− )-2,2′-Bis(di-p-tolylphosphino)-1,1′-binaphthyl (S)-(-)-2,2'-Bis(di-p-tolylphosphino)-1,1'-binaphthyl 1,1'-(1S)-[1,1'-Binaphthalene]-2,2'-diylbis[1,1-bis(4-methylphenyl)phosphine 100165-88-6 BINAPs Asymmetric Synthesis Privileged Ligands Chiral Catalysts, Ligands, and Reagents BINAP Series Chiral Phosphine