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(R)-(+)-1,1'-Bi-2-naphthol

CAS No.: 18531-94-7

Chemical Name:: (R)-(+)-1,1'-Bi-2-naphthol

Synonyms: (R)-BINOL;(R,S)-BINOL;1,1'-BINAPHTHYL-2,2'-DIOL;(+)-BINOL;AKOS 90560;DI-B-NAPHTHOL;BI-2-NAPHTHOL;(R)-(+)-BINOL;AURORA KA-7212;2,2'-DINAPHTHOL

CBNumber:: CB3380426

Molecular Formula:: C20H14O2

Molecular Weight:: 286.32

MOL File:: 18531-94-7.mol

MSDS File:: SDS

Modify Date:: 2024/4/28 16:56:32

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(R)-(+)-1,1'-Bi-2-naphthol Properties

Melting point	215-218 °C
alpha	35.5 º (c=1, THF)
Boiling point	388.69°C (rough estimate)
Density	1.301
refractive index	36.0 ° (C=1, THF)
storage temp.	Store below +30°C.
solubility	dioxane: 50 mg/mL, clear
form	Powder
pka	8.29±0.50(Predicted)
color	white to off-white
optical activity	[α]21/D +34°, c = 1 in THF
Water Solubility	Insoluble in water. Solubility in THF within almost transparency). Soluble in dioxane 50 mg/mL.
Merck	14,1226
BRN	3616837
CAS DataBase Reference	18531-94-7(CAS DataBase Reference)

SAFETY

Risk and Safety Statements

Symbol(GHS)

GHS06

Signal word

Danger

Hazard statements

H301-H315-H319

Precautionary statements

P301+P310+P330-P302+P352-P305+P351+P338

Hazard Codes

T,Xi

Risk Statements

25-36-36/37/38

Safety Statements

26-45-24/25-36

RIDADR

UN 2811 6.1/PG 3

WGK Germany

RTECS

DU3106100

TSCA

HazardClass

6.1

PackingGroup

III

HS Code

29071590

Toxicity

LD50 orally in Rabbit: 113 mg/kg

NFPA 704

	1
2		0

(R)-(+)-1,1'-Bi-2-naphthol price More Price(10)

Manufacturer	Product number	Product description	CAS number	Packaging	Price	Updated	Buy
Sigma-Aldrich(India)	8.14774	(R)-(+)-1,1′-Binaphthyl-2,2′-diol for synthesis	18531-94-7	1G	₹2260	2022-06-14	Buy
Sigma-Aldrich(India)	246948	(R)-(+)-1,1′-Bi(2-naphthol) 99%	18531-94-7	1G	₹3961.95	2022-06-14	Buy
Sigma-Aldrich(India)	8.14774	(R)-(+)-1,1′-Binaphthyl-2,2′-diol for synthesis	18531-94-7	10G	₹4910.01	2022-06-14	Buy
Sigma-Aldrich(India)	246948	(R)-(+)-1,1′-Bi(2-naphthol) 99%	18531-94-7	5G	₹10944.08	2022-06-14	Buy
Sigma-Aldrich(India)	246948	(R)-(+)-1,1′-Bi(2-naphthol) 99%	18531-94-7	10G	₹14137.45	2022-06-14	Buy

Product number	Packaging	Price	Buy
8.14774	1G	₹2260	Buy
246948	1G	₹3961.95	Buy
8.14774	10G	₹4910.01	Buy
246948	5G	₹10944.08	Buy
246948	10G	₹14137.45	Buy

(R)-(+)-1,1'-Bi-2-naphthol Chemical Properties,Uses,Production

Chemical Properties

white to light yellow crystal powde

Uses

Chiral binapthol imminium salt precursor. Salts were used for an asymmetric epoxidation of olefins.

Purification Methods

Dissolve it in cold 2.5N NaOH, extract with CH2Cl2, and acidify with 5% HCl. Collect the white precipitate and recrystallise it from aqueous EtOH and dry it in a vacuum [Akimoto & Yamada Tetrahedron 27 5999 1971]. It is optically stable in dioxane-water (100o/24hours). Racemisation: 72% in 1.2N HCl at 100o/24hours and 68% in 0.67M KOH in BuOH at 118o/23hours [Kyba et al. J Am Chem Soc 95 2693 1973]. It has also been crystallised from *C6H6 (solubility is 1%) using Norite or aqueous EtOH after chromatography through silica gel, eluting with Me2CO/*C6H6. [Kyba et al. J Org Chem 42 4173 1977; see also Brussee & Jansen Tetrahedron Lett 24 3261 1983, Akimoto & Yamada Tetrahedron 27 5999 1971, Beilstein 6 IV 7020.]

(R)-(+)-1,1'-Bi-2-naphthol Preparation Products And Raw materials

Raw materials

Copper(II) chloride dihydrate Ethanol Toluene Phosphorus oxychloride Triethylamine

(R)-(+)-1-Phenylethylamine L-1-Phenylethylamine Iron chloride hexahydrate Tetrahydrofuran Benzene

Ethyl acetate Dichloromethane 2-Naphthol 1,1'-Bi-2-naphthol

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Preparation Products

(S)-(-)-2,2'-BIS(DI-P-TOLYLPHOSPHINO)-1,1'-BINAPHTHYL (3S,4R)-4-Acetoxy-3-[(R)-1-(tert-butyldimethylsilyloxy)ethyl]azetidin-2-one (R)-(+)-2,2'-Bis(diphenylphosphino)-1,1'-binaphthyl (R)-(-)-6,6'-Dibromo-1,1'-bi-2-naphthol (R)-(+)-TolBINAP

R-3,3'-Bis(phenyl)-1,1'-bi-2-naphthol

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(R)-(+)-1,1'-Bi-2-naphthol Suppliers

Global( 461)Suppliers

Supplier	Tel	Country	ProdList	Advantage	Inquiry
SOLFYN INTERNATIONAL LLP	+91-9321772608 +91-9321772608	Mumbai, India	105	58	Inquiry
Evans Fine Chem	+91-9821340302 +91-9821340302	Maharashtra, India	286	58	Inquiry
JSK Chemicals	+919879767970	Gujarat, India	3756	58	Inquiry
A.J Chemicals	91-9810153283	New Delhi, India	6124	58	Inquiry
TCI Chemicals (India) Pvt. Ltd.	1800 425 7889	New Delhi, India	6778	58	Inquiry
Alfa Aesar	1 800 209 7001	Maharashtra, India	6913	58	Inquiry
Ms Life Sciences	08048372386Ext 826	Hyderabad, India	341	58	Inquiry
Avra Synthesis Pvt Ltd	+914027175796	New Delhi, India	1606	30	Inquiry
Anand Agencies	91-20-24454597	Maharashtra, India	2337	58	Inquiry
Synthesis With Catalysts Private Limited	08048250110Ext 908	Delhi, India	59	58	Inquiry

Supplier	Advantage
SOLFYN INTERNATIONAL LLP	58
Evans Fine Chem	58
JSK Chemicals	58
A.J Chemicals	58
TCI Chemicals (India) Pvt. Ltd.	58
Alfa Aesar	58
Ms Life Sciences	58
Avra Synthesis Pvt Ltd	30
Anand Agencies	58
Synthesis With Catalysts Private Limited	58

(R)-(+)-1,1'-Bi-2-naphthol Spectrum

(R)-(+)-1,1'-Bi-2-naphthol(18531-94-7)FT-IR (R)-(+)-1,1'-Bi-2-naphthol(18531-94-7)IR (R)-(+)-1,1'-Bi-2-naphthol(18531-94-7)Raman

18531-94-7((R)-(+)-1,1'-Bi-2-naphthol)Related Search:

p-Naphtholbenzein Phenmedipham Terbinafine hydrochloride 1-Naphthol (n)-1,1'-bi(2-naphthol),(±)-1,1'-Bi(2-naphthol),99%,(+/-)-1,1'-BI(2-NAPHTHOL),(+/-)-1,1A-Bi-2-naphthol

2-Naphthol ALPHA-NAPHTHOLBENZEIN (S)-(-)-1,1'-Bi-2-naphthol,S-(-)-1,1'-Bi-2-naphthol,99%(S)-BINOL,(S)-1,1 -BI-2-NAPHTHOL ***REVERSE***,(S)-(−)-1,1'-Bi(2-naphthol) (R)-(+)-2,2'-DIMETHOXY-1,1'-BINAPHTHYL (S)-(+)-6'-DIBROMO-1,1'-BI-2-NAPHTHOL,6,6''-DIBROMO-1,1''-BI-2-NAPHTHOL 95+%,racemic-6,6'-Dibromo-1,1'-bi-2-naphthol,min.98%

(S)-2'-Methoxy-[1,1']binaphthalenyl-2-ol 1,1'-Binaphthyl-2,2'-diyl hydrogenphosphate (R)-(-)-1,1'-Binaphthol-2,2'-bis(trifluoromethanesulfonate) (R)-(+)-3,3'-Dibromo-1,1'-bi-2-naphthol,99% (S)-(+)-1,1'-Bi-2-naphthyl ditosylate

(-1,1'-Bi-2-Naphthol Deacetate (S)-1,1μ-Binaphthalene-2,2μ-diyl bis(trifluoromethanesulfonate), (S)-1,1μ-Bi(2-naphthol) bis(trifluoromethanesulfonate) (R)-1,1'-BI-2-NAPHTHOL DIBENZOATE

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(R)-(+)-BI-2-NAPHTHOL (R)-[1,1']-Binaphth-2-ol, (R)-BINOL (+)-2,2μ-Dihydroxy-1,1μ-dinaphthyl, (R)-(+)-1,1μ-Binaphthalene-2,2μ-diol, (R)-BINOL (R)-(+)-1,1'-Bi-2-naphthol 99% [aR,(+)]-1,1'-Binaphthalene-2,2'-diol [aR,(+)]-Dinaphthol R-(+)-1_Bi-2-naphthol (R)-(+)-1,1'-Bi-2-na (1R)-2,2'-Dihydroxy-[1,1']-binaphthyl (1R)-1,1'-Binaphthalene-2,2'-diol, (R)-BINOL (R)-(+)-BINOL (R)-(+)-2,2'-Dihydroxy-1,1'-binaphthyl (R)-(+)-1,1''-BINAPHTHYL-2,2''-DIOL FOR SY e: (R)-(+)-1,1'-Bi-2-naphtho (R)-1,1'-Binaphthalene-2,2'-diol, (R)-BINOL (R)-(+)-1,1'-Bi-2-naphthol (R)-(+)-2,2'-Dihydroxy-1,1'-dinaphthyl (R)-(+)-1,1'-Bi-2-naphthol, >=99.5% Dihydroxydinaphthylwhitepowder (1R)- [1,1'-Binaphthalene]-2,2'-diol (R)-(+)-1,1'-Bi-2-naphthol DI-B-NAPHTHOL AURORA KA-7212 BI-2-NAPHTHOL (-)-2,2'-DIHYDROXY-1,1'-DINAPHTHYL (+)-2,2'-DIHYDROXY-1,1'-DINAPHTHYL (+/-)-2,2'-DIHYDROXY-1,1'-DINAPHTHYL 2,2'-DIHYDROXY-1,1'-DINAPHTHYL 2,2'-DINAPHTHOL (R)-(+)-1,1'-BIS(2-NAPHTHOL) (R)-(+)-1,1'-BINAPHTHYL-2,2'-DIOL (R)-[1,1]-BINAPHTHALENYL-2,2'-DIOL R(+)-1,1'-BINAPHTHALENE-2,2'-DIOL (R)-(+)-1,1'-BI(2,2'-NAPHTHOL) (R)-(+)-1,1'-BI-2-NAPHTHOL (R)-(+)-1,1-BI-2-NAPHTHOL (R)-1,1'-BI-2-NAPHTHOL R-1,1-BI-2-NAPHTHOL R-(+)-2,2'-DIHYDROXY-1,1'-DINAPHTHYL (R)-(+)-2,2'-DIHYDROXY-1,1'-BINAPHTHYL (R)-(+)-2,2'-DIHYDROXY-1,1-BINAPHTHYL (R)-(+)-BINOL (S)-(-)-1,1'-BI(2,2'-NAPHTHOL) (S)-[1,1'-BINAPHTHALENE]-2,2'-DIOL S(-)-1,1'-BINAPHTHALENE-2,2'-DIOL (S)-(-)-1,1'-BINAPHTHYL-2,2'-DIOL (S)-[1,1]-BINAPHTHALENYL-2,2'-DIOL S-(-)-2,2'-DIHYDROXY-1,1'-DINAPHTHYL [1,1']BINAPHTHALENYL-2,2'-DIOL 1,1'-BI-2,2'-NAPHTHOLS (+/-)-1,1'-BINAPHTHALENE-2,2'-DIOL AKOS 90560 (R)-(+)-1,1’-bi-2-nanphthol (R)-(+)-1,1'-BI-2-NAPHTHOL, 99% (99% EE/ R-(+)-1,1'-Binaphthyl-2.2'-dio R-(+)-1,1'-BI-2-NAPHTHOL/ (R)-(+)BINOL R-(+)-1,1'-Bi-2-naphthol,99%(R)-BINOL 1,1-Binaphthalene-2,2-diol, (1R)- (R)-(+)-1,1'-Bi-2-naphtol (R)-(+)-1,1''-BI(2-NAPTHOL)