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(S)-(-)-1,1'-Bi-2-naphthol

CAS No.: 18531-99-2

Chemical Name:: (S)-(-)-1,1'-Bi-2-naphthol

Synonyms: (S)-BINOL;(S)-1,1'-BI-2-NAPHTHOL;(S)-(-)-BINOL;(R,S)-BINOL;S-BINAPHTHOL;1,1'-BINAPHTHYL-2,2'-DIOL;(-)-Binol;AKOS 90560;98.0%(T&BI-2-NAPHTHOL

CBNumber:: CB6380427

Molecular Formula:: C20H14O2

Molecular Weight:: 286.32

MOL File:: 18531-99-2.mol

MSDS File:: SDS

Modify Date:: 2023/12/24 21:24:35

Request For Quotation

(S)-(-)-1,1'-Bi-2-naphthol Properties

Melting point	215-218 °C
alpha	-35.5 º (c=1, THF)
Boiling point	388.69°C (rough estimate)
Density	1 g/cm³
refractive index	-36.0 ° (C=1, THF)
storage temp.	Keep in dark place,Inert atmosphere,Room temperature
solubility	dioxane: 50 mg/mL, clear
form	Crystals or Crystalline Powder
pka	8.29±0.50(Predicted)
color	White to light gray
optical activity	[α]22/D 34°, c = 1 in THF
Merck	14,1226
BRN	3592999
CAS DataBase Reference	18531-99-2(CAS DataBase Reference)

SAFETY

Risk and Safety Statements

Symbol(GHS)

GHS07

Signal word

Warning

Hazard statements

H315-H319

Precautionary statements

P302+P352-P305+P351+P338

Hazard Codes

T,Xi

Risk Statements

25-36-36/37/38

Safety Statements

26-45-24/25-36

RIDADR

UN 2811 6.1/PG 3

WGK Germany

RTECS

DU3106100

TSCA

HazardClass

6.1

PackingGroup

III

HS Code

29072990

NFPA 704

	1
2		0

(S)-(-)-1,1'-Bi-2-naphthol price More Price(10)

Manufacturer	Product number	Product description	CAS number	Packaging	Price	Updated	Buy
Sigma-Aldrich(India)	246956	(S)-(−)-1,1′-Bi(2-naphthol) 99%	18531-99-2	1G	₹3290.8	2022-06-14	Buy
Sigma-Aldrich(India)	246956	(S)-(−)-1,1′-Bi(2-naphthol) 99%	18531-99-2	25G	₹4817.13	2022-06-14	Buy
Sigma-Aldrich(India)	246956	(S)-(−)-1,1′-Bi(2-naphthol) 99%	18531-99-2	5G	₹5282.6	2022-06-14	Buy
ALFA India	ALF-L08423-14	(S)-(-)-1,1'-Bi(2-naphthol), 99%	18531-99-2	25g	₹13272	2022-05-26	Buy
ALFA India	ALF-L08423-06	(S)-(-)-1,1'-Bi(2-naphthol), 99%	18531-99-2	5g	₹9218	2022-05-26	Buy

Product number	Packaging	Price	Buy
246956	1G	₹3290.8	Buy
246956	25G	₹4817.13	Buy
246956	5G	₹5282.6	Buy
ALF-L08423-14	25g	₹13272	Buy
ALF-L08423-06	5g	₹9218	Buy

(S)-(-)-1,1'-Bi-2-naphthol Chemical Properties,Uses,Production

Chemical Properties

white to light yellow crystal powde

Uses

Chiral ligand.

Purification Methods

Dissolve it in cold 2.5N NaOH, extract with CH2Cl2, and acidify with 5% HCl. Collect the white precipitate and recrystallise it from aqueous EtOH and dry it in a vacuum [Akimoto & Yamada Tetrahedron 27 5999 1971]. It is optically stable in dioxane-water (100o/24hours). Racemisation: 72% in 1.2N HCl at 100o/24hours and 68% in 0.67M KOH in BuOH at 118o/23hours [Kyba et al. J Am Chem Soc 95 2693 1973]. It has also been crystallised from *C6H6 (solubility is 1%) using Norite or aqueous EtOH after chromatography through silica gel, eluting with Me2CO/*C6H6. [Kyba et al. J Org Chem 42 4173 1977; see also Brussee & Jansen Tetrahedron Lett 24 3261 1983, Akimoto & Yamada Tetrahedron 27 5999 1971, Beilstein 6 IV 7020.]

(S)-(-)-1,1'-Bi-2-naphthol Preparation Products And Raw materials

Raw materials

Copper(II) chloride dihydrate Ethanol Toluene Phosphorus oxychloride Triethylamine

(R)-(+)-1-Phenylethylamine L-1-Phenylethylamine Iron chloride hexahydrate Tetrahydrofuran Benzene

Ethyl acetate Dichloromethane 2-Naphthol

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Preparation Products

(S)-(-)-2,2'-BIS(DI-P-TOLYLPHOSPHINO)-1,1'-BINAPHTHYL (S)-(-)-2,2'-Bis(diphenylphosphino)-1,1'-binaphthyl (R)-(+)-2,2'-BIS(METHOXYMETHOXY)-1,1'-BINAPHTHYL

(S)-(-)-1,1'-Bi-2-naphthol Suppliers

Global( 467)Suppliers

Supplier	Tel	Country	ProdList	Advantage	Inquiry
JSK Chemicals	+919879767970	Gujarat, India	3756	58	Inquiry
Evans Fine Chem	+91-9821340302 +91-9821340302	Maharashtra, India	286	58	Inquiry
SOLFYN INTERNATIONAL LLP	+91-9321772608 +91-9321772608	Mumbai, India	105	58	Inquiry
ASM Organics	91-9866122393	Andhra Pradesh, India	1188	58	Inquiry
Loba Chemie Pvt., Ltd.	91-22-66636663	Maharashtra, India	766	58	Inquiry
S.Zhaveri Pharmakem Pvt. Ltd	-66607687	Mumbai, India	58	58	Inquiry
Chemrich Fine Chemicals Pvt., Ltd.	91-40-23607444	Hyderabad, India	400	58	Inquiry
Azole Rasayanas India Private Limited	91-40-29707735	Hyderabad, India	684	58	Inquiry
Souvenier Chemicals	08048372762Ext 645	Mumbai, India	396	58	Inquiry
Arene Life Sciences Limited	09866147700	Hyderabad, India	166	58	Inquiry

Supplier	Advantage
JSK Chemicals	58
Evans Fine Chem	58
SOLFYN INTERNATIONAL LLP	58
ASM Organics	58
Loba Chemie Pvt., Ltd.	58
S.Zhaveri Pharmakem Pvt. Ltd	58
Chemrich Fine Chemicals Pvt., Ltd.	58
Azole Rasayanas India Private Limited	58
Souvenier Chemicals	58
Arene Life Sciences Limited	58

(S)-(-)-1,1'-Bi-2-naphthol Spectrum

(S)-(-)-1,1'-Bi-2-naphthol(18531-99-2)FT-IR (S)-(-)-1,1'-Bi-2-naphthol(18531-99-2)IR (S)-(-)-1,1'-Bi-2-naphthol(18531-99-2)Raman

18531-99-2((S)-(-)-1,1'-Bi-2-naphthol)Related Search:

ALPHA-NAPHTHOLBENZEIN p-Naphtholbenzein Solvent Red 43 (n)-1,1'-bi(2-naphthol),(+/-)-1,1A-Bi-2-naphthol,(±)-1,1'-Bi(2-naphthol),99%,(+/-)-1,1'-BI(2-NAPHTHOL),1,1'-BI-2-NAPHTHOL 1-Naphthol

Terbinafine Hydrochloride 2-Naphthol Phenmedipham (S)-(-)-1,1''-BI-2-NAPHTHOL 99 E.E+% (R)-(+)-1,1'-Bi-2-naphthol

5,5',6,6',7,7',8,8'-Octahydro-bi-2-naphthol,(R)-(+)-5,5',6,6',7,7',8,8'-Octahydro-1,1'-bi-2-naphthol,99% (S)-(-)-6,6'-Dibromo-1,1'-bi-2-naphthol (R)-(-)-6,6'-Dibromo-1,1'-bi-2-naphthol (-1,1'-Bi-2-Naphthol Deacetate (S)-1,1μ-Binaphthalene-2,2μ-diyl bis(trifluoromethanesulfonate), (S)-1,1μ-Bi(2-naphthol) bis(trifluoromethanesulfonate)

(S)-(-)-3,3'-Dibromo-1,1'-bi-2-naphthol,(S)-(-)-3,3'-Dibromo-1,1'-bi-2-naphthol,99% (S)-(-)-5,5',6,6',7,7',8,8'-Octahydro-1,1'-bi-2-naphthol,99% (S)-6,6'-DIMETHYL-1,1'-BI-2-NAPHTHOL,6,6'-Dimethyl-1,1'-bi-2-naphthol

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AKOS 90560 S-(-)-1,1'-Bi-2-naphthol,99%(S)-BINOL 1,1-Binaphthalene-2,2-diol, (1S)- S-BINOL/S-(-)-1.1''-BINAPHTHYL-2.2''-DIOL (S)-(-)-1,1'-Bi-2-naphtol S-(-)-2,2''-DIHYDROXY-1,1''-DINAPHTHYL (S)-BINOL (S)-1,1 -BI-2-NAPHTHOL ***REVERSE*** S-1,1-Bi-2-Naphtho (S)-[1,1']-Binaphth-2-ol, (S)-BINOL (-)-2,2μ-Dihydroxy-1,1μ-dinaphthyl, (S)-(-)-1,1μ-Binaphthalene-2,2μ-diol, (S)-BINOL [aS,(-)]-1,1'-Binaphthalene-2,2'-diol [aS,(-)]-2,2'-Dihydroxy-1,1'-binaphthalene [aS,(-)]-Dinaphthol (1S)-1,1'-Binaphthalene-2,2'-diol, (S)-BINOL (S)-(-)-1,1'-Bi-2-naphthol,99% （S）-(-)-1_Bi-3-naphthol (S)-(-)-1,1'-Bi-2-na (1S)-2,2'-Dihydroxy-[1,1']-binaphthyl (R)-(+)-2,2'-DIHYDROXY-1,1'-BINAPHTHYL (s)-(-)-1,1’-bi-2-nanphthol 1,1'-BI-2,2'-NAPHTHOLS [1,1']BINAPHTHALENYL-2,2'-DIOL (+/-)-1,1'-BINAPHTHALENE-2,2'-DIOL (S)-(-)-BINOL (S)-(-)-2,2'-Dihydroxy-1,1'-binaphthyl (S)-(-)-1,1''-BINAPHTHYL-2,2''-DIOL FOR SY (S)-1,1'-Binaphthalene-2,2'-diol, (S)-BINOL (S)-(-)-1,1'-Bi-2-naphthol S-(-)-2,2'-Dihydroxy-1,1'-binaphthyl AURORA KA-7212 BI-2-NAPHTHOL DI-B-NAPHTHOL (-)-2,2'-DIHYDROXY-1,1'-DINAPHTHYL (+)-2,2'-DIHYDROXY-1,1'-DINAPHTHYL (+/-)-2,2'-DIHYDROXY-1,1'-DINAPHTHYL 2,2'-DIHYDROXY-1,1'-DINAPHTHYL 2,2'-DINAPHTHOL (S)-(-)-1,1'-Bi-2-naphthol (S)-(-)-1,1'-Bi-2-naphthol, >=99.5% (S)-(-)-1,1'-Bi-2-phthol (S)-(-)-1,1'-Binaphthyl-2,2'-diol for synthesis (R)-(+)-2,2'-DIHYDROXY-1,1-BINAPHTHYL (R)-(+)-1,1'-BI(2,2'-NAPHTHOL) (R)-(+)-1,1'-BINAPHTHYL-2,2'-DIOL R(+)-1,1'-BINAPHTHALENE-2,2'-DIOL (R)-[1,1]-BINAPHTHALENYL-2,2'-DIOL (R)-(+)-1,1'-BIS(2-NAPHTHOL) S-(-)-2,2'-DIHYDROXY-1,1'-DINAPHTHYL (S)-(-)-2,2'-DIHYDROXY-1,1'-BINAPHTHYL (S)-(-)-2,2'-DIHYDROXY-1,1-BINAPHTHYL (S)-[1,1]-BINAPHTHALENYL-2,2'-DIOL (S)-(-)-1,1'-BINAPHTHYL-2,2'-DIOL (S)-[1,1'-BINAPHTHALENE]-2,2'-DIOL S(-)-1,1'-BINAPHTHALENE-2,2'-DIOL (S)-(-)-1,1'-BI(2,2'-NAPHTHOL) (S)-(-)-1,1'-BI-2-NAPHTHOL (S)-(+)-1,1'-BI-2-NAPHTHOL (S)-1,1-BI-2-NAPHTHOL 98.0%(T& (1S)-[1,1'-Binaphthalene]-2,2'-diol