Dichloro{(R)-(+)-2,2'-bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl}[(2R)-(-)-1,1-bis(4-methoxyphenyl)-3-methyl-1,2-butanediamine]ruthenium(II)

CAS No.: 220114-32-9

Chemical Name:: Dichloro{(R)-(+)-2,2'-bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl}[(2R)-(-)-1,1-bis(4-methoxyphenyl)-3-methyl-1,2-butanediamine]ruthenium(II)

Synonyms: RuCl2[(R)-xylbinap][(R)-daipen];RuCl2[(R)-DM-BINAP][(R)-DAIPEN];RuCl2[(R)-xylbinap][(R)-daipen] RuCl2[(R)-xylbinap][(R)-daipen];Dichloro{(R)-(+)-2,2'-bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl}[(2R)-(-)-1,1-bis(4-methoxyphenyl);dichloro{(r)-(+)-2,2'-bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl}[(2r)-(-)-1,1-bis(4-methoxyphenyl)-3-methyl-1,2-butanediamine]ruthenium(ii);Dichloro{(R)-(+)-2,2'-bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl}[(2R)-(-)-1,1-bis(4-methoxyphenyl)-3-methyl-1,2-butanediamine]ruthenium(II);Dichloro{(R)-(+)-2,2'-bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl}[(2R)-(-)-1,1-bis(4-methoxyphenyl)-3-methyl-1,2-butanediamine]ruthenium(II) RuCl2[(R)-xylbinap][(R)-daipen];Dichloro{(R)-(+)-2,2''-bis[di(3,5-xylyl)phosphino]-1,1''-binaphthyl}[(2R)-(-)-1,1-bis(4-methoxyphenyl)-3-methyl-1,2-butanediamine]ruthenium(II) RuCl2[(R)-xylbinap][(R)-daipen]

CBNumber:: CB61181072

Molecular Formula:: C71H74Cl2N2O2P2Ru

Molecular Weight:: 1221.3

MOL File:: 220114-32-9.mol

Modify Date:: 2023/6/8 17:06:35

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Dichloro{(R)-(+)-2,2'-bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl}[(2R)-(-)-1,1-bis(4-methoxyphenyl)-3-methyl-1,2-butanediamine]ruthenium(II) Properties

Melting point	197-211 °C
storage temp.	2-8°C
form	solid
color	yellow to dark brown or green
Sensitive	air sensitive

SAFETY

Risk and Safety Statements

Symbol(GHS)	GHS07
Signal word	Warning
Hazard statements	H315-H319-H335
Precautionary statements	P264-P280-P305+P351+P338-P337+P313P-P264-P280-P302+P352-P321-P332+P313-P362
WGK Germany	3
HS Code	2931.90.6000

Dichloro{(R)-(+)-2,2'-bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl}[(2R)-(-)-1,1-bis(4-methoxyphenyl)-3-methyl-1,2-butanediamine]ruthenium(II) price More Price(3)

Manufacturer	Product number	Product description	CAS number	Packaging	Price	Updated	Buy
Sigma-Aldrich(India)	692255	RuCl2[(R)−DM−BINAP][(R)−DAIPEN]	220114-32-9	100MG	₹5372.4	2022-06-14	Buy
TCI Chemicals (India)	R0133	RuCl2[(R)-xylbinap][(R)-daipen]	220114-32-9	200MG	₹4500	2022-05-26	Buy
TCI Chemicals (India)	R0133	RuCl2[(R)-xylbinap][(R)-daipen]	220114-32-9	1G	₹15200	2022-05-26	Buy

Product number	Packaging	Price	Buy
692255	100MG	₹5372.4	Buy
R0133	200MG	₹4500	Buy
R0133	1G	₹15200	Buy

Dichloro{(R)-(+)-2,2'-bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl}[(2R)-(-)-1,1-bis(4-methoxyphenyl)-3-methyl-1,2-butanediamine]ruthenium(II) Chemical Properties,Uses,Production

Uses

Chiral RuCl2(diphosphine)?(1,?2-?diamine) complexes catalyzes the asymetrical hydrogenation of amino ketones. E.g., hydrogenation of MeCOCH2NMe2 in presence of trans-?RuCl2[(R)?-?xylbinap]?[(R)?-?daipen] gave 79?% (S)?-?MeCH(OH)?CH2NMe2. This compound was used as a catalyst.

Dichloro{(R)-(+)-2,2'-bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl}[(2R)-(-)-1,1-bis(4-methoxyphenyl)-3-methyl-1,2-butanediamine]ruthenium(II) Preparation Products And Raw materials

Raw materials

Preparation Products

Dichloro{(R)-(+)-2,2'-bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl}[(2R)-(-)-1,1-bis(4-methoxyphenyl)-3-methyl-1,2-butanediamine]ruthenium(II) Suppliers

Global( 32)Suppliers

Supplier	Tel	Country	ProdList	Advantage	Inquiry
TCI Chemicals (India) Pvt. Ltd.	1800 425 7889	New Delhi, India	6778	58	Inquiry
Zhengzhou Alfa Chemical Co.,Ltd	+8618530059196	China	13156	58	Inquiry
Career Henan Chemica Co	+86-0371-86658258 +8613203830695	China	30253	58	Inquiry
Aladdin Scientific	+1-+1(833)-552-7181	United States	52927	58	Inquiry
Watson Biotechnology Co.,Ltd	+86-18186686046 +86-18186686046	China	5814	58	Inquiry
Shanghai Haohong Pharmaceutical Co., Ltd.	400-8210725 4008210725	China	40035	58	Inquiry
Henan Alpha Chemical Co., Ltd.	0371-0371-55055611 18137792234	China	10176	58	Inquiry
Shanghai Aladdin Biochemical Technology Co.,Ltd.	+86-18521732826	China	48467	58	Inquiry
Shaoxing Zejun Pharmaceuticals Co.,Ltd	0575-82126188 15395856318	China	442	58	Inquiry
Zhengzhou Kingorgchem Chemical Technology Co., Ltd.gy Co., Ltd.	0371-65511006 18625597674	China	953	55	Inquiry

Supplier	Advantage
TCI Chemicals (India) Pvt. Ltd.	58
Zhengzhou Alfa Chemical Co.,Ltd	58
Career Henan Chemica Co	58
Aladdin Scientific	58
Watson Biotechnology Co.,Ltd	58
Shanghai Haohong Pharmaceutical Co., Ltd.	58
Henan Alpha Chemical Co., Ltd.	58
Shanghai Aladdin Biochemical Technology Co.,Ltd.	58
Shaoxing Zejun Pharmaceuticals Co.,Ltd	58
Zhengzhou Kingorgchem Chemical Technology Co., Ltd.gy Co., Ltd.	55

220114-32-9(Dichloro{(R)-(+)-2,2'-bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl}[(2R)-(-)-1,1-bis(4-methoxyphenyl)-3-methyl-1,2-butanediamine]ruthenium(II))Related Search:

Chloro{(R)-(+)-2,2'-bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl} [(2R)-(-)-1-(4-Methoxyphenyl)- 1 (4-Methoxyphenyl-kC)-3- Methyl-1,2-butanediaMine]rutheniuM(II) (R)-RUCY XylBINAP ((R,R)-2-AMINO-1,2-DIPHENYLETHYL)[(4-TOLYL)SULFONYL]AMIDO](P-CYMENE)RUTHENIUM(II)CHLORIDE Chloro{[(1S,2S)-(+)-2-amino-1,2-diphenylethyl](4-toluenesulfonyl)amido}(mesitylene)ruthenium(II), min. 90% RuCl[(S,S)-Tsdpen](mesitylene) RuCl[(S,S)-FsDPEN](p-cymene) Dichlorophen

Chlorine dioxide (R)-DM-BINAP DICHLORO[(R)-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHYL][(R)-1,1-BIS(P-METHOXYPHENYL)-2-ISOPROPYLETHANE-1,2-DIAMINE]RUTHENIUM(II) 2,2-BIS(4-METHOXYLPHENYL)ETHYLAMINE (S)-(-)-2,2'-BIS(DI-P-TOLYLPHOSPHINO)-1,1'-BINAPHTHYL

DICHLORO[(R)-(+)-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHYL]RUTHENIUM (II) (2R)-(-)-1,1-Bis(4-methoxyphenyl)-3-methyl-1,2-butanediamine 2-(4-METHOXYPHENYL)-2-PHENYLETHYLAMINE HYDROCHLORIDE Dichloro{(R)-(+)-2,2'-bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl}[(2R)-(-)-1,1-bis(4-methoxyphenyl)-3-methyl-1,2-butanediamine]ruthenium(II) (S)-(-)-2,2'-Bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl

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Dichloro{(R)-(+)-2,2'-bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl}[(2R)-(-)-1,1-bis(4-methoxyphenyl)-3-methyl-1,2-butanediamine]ruthenium(II) RuCl2[(R)-DM-BINAP][(R)-DAIPEN] Dichloro{(R)-(+)-2,2'-bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl}[(2R)-(-)-1,1-bis(4-methoxyphenyl) Dichloro{(R)-(+)-2,2'-bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl}[(2R)-(-)-1,1-bis(4-methoxyphenyl)-3-methyl-1,2-butanediamine]ruthenium(II) RuCl2[(R)-xylbinap][(R)-daipen] RuCl2[(R)-xylbinap][(R)-daipen] RuCl2[(R)-xylbinap][(R)-daipen] RuCl2[(R)-xylbinap][(R)-daipen] Dichloro{(R)-(+)-2,2''-bis[di(3,5-xylyl)phosphino]-1,1''-binaphthyl}[(2R)-(-)-1,1-bis(4-methoxyphenyl)-3-methyl-1,2-butanediamine]ruthenium(II) RuCl2[(R)-xylbinap][(R)-daipen] dichloro{(r)-(+)-2,2'-bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl}[(2r)-(-)-1,1-bis(4-methoxyphenyl)-3-methyl-1,2-butanediamine]ruthenium(ii) 220114-32-9 C71H74Cl2N2O2P2Ru