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Dichloro{(R)-(+)-2,2'-bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl}[(2R)-(-)-1,1-bis(4-methoxyphenyl)-3-methyl-1,2-butanediamine]ruthenium(II)

Dichloro{(R)-(+)-2,2'-bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl}[(2R)-(-)-1,1-bis(4-methoxyphenyl)-3-methyl-1,2-butanediamine]ruthenium(II) Structure
  • ₹4500 - ₹15200
  • Product name: Dichloro{(R)-(+)-2,2'-bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl}[(2R)-(-)-1,1-bis(4-methoxyphenyl)-3-methyl-1,2-butanediamine]ruthenium(II)
  • CAS: 220114-32-9
  • MF: C71H74Cl2N2O2P2Ru
  • MW: 1221.3
  • EINECS:
  • MDL Number:MFCD09753026
  • Synonyms:Dichloro{(R)-(+)-2,2'-bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl}[(2R)-(-)-1,1-bis(4-methoxyphenyl)-3-methyl-1,2-butanediamine]ruthenium(II);RuCl2[(R)-DM-BINAP][(R)-DAIPEN];Dichloro{(R)-(+)-2,2'-bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl}[(2R)-(-)-1,1-bis(4-methoxyphenyl);Dichloro{(R)-(+)-2,2'-bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl}[(2R)-(-)-1,1-bis(4-methoxyphenyl)-3-methyl-1,2-butanediamine]ruthenium(II) RuCl2[(R)-xylbinap][(R)-daipen];RuCl2[(R)-xylbinap][(R)-daipen] RuCl2[(R)-xylbinap][(R)-daipen];RuCl2[(R)-xylbinap][(R)-daipen];Dichloro{(R)-(+)-2,2''-bis[di(3,5-xylyl)phosphino]-1,1''-binaphthyl}[(2R)-(-)-1,1-bis(4-methoxyphenyl)-3-methyl-1,2-butanediamine]ruthenium(II) RuCl2[(R)-xylbinap][(R)-daipen];dichloro{(r)-(+)-2,2'-bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl}[(2r)-(-)-1,1-bis(4-methoxyphenyl)-3-methyl-1,2-butanediamine]ruthenium(ii)
3 prices
Selected condition:

Brand

  • TCI Chemicals (India)
  • Sigma-Aldrich(India)

Package

  • 100MG
  • 200MG
  • 1G
  • ManufacturerTCI Chemicals (India)
  • Product numberR0133
  • Product descriptionRuCl2[(R)-xylbinap][(R)-daipen]
  • Packaging200MG
  • Price₹4500
  • Updated2022-05-26
  • Buy
  • ManufacturerTCI Chemicals (India)
  • Product numberR0133
  • Product descriptionRuCl2[(R)-xylbinap][(R)-daipen]
  • Packaging1G
  • Price₹15200
  • Updated2022-05-26
  • Buy
  • ManufacturerSigma-Aldrich(India)
  • Product number692255
  • Product descriptionRuCl2[(R)−DM−BINAP][(R)−DAIPEN]
  • Packaging100MG
  • Price₹5372.4
  • Updated2022-06-14
  • Buy
Manufacturer Product number Product description Packaging Price Updated Buy
TCI Chemicals (India) R0133 RuCl2[(R)-xylbinap][(R)-daipen] 200MG ₹4500 2022-05-26 Buy
TCI Chemicals (India) R0133 RuCl2[(R)-xylbinap][(R)-daipen] 1G ₹15200 2022-05-26 Buy
Sigma-Aldrich(India) 692255 RuCl2[(R)−DM−BINAP][(R)−DAIPEN] 100MG ₹5372.4 2022-06-14 Buy

Properties

Melting point :197-211 °C
storage temp. :2-8°C
form :solid
color :yellow to dark brown or green
Sensitive :air sensitive

Safety Information

Symbol(GHS): GHS hazard pictograms
Signal word: Warning
Hazard statements:
Code Hazard statements Hazard class Category Signal word Pictogram P-Codes
H315 Causes skin irritation Skin corrosion/irritation Category 2 Warning GHS hazard pictograms P264, P280, P302+P352, P321,P332+P313, P362
H319 Causes serious eye irritation Serious eye damage/eye irritation Category 2A Warning GHS hazard pictograms P264, P280, P305+P351+P338,P337+P313P
H335 May cause respiratory irritation Specific target organ toxicity, single exposure;Respiratory tract irritation Category 3 Warning GHS hazard pictograms
Precautionary statements:
P264 Wash hands thoroughly after handling.
P264 Wash skin thouroughly after handling.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P302+P352 IF ON SKIN: wash with plenty of soap and water.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P321 Specific treatment (see … on this label).
P332+P313 IF SKIN irritation occurs: Get medical advice/attention.
P362 Take off contaminated clothing and wash before reuse.

Description

Chiral RuCl2(diphosphine)?(1,?2-?diamine) complexes catalyzes the asymetrical hydrogenation of amino ketones. E.g., hydrogenation of MeCOCH2NMe2 in presence of trans-?RuCl2[(R)?-?xylbinap]?[(R)?-?daipen] gave 79?% (S)?-?MeCH(OH)?CH2NMe2. This compound was used as a catalyst.

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