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ChemicalBook > Product Catalogue >Organic Chemistry >Organometallic compounds >Organic rhodium >((R,R)-2-AMINO-1,2-DIPHENYLETHYL)[(4-TOLYL)SULFONYL]AMIDO](P-CYMENE)RUTHENIUM(II)CHLORIDE

((R,R)-2-AMINO-1,2-DIPHENYLETHYL)[(4-TOLYL)SULFONYL]AMIDO](P-CYMENE)RUTHENIUM(II)CHLORIDE

((R,R)-2-AMINO-1,2-DIPHENYLETHYL)[(4-TOLYL)SULFONYL]AMIDO](P-CYMENE)RUTHENIUM(II)CHLORIDE Structure
  • ₹3651.9 - ₹10800
  • Product name: ((R,R)-2-AMINO-1,2-DIPHENYLETHYL)[(4-TOLYL)SULFONYL]AMIDO](P-CYMENE)RUTHENIUM(II)CHLORIDE
  • CAS: 192139-92-7
  • MF: C21H21ClN2O2RuS.C10H14
  • MW: 636.219
  • EINECS:
  • MDL Number:MFCD10567385
  • Synonyms:((R,R)-2-AMINO-1,2-DIPHENYLETHYL)[(4-TOLYL)SULFONYL]AMIDO](P-CYMENE)RUTHENIUM(II)CHLORIDE;Chloro{[(1R,2R)-(-)-2-amino-1,2-diphenylethyl](4-toluenesulfonyl)amido}(p-cymene)ruthenium(II), min. 95% RuCl[(R,R)-Tsdpen](p-cymene);Chloro{[(1R,2R)-(-)-2-amino-1,2-diphenylethyl](4-toluenesulfonyl)amido}(p-cymene)ruthenium(II), min. 95%;Chloro{[(1R,2R)-(-)-2-amino-1,2-diphenylethyl](4-toluenesulfonyl)amido}(p-
    cymene)ruthenium(II), min. 95% RuCl[(R,R)-Tsdpen](p-cymene);Chloro{[(1R,2R)-(-)-2-aMino-1,2-diphenylethyl](4-toluenesulfonyl)aMido}(p-cyMene)rutheniuM(II),95% RuCl[(R,R)-Tsdpen](p-cyMene);((R,R)-2-aMino-1,2-diphenylethyl0[(4-tolyl)sulfonyl]aMino](p-cyMene)RutheniuM(II)chloride;Chloro{[(1R,2R)-(-)-2-aMino-1,2-diphenylethyl](4-toluenesulfonyl)aMido}(p-cyMene)rutheniuM(II), Min. 95% C31H35ClN2O2RuS;Chloro{[(1R,2R)-(-)-2-aMino-1,2-diphenylethyl](4-toluenesulfonyl)aMido}(p-cyMene)rutheniuM(II),RuCl[(R,R)-Tsdpen](p-cyMene)
4 prices
Selected condition:

Brand

  • TCI Chemicals (India)
  • Sigma-Aldrich(India)

Package

  • 100MG
  • 200MG
  • 500MG
  • 1G
  • ManufacturerTCI Chemicals (India)
  • Product numberR0125
  • Product descriptionRuCl[(R,R)-Tsdpen](p-cymene)
  • Packaging200MG
  • Price₹3700
  • Updated2022-05-26
  • Buy
  • ManufacturerTCI Chemicals (India)
  • Product numberR0125
  • Product descriptionRuCl[(R,R)-Tsdpen](p-cymene)
  • Packaging1G
  • Price₹10800
  • Updated2022-05-26
  • Buy
  • ManufacturerSigma-Aldrich(India)
  • Product number703907
  • Product descriptionRuCl(p-cymene)[(R,R)-Ts-DPEN]
  • Packaging100MG
  • Price₹3651.9
  • Updated2022-06-14
  • Buy
  • ManufacturerSigma-Aldrich(India)
  • Product number703907
  • Product descriptionRuCl(p-cymene)[(R,R)-Ts-DPEN]
  • Packaging500MG
  • Price₹10334.1
  • Updated2022-06-14
  • Buy
Manufacturer Product number Product description Packaging Price Updated Buy
TCI Chemicals (India) R0125 RuCl[(R,R)-Tsdpen](p-cymene) 200MG ₹3700 2022-05-26 Buy
TCI Chemicals (India) R0125 RuCl[(R,R)-Tsdpen](p-cymene) 1G ₹10800 2022-05-26 Buy
Sigma-Aldrich(India) 703907 RuCl(p-cymene)[(R,R)-Ts-DPEN] 100MG ₹3651.9 2022-06-14 Buy
Sigma-Aldrich(India) 703907 RuCl(p-cymene)[(R,R)-Ts-DPEN] 500MG ₹10334.1 2022-06-14 Buy

Properties

Melting point :215 °C
storage temp. :2-8°C
solubility :Deuterated Chloroform, DMF
form :solid
color :yellow to dark brown
optical activity :[α]20/D 116°, c = 0.1 in chloroform
Sensitive :air sensitive
InChIKey :AZFNGPAYDKGCRB-MNPNNRAMNA-M
SMILES :C1=C(S(=O)(=O)N([C@H](C2=CC=CC=C2)[C@H](N)C2=CC=CC=C2)[Ru]Cl)C=CC(C)=C1.C1=CC(C)=CC=C1C(C)C |&1:6,13,r|

Safety Information

Symbol(GHS): GHS hazard pictograms
Signal word: Warning
Hazard statements:
Code Hazard statements Hazard class Category Signal word Pictogram P-Codes
H302 Harmful if swallowed Acute toxicity,oral Category 4 Warning GHS hazard pictograms P264, P270, P301+P312, P330, P501
H315 Causes skin irritation Skin corrosion/irritation Category 2 Warning GHS hazard pictograms P264, P280, P302+P352, P321,P332+P313, P362
H319 Causes serious eye irritation Serious eye damage/eye irritation Category 2A Warning GHS hazard pictograms P264, P280, P305+P351+P338,P337+P313P
H335 May cause respiratory irritation Specific target organ toxicity, single exposure;Respiratory tract irritation Category 3 Warning GHS hazard pictograms
Precautionary statements:
P261 Avoid breathing dust/fume/gas/mist/vapours/spray.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P301+P312 IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.
P302+P352 IF ON SKIN: wash with plenty of soap and water.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

Description

RuCl(p-cymene)[(R,R)-Ts-DPEN] is a phosphine cationic ruthenium catalysts used for enantioselective hydrogenation of quinolines, N-Alkyl ketimines, antitumor and antiproliferative derivatives of natural products isolated from bacteria, and hydroxy arylaldehydes via Rap-Stoermer-enantioselective transfer hydrogenation.

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