ChemicalBook > Product Catalog >Organic Chemistry >Organometallic compounds >Organic rhodium >((R,R)-2-AMINO-1,2-DIPHENYLETHYL)[(4-TOLYL)SULFONYL]AMIDO](P-CYMENE)RUTHENIUM(II)CHLORIDE

((R,R)-2-AMINO-1,2-DIPHENYLETHYL)[(4-TOLYL)SULFONYL]AMIDO](P-CYMENE)RUTHENIUM(II)CHLORIDE

((R,R)-2-AMINO-1,2-DIPHENYLETHYL)[(4-TOLYL)SULFONYL]AMIDO](P-CYMENE)RUTHENIUM(II)CHLORIDE Structure
CAS No.
192139-92-7
Chemical Name:
((R,R)-2-AMINO-1,2-DIPHENYLETHYL)[(4-TOLYL)SULFONYL]AMIDO](P-CYMENE)RUTHENIUM(II)CHLORIDE
Synonyms
RuCL;TsDPEN;RuCl[(R,R)-Tsdpen](p-cymene);RuCl(p-cymene)[(R,R)-Ts-DPEN];Chloro{[(1R,2R)-(-)-2-amino-1,2-diphenylethyl](4-toluenesulfonyl)amido}(p-cymene)ruthenium(II);(R,R)-N-;R)-2-AMINO-1;[(R,R)-Tsdpen](p-cymene);RuCl (cymene)[(R,R)-TsDPEN];CHLORO{[(1R,2R)-(-)-2AMINO-1,2DIPHENY
CBNumber:
CB81564668
Molecular Formula:
C21H21ClN2O2RuS.C10H14
Molecular Weight:
636.219
MOL File:
192139-92-7.mol
Modify Date:
2023/6/28 13:45:06

((R,R)-2-AMINO-1,2-DIPHENYLETHYL)[(4-TOLYL)SULFONYL]AMIDO](P-CYMENE)RUTHENIUM(II)CHLORIDE Properties

Melting point 215 °C
storage temp. 2-8°C
solubility Deuterated Chloroform, DMF
form solid
color yellow to dark brown
optical activity [α]20/D 116°, c = 0.1 in chloroform
Sensitive air sensitive
InChIKey AZFNGPAYDKGCRB-MNPNNRAMNA-M
SMILES C1=C(S(=O)(=O)N([C@H](C2=CC=CC=C2)[C@H](N)C2=CC=CC=C2)[Ru]Cl)C=CC(C)=C1.C1=CC(C)=CC=C1C(C)C |&1:6,13,r|

SAFETY

Risk and Safety Statements

Symbol(GHS) 
GHS07
Signal word  Warning
Hazard statements  H302-H315-H319-H335
Precautionary statements  P261-P280-P301+P312-P302+P352-P305+P351+P338
WGK Germany  3
HS Code  28439000
NFPA 704
1
2 0

((R,R)-2-AMINO-1,2-DIPHENYLETHYL)[(4-TOLYL)SULFONYL]AMIDO](P-CYMENE)RUTHENIUM(II)CHLORIDE price More Price(4)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich(India) 703907 RuCl(p-cymene)[(R,R)-Ts-DPEN] 192139-92-7 100MG ₹3651.9 2022-06-14 Buy
Sigma-Aldrich(India) 703907 RuCl(p-cymene)[(R,R)-Ts-DPEN] 192139-92-7 500MG ₹10334.1 2022-06-14 Buy
TCI Chemicals (India) R0125 RuCl[(R,R)-Tsdpen](p-cymene) 192139-92-7 200MG ₹3700 2022-05-26 Buy
TCI Chemicals (India) R0125 RuCl[(R,R)-Tsdpen](p-cymene) 192139-92-7 1G ₹10800 2022-05-26 Buy
Product number Packaging Price Buy
703907 100MG ₹3651.9 Buy
703907 500MG ₹10334.1 Buy
R0125 200MG ₹3700 Buy
R0125 1G ₹10800 Buy

((R,R)-2-AMINO-1,2-DIPHENYLETHYL)[(4-TOLYL)SULFONYL]AMIDO](P-CYMENE)RUTHENIUM(II)CHLORIDE Chemical Properties,Uses,Production

Chemical Properties

Orange to brown powder

Uses

Phosphine cationic ruthenium catalysts used for enantioselective hydrogenation of:

  • Quinolines
  • N-Alkyl ketimines
  • Antitumor and antiproliferative derivatives of natural products isolated from bacteria
  • Hydroxy arylaldehydes via Rap-Stoermer-enantioselective transfer hydrogenation

Catalyst with improved performance modified via microenvironment engineering of nanocages

General Description

RuCl(p-cymene)[(R,R)-Ts-DPEN] is a chiral diamine ligand complexed with ruthenium.

((R,R)-2-AMINO-1,2-DIPHENYLETHYL)[(4-TOLYL)SULFONYL]AMIDO](P-CYMENE)RUTHENIUM(II)CHLORIDE Preparation Products And Raw materials

Raw materials

Preparation Products

Global( 166)Suppliers
Supplier Tel Country ProdList Advantage Inquiry
Evans Fine Chem +91-9821340302 +91-9821340302 Maharashtra, India 286 58 Inquiry
SOLFYN INTERNATIONAL LLP +91-9321772608 +91-9321772608 Mumbai, India 105 58 Inquiry
Johnson Matthey Chemicals India Pvt Ltd +91-9820622275 +91-9711869003 Maharashtra, India 69 58 Inquiry
CHEMSWORTH +91-261-2397244 New Delhi, India 6707 30 Inquiry
CLEARSYNTH LABS LTD. +91-22-45045900 Hyderabad, India 6351 58 Inquiry
TCI Chemicals (India) Pvt. Ltd. 1800 425 7889 New Delhi, India 6778 58 Inquiry
Hangzhou ICH Biofarm Co., Ltd +86-0571-28186870; +undefined8613073685410 China 985 58 Inquiry
Capot Chemical Co.,Ltd. 571-85586718 +8613336195806 China 29798 60 Inquiry
Shanghai Daken Advanced Materials Co.,Ltd +86-371-66670886 China 16220 58 Inquiry
Henan Tianfu Chemical Co.,Ltd. +86-0371-55170693 +86-19937530512 China 21676 55 Inquiry
((R,R)-2-AMINO-1,2-DIPHENYLETHYL)[(4-TOLYL)SULFONYL]AMIDO](P-CYMENE)RUTHENIUM(II)CHLORIDE Chloro{[(1R,2R)-(-)-2-amino-1,2-diphenylethyl](4-toluenesulfonyl)amido}(p-cymene)ruthenium(II), min. 95% RuCl[(R,R)-Tsdpen](p-cymene) Chloro{[(1R,2R)-(-)-2-amino-1,2-diphenylethyl](4-toluenesulfonyl)amido}(p-cymene)ruthenium(II), min. 95% Chloro{[(1R,2R)-(-)-2-amino-1,2-diphenylethyl](4-toluenesulfonyl)amido}(p-
cymene)ruthenium(II), min. 95% RuCl[(R,R)-Tsdpen](p-cymene)
Chloro{[(1R,2R)-(-)-2-aMino-1,2-diphenylethyl](4-toluenesulfonyl)aMido}(p-cyMene)rutheniuM(II),95% RuCl[(R,R)-Tsdpen](p-cyMene) ((R,R)-2-aMino-1,2-diphenylethyl0[(4-tolyl)sulfonyl]aMino](p-cyMene)RutheniuM(II)chloride Chloro{[(1R,2R)-(-)-2-aMino-1,2-diphenylethyl](4-toluenesulfonyl)aMido}(p-cyMene)rutheniuM(II), Min. 95% C31H35ClN2O2RuS Chloro{[(1R,2R)-(-)-2-aMino-1,2-diphenylethyl](4-toluenesulfonyl)aMido}(p-cyMene)rutheniuM(II),RuCl[(R,R)-Tsdpen](p-cyMene) RutheniuM,[N-[(1R,2R)-2-(aMino-kN)-1,2-diphenylethyl]-4-MethylbenzenesulfonaMidato-kN]chloro[(1,2,3,4,5,6-h)-1-Methyl-4-(1-Methylethyl)benzene]- [((R,R)-2-AMino-1,2-diphenylethyl)[(4-tolyl)sulfonyl]aMido](chloro)(η6-p-cyMene)rutheniuM (R,R)-N- ((R,r)-2-amino-1,2-diphenylethy)[(4-tolyl)sulfonyl]amido](pcymene)ruthenium(II)chloride (R,R)-N-(p-Toluenesulfonyl)-1,2-diphenylethanediamine(chloro [(1R,2R)-2-amino-1,2-diphenyl-ethyl]-(p-tolylsulfonyl)azanide ((R,R)-2-amino-1,2-diphenylethyl)[(4-tolyl)sulfonyl]amido](p... R)-2-AMINO-1 2-DIPHENYLETHYL)[(4-TOLYL)SULFONYL]AMIDO](P-CYMENE)RUTHENIUM(II)CHLORIDE (1R,2R)-2-amino-1,2-diphenylethyl]-(4-methylphenyl)sulfonylazanide [N-[(1R,2R)-2-(Amino-KN)-1,2-diphenylethyl]-4-methylbenzenesulfonamidato-KN]chloro[(1,2,3,4,5,6-η:)-1-methyl- [RuCl(η6-p-cymene)(N-tosyl-1,2-diphenylethylenediamine)] RuCl(p-cymene)[(R,R)-Ts-DPEN] Chloro{[(1R,2R)-(-)-2-amino-1,2-diphenylethyl](4-toluenesulfonyl)amido}(p-cymene)ruthenium(II) Ruthenium,[N-[(1R,2R)-2-(amino-kN)-1,2-diphenylethyl]-4-methylbenzenesulfonamidato-kN]chloro[(1,2,3,4,5,6-h)-1-methyl-4-(1-methylethyl)benzene]-,98% [(R,R)-Tsdpen](p-cymene) Ruthenium, [N-[(1R,2R)-2-(amino-κN)-1,2-diphenylethyl]-4-methylbenzenesulfonamidato-κN]chloro[(1,2,3,4,5,6-η)-1-methyl-4-(1-methylethyl)benzene]- [(R,R)-N-(2-Amino-1,2-diphenylethyl)-p-toluenesulfonamide]chloro(p-cymene)ruthenium(II) Chloro(p-cymene)[(R,R)-N-(p-toluenesulfonyl)-1,2-diphenylethylenediamine]ruthenium(II) ((R,R)-2-AMINO-1,2-DIPHENYLETHYL)[(4-TOLYL)SULFONYL]AMIDO](P-CYMENE)RUTHENIUM(II)CHLORIDE ISO 9001:2015 REACH RuCl (cymene)[(R,R)-TsDPEN] RuCl(p-cymene)[(R,R)-Ts-DPEN] Chloro{[(1R,2R)-(-)-2-amino-1,2-diphenylethyl](4-toluenesulfonyl)amido}(p-cymene)ruthenium(II) TsDPEN RuCl[(R,R)-Tsdpen](p-cymene) RuCL [((R,R)-2-Amino-1,2-diphenylethyl)[(4-tolyl)sulfonyl]amido](chloro)( p -cymene)ruthenium(II) 192139-92-7 [(1R,2R)-2-amiNA-1,2-diphenylethyl]-(4-methylphenyl)sulfonylazanide RuCl[(R,R)-Tsdpen](p-cymene)/Chloro{[(1R,2R)-(-)-2-amino-1,2-diphenylethyl](4-toluenesulfonyl)amido}(p-cymene)ruthenium(II) CHLORO{[(1R,2R)-(-)-2AMINO-1,2DIPHENY 192139-92-7 C31H35ClN2O2RuS Ru organometallic complex