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ChemicalBook > Product Catalogue >Organic Chemistry >Organometallic compounds >Organic rhodium >(S,S)-N-(p-Toluenesulfonyl)-1,2-diphenylethanediamine(chloro)(p-cymene)ruthenium(II)

(S,S)-N-(p-Toluenesulfonyl)-1,2-diphenylethanediamine(chloro)(p-cymene)ruthenium(II)

(S,S)-N-(p-Toluenesulfonyl)-1,2-diphenylethanediamine(chloro)(p-cymene)ruthenium(II) Structure
  • ₹3700 - ₹13100
  • Product name: (S,S)-N-(p-Toluenesulfonyl)-1,2-diphenylethanediamine(chloro)(p-cymene)ruthenium(II)
  • CAS: 192139-90-5
  • MF: C31H30ClN2O2RuS
  • MW: 631.17
  • EINECS:
  • MDL Number:MFCD09953484
  • Synonyms:-1,2-diphenylethanediamine(chloro);-N-(p-Toluenesulfonyl);(S,S)-N-(p-Toluenesulfonyl)-1,2-diphenylethanediamine(chloro)(p-cymene)ruthenium(II);Chloro{[(1S,2S)-(+)-amino-1,2-diphenylethyl](4-toluenesulfonyl)amido}(p-cymene)ruthenium(II);[N-[(1S,2S)-2-(Amino-kN)-1,2-diphenylethyl]-4-methylbenzenesulfonamidato-kN]chloro[(1,2,3,4,5,6-n)-1-methyl-4-(1-methylethyl)benzene]ruthenium;Chloro{[(1S,2S)-(+)-2-amino-1,2-diphenylethyl](4-toluenesulfonyl)amido}(p-
    cymene)ruthenium(II), min. 95% RuCl[(S,S)-Tsdpen](p-cymene);Chloro{[(1S,2S)-(+)-2-amino-1,2-diphenylethyl](4-toluenesulfonyl)amido}(p-cymene)ruthenium(II), min. 95%;Chloro{[(1S,2S)-(+)-2-amino-1,2-diphenylethyl](4-toluenesulfonyl)amido}(p-cymene)ruthenium(II), min. 95% RuCl[(S,S)-Tsdpen](p-cymene)
4 prices
Selected condition:

Brand

  • TCI Chemicals (India)
  • Sigma-Aldrich(India)

Package

  • 100MG
  • 200MG
  • 500MG
  • 1G
  • ManufacturerTCI Chemicals (India)
  • Product numberR0124
  • Product descriptionRuCl[(S,S)-Tsdpen](p-cymene)
  • Packaging200MG
  • Price₹3700
  • Updated2022-05-26
  • Buy
  • ManufacturerTCI Chemicals (India)
  • Product numberR0124
  • Product descriptionRuCl[(S,S)-Tsdpen](p-cymene)
  • Packaging1G
  • Price₹13100
  • Updated2022-05-26
  • Buy
  • ManufacturerSigma-Aldrich(India)
  • Product number703915
  • Product descriptionRuCl(p-cymene)[(S,S)-Ts-DPEN]
  • Packaging100MG
  • Price₹3840.6
  • Updated2022-06-14
  • Buy
  • ManufacturerSigma-Aldrich(India)
  • Product number703915
  • Product descriptionRuCl(p-cymene)[(S,S)-Ts-DPEN]
  • Packaging500MG
  • Price₹11188.8
  • Updated2022-06-14
  • Buy
Manufacturer Product number Product description Packaging Price Updated Buy
TCI Chemicals (India) R0124 RuCl[(S,S)-Tsdpen](p-cymene) 200MG ₹3700 2022-05-26 Buy
TCI Chemicals (India) R0124 RuCl[(S,S)-Tsdpen](p-cymene) 1G ₹13100 2022-05-26 Buy
Sigma-Aldrich(India) 703915 RuCl(p-cymene)[(S,S)-Ts-DPEN] 100MG ₹3840.6 2022-06-14 Buy
Sigma-Aldrich(India) 703915 RuCl(p-cymene)[(S,S)-Ts-DPEN] 500MG ₹11188.8 2022-06-14 Buy

Properties

Melting point :>175 °C
alpha :178o (C=0.5 IN CHLOROFORM)
storage temp. :2-8°C
solubility :soluble in Chloroform, DCM, Ethyl Acetate
form :solid
color :yellow to dark brown
optical activity :[α]20/D +178°, c = 0.5 in chloroform
Sensitive :air sensitive
InChIKey :DCJKLKCGNMDXFR-MNPNNRAMNA-M
SMILES :[Cl-][Ru+2]123456(N[C@@H](C7C=CC=CC=7)[C@H](C7C=CC=CC=7)[N-]1S(C1C=CC(C)=CC=1)(=O)=O)C1(C)C2=C3C4(C(C)C)=C5C6=1 |&1:3,10,r|

Safety Information

Symbol(GHS): GHS hazard pictograms
Signal word: Warning
Hazard statements:
Code Hazard statements Hazard class Category Signal word Pictogram P-Codes
H315 Causes skin irritation Skin corrosion/irritation Category 2 Warning GHS hazard pictograms P264, P280, P302+P352, P321,P332+P313, P362
H319 Causes serious eye irritation Serious eye damage/eye irritation Category 2A Warning GHS hazard pictograms P264, P280, P305+P351+P338,P337+P313P
H335 May cause respiratory irritation Specific target organ toxicity, single exposure;Respiratory tract irritation Category 3 Warning GHS hazard pictograms
Precautionary statements:
P261 Avoid breathing dust/fume/gas/mist/vapours/spray.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

Description

Catalyst involved in: ? Asymmetric transfer hydrogenation of imines and ketones ? Intramolecular asymmetric reductive amination ? Tandem hydroformylation / hydrogenation of terminal olefins Reactant involved in studies of thermal decomposition of arenerut

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