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ChemicalBook > Product Catalogue >Chemical Reagents >Organic reagents >Polyamines >(1R,2R)-(-)-N-p-Tosyl-1,2-diphenylethylenediamine

(1R,2R)-(-)-N-p-Tosyl-1,2-diphenylethylenediamine

(1R,2R)-(-)-N-p-Tosyl-1,2-diphenylethylenediamine Structure
  • ₹8300 - ₹50165
  • Product name: (1R,2R)-(-)-N-p-Tosyl-1,2-diphenylethylenediamine
  • CAS: 144222-34-4
  • MF: C21H22N2O2S
  • MW: 366.48
  • EINECS:
  • MDL Number:MFCD02093428
  • Synonyms:(R,R)-N-(P-TOLUENESULFONYL)-1,2-DIPHENYLETHYLENEDIAMINE;(R,R)-N-(2-AMINO-1,2-DIPHENYLETHYL)-P-TOLUENESULFONAMIDE;(R,R)-TSDPEN;(1R,2R)-(-)-N-p-Tosyl-1,2-diphenylethylenediamine;(1R,2R)-(-)-N-p-Tosyl-1,2-diphenylethylenediamine98%;(R,R)-Ts-DPEN, (1R,2R)-N-(p-Toluenesulfonyl)-1,2-diphenylethanediamine, 98%;Benzenesulfonamide,N-[(1R,2R)-2-amino-1,2-diphenylethyl]-4-methyl-;(1R,2R)-(-)-N-p-Tosyl-1,2-diphenylethylenediamine≥ 99% (Assay, Chiral purity)
5 prices
Selected condition:

Brand

  • Sigma-Aldrich(India)
  • TCI Chemicals (India)
  • ALFA India

Package

  • 1G
  • 5g
  • 25g
  • ManufacturerSigma-Aldrich(India)
  • Product number484334
  • Product description(1R,2R)-(−)-N-p-Tosyl-1,2-diphenylethylenediamine 98%
  • Packaging1G
  • Price₹14462.2
  • Updated2022-06-14
  • Buy
  • ManufacturerTCI Chemicals (India)
  • Product numberA1548
  • Product description(R,R)-N-(2-Amino-1,2-diphenylethyl)-p-toluenesulfonamide
  • Packaging1G
  • Price₹8300
  • Updated2022-05-26
  • Buy
  • ManufacturerALFA India
  • Product numberALF-H26061-14
  • Product description(1R,2R)-N-(p-Toluenesulfonyl)-1,2-diphenylethanediamine, 98+%
  • Packaging25g
  • Price₹50165
  • Updated2022-05-26
  • Buy
  • ManufacturerALFA India
  • Product numberALF-H26061-06
  • Product description(1R,2R)-N-(p-Toluenesulfonyl)-1,2-diphenylethanediamine, 98+%
  • Packaging5g
  • Price₹42093
  • Updated2022-05-26
  • Buy
  • ManufacturerALFA India
  • Product numberALF-H26061-03
  • Product description(1R,2R)-N-(p-Toluenesulfonyl)-1,2-diphenylethanediamine, 98+%
  • Packaging1g
  • Price₹8300
  • Updated2022-05-26
  • Buy
Manufacturer Product number Product description Packaging Price Updated Buy
Sigma-Aldrich(India) 484334 (1R,2R)-(−)-N-p-Tosyl-1,2-diphenylethylenediamine 98% 1G ₹14462.2 2022-06-14 Buy
TCI Chemicals (India) A1548 (R,R)-N-(2-Amino-1,2-diphenylethyl)-p-toluenesulfonamide 1G ₹8300 2022-05-26 Buy
ALFA India ALF-H26061-14 (1R,2R)-N-(p-Toluenesulfonyl)-1,2-diphenylethanediamine, 98+% 25g ₹50165 2022-05-26 Buy
ALFA India ALF-H26061-06 (1R,2R)-N-(p-Toluenesulfonyl)-1,2-diphenylethanediamine, 98+% 5g ₹42093 2022-05-26 Buy
ALFA India ALF-H26061-03 (1R,2R)-N-(p-Toluenesulfonyl)-1,2-diphenylethanediamine, 98+% 1g ₹8300 2022-05-26 Buy

Properties

Melting point :128-131 °C(lit.)
Boiling point :537.3±60.0 °C(Predicted)
alpha :-61.5 º (c=1, CH2Cl2)
Density :1.1440 (rough estimate)
refractive index :-30 ° (C=0.4, CHCl3)
storage temp. :Keep in dark place,Inert atmosphere,Room temperature
solubility :Chloroform, Methanol
pka :10.76±0.50(Predicted)
form :Crystals or Crystalline Powder
color :White to slightly yellow
optical activity :[α]20/D 35°, c = 1 in chloroform
Water Solubility :insoluble
InChIKey :UOPFIWYXBIHPIP-NHCUHLMSSA-N
CAS DataBase Reference :144222-34-4(CAS DataBase Reference)

Safety Information

Symbol(GHS): GHS hazard pictograms
Signal word: Warning
Hazard statements:
Code Hazard statements Hazard class Category Signal word Pictogram P-Codes
H315 Causes skin irritation Skin corrosion/irritation Category 2 Warning GHS hazard pictograms P264, P280, P302+P352, P321,P332+P313, P362
H319 Causes serious eye irritation Serious eye damage/eye irritation Category 2A Warning GHS hazard pictograms P264, P280, P305+P351+P338,P337+P313P
H335 May cause respiratory irritation Specific target organ toxicity, single exposure;Respiratory tract irritation Category 3 Warning GHS hazard pictograms
Precautionary statements:
P261 Avoid breathing dust/fume/gas/mist/vapours/spray.
P264 Wash hands thoroughly after handling.
P264 Wash skin thouroughly after handling.
P271 Use only outdoors or in a well-ventilated area.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P302+P352 IF ON SKIN: wash with plenty of soap and water.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

Description

(1R,2R)-(-)-N-p-Tosyl-1,2-diphenylethylenediamine is a chiral diamine ligand for cooperative metal-Bronsted acid catalyzed reductive amination using hydrogen gas.

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