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(1R,2R)-trans-N-Boc-1,2-Cyclohexanediamine

(1R,2R)-trans-N-Boc-1,2-Cyclohexanediamine Structure
  • ₹6581.6 - ₹29700
  • Product name: (1R,2R)-trans-N-Boc-1,2-Cyclohexanediamine
  • CAS: 146504-07-6
  • MF: C11H22N2O2
  • MW: 214.3
  • EINECS:
  • MDL Number:MFCD08726023
  • Synonyms:(1R,2R)-trans-N-Boc-1,2-Cyclohexanediamine;(1R)-trans-N-Boc-1,2-diaminocyclohexane;Trans (1R,2R)-1N-Boc-cyclohexane-1,2-diamine;Carbamic acid, N-[(1R,2R)-2-aminocyclohexyl]-, 1,1-dimethylethyl ester;N-Boc-1R,2R-Cyclohexanediamine;((1R,2R)-2-Aminocyclohexyl)-carbamic acid tert-butyl ester;(1R,2R)-(-)-N-(t-Butoxycarbonyl)-1,2-cyclohexanediamine;(1R,2R)-N-tert.-Butoxycarbonylcyclohexane-1,2-diamine
4 prices
Selected condition:

Brand

  • TCI Chemicals (India)
  • Sigma-Aldrich(India)

Package

  • 250MG
  • 1G
  • 5G
  • ManufacturerTCI Chemicals (India)
  • Product numberB5647
  • Product description(1R,2R)-N1-(tert-Butoxycarbonyl)-1,2-cyclohexanediamine min. 98.0 %
  • Packaging1G
  • Price₹7300
  • Updated2022-05-26
  • Buy
  • ManufacturerTCI Chemicals (India)
  • Product numberB5647
  • Product description(1R,2R)-N1-(tert-Butoxycarbonyl)-1,2-cyclohexanediamine min. 98.0 %
  • Packaging5G
  • Price₹29700
  • Updated2022-05-26
  • Buy
  • ManufacturerSigma-Aldrich(India)
  • Product number670650
  • Product description(1R,2R)-trans-N-Boc-1,2-cyclohexanediamine 97%
  • Packaging250MG
  • Price₹6581.6
  • Updated2022-06-14
  • Buy
  • ManufacturerSigma-Aldrich(India)
  • Product number670650
  • Product description(1R,2R)-trans-N-Boc-1,2-cyclohexanediamine 97%
  • Packaging1G
  • Price₹15501.4
  • Updated2022-06-14
  • Buy
Manufacturer Product number Product description Packaging Price Updated Buy
TCI Chemicals (India) B5647 (1R,2R)-N1-(tert-Butoxycarbonyl)-1,2-cyclohexanediamine min. 98.0 % 1G ₹7300 2022-05-26 Buy
TCI Chemicals (India) B5647 (1R,2R)-N1-(tert-Butoxycarbonyl)-1,2-cyclohexanediamine min. 98.0 % 5G ₹29700 2022-05-26 Buy
Sigma-Aldrich(India) 670650 (1R,2R)-trans-N-Boc-1,2-cyclohexanediamine 97% 250MG ₹6581.6 2022-06-14 Buy
Sigma-Aldrich(India) 670650 (1R,2R)-trans-N-Boc-1,2-cyclohexanediamine 97% 1G ₹15501.4 2022-06-14 Buy

Properties

Melting point :114-115℃
Boiling point :322.1±31.0 °C(Predicted)
Density :1.02±0.1 g/cm3(Predicted)
storage temp. :under inert gas (nitrogen or Argon) at 2–8 °C
form :powder to crystal
pka :12.26±0.40(Predicted)
color :White to Almost white
optical activity :[α]/D -26±2°, c = 1 in chloroform
BRN :7023564
InChIKey :AKVIZYGPJIWKOS-RKDXNWHRSA-N

Safety Information

Symbol(GHS): GHS hazard pictograms
Signal word: Danger
Hazard statements:
Code Hazard statements Hazard class Category Signal word Pictogram P-Codes
H314 Causes severe skin burns and eye damage Skin corrosion/irritation Category 1A, B, C Danger GHS hazard pictograms P260,P264, P280, P301+P330+ P331,P303+P361+P353, P363, P304+P340,P310, P321, P305+ P351+P338, P405,P501
Precautionary statements:
P260 Do not breathe dust/fume/gas/mist/vapours/spray.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P303+P361+P353 IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P363 Wash contaminated clothing before reuse.

Description

(1R,2R)-trans-N-Boc-1,2-cyclohexanediamine can be used as:
  • An organocatalyst in the intramolecular desymmetrization of cyclohexanones to yield 2-azabicyclo[3.3.1]nonane.
  • A starting material in the synthesis of a chiral nickel catalyst applicable for the Michael addition reaction of 1,3-dicarbonyl compounds to yield nitroalkenes.


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