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HEXAHYDRO-1,3,5-TRINITRO-1,3,5-TRIAZINE

HEXAHYDRO-1,3,5-TRINITRO-1,3,5-TRIAZINE Structure
CAS No.
121-82-4
Chemical Name:
HEXAHYDRO-1,3,5-TRINITRO-1,3,5-TRIAZINE
Synonyms
T4;RDX;pe4;cx84a;DFNB24;khp281;HEXOGEN;Cyklonit;Geksogen;Heksogen
CBNumber:
CB6714556
Molecular Formula:
C3H6N6O6
Molecular Weight:
222.12
MOL File:
121-82-4.mol
Modify Date:
2024/3/14 15:18:27

HEXAHYDRO-1,3,5-TRINITRO-1,3,5-TRIAZINE Properties

Melting point 205-206°
Boiling point 363.28°C (rough estimate)
Density d420 1.82
vapor pressure 0Pa at 20℃
refractive index 1.6700 (estimate)
Flash point 2℃
storage temp. 2-8°C
pka -15.06±0.20(Predicted)
form Colorless crystals
Water Solubility 59.75mg/L(25 ºC)
Exposure limits TLV-TWA skin 1.5 mg/m3 (ACGIH and MSHA).
Stability Unstable. Explosive.
LogP 0.87 at 23℃
EPA Substance Registry System Cyclonite (121-82-4)

SAFETY

Risk and Safety Statements

Symbol(GHS) 
GHS02,GHS07,GHS08
Signal word  Danger
Hazard statements  H225-H302+H332-H319-H373-H302+H312+H332
Precautionary statements  P210-P305+P351+P338-P261-P302+P352+P312-P304+P340+P312-P337+P313-P403+P235
Hazard Codes  F,T,Xn,E
Risk Statements  11-23/24/25-36/37/38-36-20/21/22-3
Safety Statements  16-27-45-36/37-35-26
RIDADR  0072
OEB B
OEL TWA: 1.5 mg/m3, STEL: 3 mg/m3 [skin]
WGK Germany  2
HazardClass  1.1D
HS Code  29339900
Toxicity LD50 oral in rat: 100mg/kg

HEXAHYDRO-1,3,5-TRINITRO-1,3,5-TRIAZINE price More Price(1)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich(India) ERR-001S RDX solution 1000?μg/mL in acetonitrile, ampule of 1.2?mL, certified reference material, Cerilliant? 121-82-4 1.2ML ₹2590 2022-06-14 Buy
Product number Packaging Price Buy
ERR-001S 1.2ML ₹2590 Buy

HEXAHYDRO-1,3,5-TRINITRO-1,3,5-TRIAZINE Chemical Properties,Uses,Production

Chemical Properties

Hexahydro-1,3,5-trinitro-S-triazine is a white crystalline compound.

Uses

Cyclonite is a high explosive and principal constituent of plastic bombs. It is preparedby treating hexamethylenetetramine with nitric acid,ammoniumnitrate,andaceticanhydride: It is also used as a rat poison.

Definition

ChEBI: An N-nitro compound that is 1,3,5-triazinane in which all three of the hydrogens attached to the nitrogens have been replaced by nitro groups. It is widely used in both industrial and military explosives.

General Description

Cyclotrimethylene trinitramine is an explosive. The explosion can be initiated by a sudden shock, high temperature or a combination of the two. The primary hazard is from blast effect and not from flying projectiles and fragments. Under prolonged exposure to heat or fire they can explode.

Air & Water Reactions

Insoluble in water.

Reactivity Profile

CYCLOTRIMETHYLENE TRINITRAMINE is incompatible with strong oxidizing agents, combustible materials and heat. Detonates on contact with mercury fulminate . Danger of explosion when dry. The self heating and explosive decomposition of the explosive and aqueous alkali (calcium hydroxide) has been studied, [Chem Abs., 1988, 109, 112968].

Health Hazard

Cyclonite is a highly toxic substance. Repeated exposure can cause nausea, vomiting, and convulsions.
LD50 value, oral (rats): 100 mg/kg.

Fire Hazard

MAY EXPLODE AND THROW FRAGMENTS 1600 meters (1 MILE) OR MORE IF FIRE REACHES CARGO.

Safety Profile

Poison by ingestion, intraperitoneal, and intravenous routes. An experimental teratogen. Other experimental reproductive effects. A corrosive irritant to skin, eyes, and mucous membranes. Cases of epileptifonn convulsions have been reported from exposure. It is one of the most powerful high explosives in use today. Has more shattering power than TNT and is often mixed with TNT as a bursting charge for aerial bombs, mines, and torpedoes. It is easily initiated by mercury fulrmnate, which may be used as a booster. When heated to decomposition it emits toxic fumes of NOx. See also MINES, NITRATES, and EXPLOSIVES, HIGH.

Potential Exposure

A potential danger to those involved in the manufacture of this material and its handling in munitions and solid-propellant manufacture. It is also used as a rat poison; a powerful military explosive; a base charge for detonators; and in plastic explosives.

Shipping

UN0483 Cyclotrimethylenetrinitramine, desensi- tized or Cyclonite, desensitized or Hexogen, desensitized or RDX, desensitized, Hazard Class: 1D; Labels: 1D- Explosive (with a mass explosion hazard); D-Substances or articles which may mass detonate (with blast and/or frag- ment hazard) when exposed to fire. UN0072 Cyclotrimethylenetrinitramine, wetted or Cyclonite, wetted or Hexogen, wetted or RDX, wetted with not ,15% water by mass, Hazard Class: 1D; Labels: 1D-Explosive (with a mass explosion hazard); D-Substances or articles which may mass detonate (with blast and/or fragment hazard) when exposed to fire.

Purification Methods

RDX crystallises from acetone. [Bachmann & Sheehan J Am Chem Soc 71 1842 1949, Beilstein 26 II 5, 26 III/IV 22.] EXPLOSIVE.

Incompatibilities

Heat, physical damage, shock, and deto- nators. Detonates on contact with mercury fulminate. Keep away from other explosives, combustibles, oxidizers (such as chlorates, nitrates, perchlorates, permanganates, perox- ides; bromine, chlorine, and fluorine); reducing agents; and aqueous alkaline solutions.

Waste Disposal

Pour over soda ash, neutralize and flush to sewer with water. Also HMX may be recov- ered from solid propellant waste.

HEXAHYDRO-1,3,5-TRINITRO-1,3,5-TRIAZINE Preparation Products And Raw materials

Raw materials

Preparation Products

HEXAHYDRO-1,3,5-TRINITRO-1,3,5-TRIAZINE HEXOGEN 1,3,5-TRINITRO-1,3,5-TRIAZACYCLOHEXANE RDX T4 TRIMETHYLENE TRINITRAMINE RDX,1X1ML, ACN 1000UG/ML SPHERICAL 1,3,5-TRINITRO-1,3,5-TRIAZACYCLOHEXANE Trinitromethylenetriamine 1,3,5-Triaza-1,3,5-Trinitrocyclohexane LABOTEST-BB LT00044464 1,3,5-trinitro-1,3,5-triazinan solution rdx solution 1,3,5-TRINITRO-1,3,5-HEXAHYDROTRIAZINE S-TRIMETHYLENETRINITRAMINE HEXAHYDRO-1,3,5-TRINITROTRIAZINE 1,3,5-TRINITRO-1,3,5-TRIAZINE 1,3,5-Trinitro-1,3,5-perhydrotriazine 1,3,5-Trinitro-1,3,5-triazinan solution, Cyclotrimethylentrinitramin, Hexogen Inactive-cyclonite Hexahydro-1,3,5-Trinitro-1,3,5-Triazine,0.1 mg/mL in MeOH:AcCN (1:1) Hexogen, Cyclonite, RDX RDX (Hexahydro-1,3,5-trinitro-1,3,5-triazine) Cyclotrimethylentrinitramin DFNB24 3,5-Triazine,hexahydro-1,3,5-trinitro-1 5-triazine,hexahydro-1,3,5-trinitro-3 5-triazine,perhydro,1,3,5-trinitro-3 cx84a Cyclonite Cyclotrimethylenenitramine cyclotrimethylenetrinitramine,[desensitized] cyclotrimethylenetrinitramine,[wetwith>=10%water] Cyklonit Esaidro-1,3,5-trinitro-1,3,5-triazina Geksogen Heksogen heksogen(polish) Hexahydro-1,3,5-trinitro-1,3,5-triazin hexahydro-1,3,5-trinitro-s-triazin Hexahydro-1,3,5-trinitro-s-triazine Hexogeen Hexogen (explosive) Hexogen 5W hexogen(explosive) Hexogen1,3,5-Trinitrohexahydro-1,3,5-triazine hexogen5w hexolite[qr] khp281 PBX(AF) 108 pbx(af)108 PBXW 108(E) pbxw108(e) pe4 perhydro-1,3,5-trinitro-1,3,5-triazine s-Triazine, hexahydro-1,3,5-trinitro- s-triazine,hexahydro-1,3,5-trinitro- sym-Trimethylenetrinitramine