CYCLOPROPYL PHENYL SULFIDE
- CAS No.
- 14633-54-6
- Chemical Name:
- CYCLOPROPYL PHENYL SULFIDE
- Synonyms
- CYCLOPROPYL PHENYL S;Cyclopropylthiobenzene;Phenylthiocyclopropane;cyclopropyl(phenyl)sulfane;CYCLOPROPYL PHENYL SULFIDE;1-(Phenylthio)cyclopropane;Benzene, (cyclopropylthio)-;CYCLOPROPYL PHENYL SULPHIDE;CyclopropylPhenylSulfide>(Cyclopropylsulfanyl)benzene
- CBNumber:
- CB7164145
- Molecular Formula:
- C9H10S
- Molecular Weight:
- 150.24
- MOL File:
- 14633-54-6.mol
- MSDS File:
- SDS
- Modify Date:
- 2025/1/27 9:38:02
| Boiling point | 62-63 °C/1 mmHg (lit.) |
|---|---|
| Density | 1.045 g/mL at 25 °C (lit.) |
| refractive index |
n |
| Flash point | 197 °F |
| form | clear liquid |
| color | Colorless to Light yellow to Light orange |
| BRN | 2075701 |
| CAS DataBase Reference | 14633-54-6(CAS DataBase Reference) |
SAFETY
Risk and Safety Statements
| Symbol(GHS) |  GHS07 |
|||||||||
|---|---|---|---|---|---|---|---|---|---|---|
| Signal word | Warning | |||||||||
| Hazard statements | H315-H319-H335 | |||||||||
| Precautionary statements | P261-P264-P271-P280-P302+P352-P305+P351+P338 | |||||||||
| Hazard Codes | Xi | |||||||||
| Risk Statements | 36/37/38 | |||||||||
| Safety Statements | 26-36/37/39 | |||||||||
| RIDADR | UN 2810 6.1/PG 3 | |||||||||
| WGK Germany | 3 | |||||||||
| HazardClass | 9 | |||||||||
| HS Code | 29309090 | |||||||||
| NFPA 704 |
|
CYCLOPROPYL PHENYL SULFIDE price More Price(6)
| Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
|---|---|---|---|---|---|---|---|
| Sigma-Aldrich(India) | 227242 | Cyclopropyl phenyl sulfide 99% | 14633-54-6 | 5G | ₹5715.6 | 2022-06-14 | Buy |
| Sigma-Aldrich(India) | 227242 | Cyclopropyl phenyl sulfide 99% | 14633-54-6 | 25G | ₹19614.9 | 2022-06-14 | Buy |
| TCI Chemicals (India) | C1014 | Cyclopropyl Phenyl Sulfide min. 98.0 % | 14633-54-6 | 5G | ₹6300 | 2022-05-26 | Buy |
| ALFA India | ALF-L12321-06 | Cyclopropyl phenyl sulfide, 98+% | 14633-54-6 | 5g | ₹6378 | 2022-05-26 | Buy |
| TCI Chemicals (India) | C1014 | Cyclopropyl Phenyl Sulfide min. 98.0 % | 14633-54-6 | 25G | ₹15500 | 2022-05-26 | Buy |
CYCLOPROPYL PHENYL SULFIDE Chemical Properties,Uses,Production
Chemical Properties
CLEAR YELLOWISH LIQUID
Uses
Cyclopropyl phenyl sulfide was used as a reagent in the conversion of a ketone into a spirocyclobutanone.
Synthesis Reference(s)
Synthetic Communications, 10, p. 311, 1980 DOI: 10.1080/00397918008062755
Synthesis
Phenylthiocyclopropane is easily prepared from 1-phenylthio-3-chloropropane (itself obtained on reaction of 1-bromo- 3-chloropropane and phenylthiolates) and Potassium Amide in liquid ammonia (eq 1).
1,3-Bis(phenylthio)propane reacts with n-Butyllithium in THF to produce Phenylthiocyclopropane on reaction with only 1 equiv n-Buli, or 1-lithio-1-phenylthiocyclopropane (2) if 2 equiv are used (eq 2).
Phenylthiocyclopropane has also been synthesized from 3-tributylstannylpropanal (available from tributylstannyllithium and Acrolein) and trimethylsilyl phenyl sulfide in the presence of Titanium(IV) Chloride as acid catalyst (eq 3), and on substitution of (i) Cyclopropyllithium with Diphenyl Disulfide (eq 4), (ii) cyclopropyl bromide with potassium benzenethiolate (eq 5) or (iii) 1,1-dibromocyclopropane, also with benzenethiolates, and by reduction of α- bromocyclopropyl phenyl sulfide with sodium methanethiolate (eq 6). In addition, cyclopropyl phenyl sulfoxide can be reduced to (1) in more than 70% yield with Chlorotrimethylstannane-benzenethiol (eq 7).
CYCLOPROPYL PHENYL SULFIDE Preparation Products And Raw materials
| Supplier | Tel | Country | ProdList | Advantage | Inquiry |
|---|---|---|---|---|---|
| GLR Innovations | +91 9891111994 | New Delhi, India | 4535 | 58 | Inquiry |
| 5 E Scientific | 91-22-28016026 | Maharashtra, India | 136 | 58 | Inquiry |
| Agadvi Research Laboratory (P) Ltd. | 91-9632511855 | Karnataka, India | 4 | 58 | Inquiry |
| ALLCHEM LIFESCIENCE PVT. LTD | +91 957 472 2211 | New Delhi, India | 317 | 58 | Inquiry |
| TCI Chemicals (India) Pvt. Ltd. | 1800 425 7889 | New Delhi, India | 6768 | 58 | Inquiry |
| Alfa Aesar | 1 800 209 7001 | Maharashtra, India | 6905 | 58 | Inquiry |
| Eburon Organics (I) Pvt, Ltd | +91 260 240 0894 | Gujarat, India | 114 | 58 | Inquiry |
| Henan Fengda Chemical Co., Ltd | +86-371-86557731 +86-13613820652 | China | 20235 | 58 | Inquiry |
| Capot Chemical Co.,Ltd. | +86-（0）57185586718 +86-13336195806 | China | 29730 | 60 | Inquiry |
| Shanghai Daken Advanced Materials Co.,Ltd | +86-371-+86-371-66670886 | China | 19805 | 58 | Inquiry |
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