1,3,5,7-Cyclooctatetraene
![1,3,5,7-Cyclooctatetraene Structure](CAS/GIF/629-20-9.gif)
- CAS No.
- 629-20-9
- Chemical Name:
- 1,3,5,7-Cyclooctatetraene
- Synonyms
- COT;ESTF;C-COT;TPL-2;1,3,5,7-c;1,3,5,7-COT;[8]Annulene;Cot active mouse;CYCLOOCTATETRAENE;CycloctateTraene.
- CBNumber:
- CB7164468
- Molecular Formula:
- C8H8
- Molecular Weight:
- 104.15
- MOL File:
- 629-20-9.mol
- MSDS File:
- SDS
- Modify Date:
- 2023/12/26 11:30:52
Melting point | ?5-?3 °C (lit.) |
---|---|
Boiling point | 142-143 °C (lit.) |
Density | 0.925 g/mL at 25 °C (lit.) |
refractive index |
n |
Flash point | 72 °F |
storage temp. | -20°C |
solubility | Chloroform (Soluble), Methanol (Soluble) |
form | Liquid |
Specific Gravity | 0.943 |
color | Turbid yellow to yellow-brown |
Water Solubility | Not miscible or difficult to mix in water. |
Sensitive | Light Sensitive |
BRN | 2496800 |
Dielectric constant | 2.46 |
Stability | Stability Unstable - commercial product may be stabilized by the addition of a small amount of hydroquinone. May form explosive peroxides in storage. Do not distill to small volume. Readily forms explosive mixtures with air. Flammable. Incompatible with air, strong oxidizing agents. |
LogP | 3.080 |
CAS DataBase Reference | 629-20-9(CAS DataBase Reference) |
EPA Substance Registry System | 1,3,5,7-Cyclooctatetraene (629-20-9) |
SAFETY
Risk and Safety Statements
Symbol(GHS) | ![]() ![]() ![]() GHS02,GHS07,GHS08 |
|||||||||
---|---|---|---|---|---|---|---|---|---|---|
Signal word | Danger | |||||||||
Hazard statements | H225-H304-H315-H319-H335 | |||||||||
Precautionary statements | P210-P233-P301+P310-P303+P361+P353-P305+P351+P338-P331 | |||||||||
Hazard Codes | Xn,Xi,T | |||||||||
Risk Statements | 10-36/37/38-65-61 | |||||||||
Safety Statements | 26-62-45-53 | |||||||||
RIDADR | UN 2358 3/PG 2 | |||||||||
WGK Germany | 3 | |||||||||
RTECS | GY0175600 | |||||||||
F | 8-10 | |||||||||
TSCA | Y | |||||||||
HazardClass | 3 | |||||||||
PackingGroup | II | |||||||||
HS Code | 29021900 | |||||||||
NFPA 704 |
|
1,3,5,7-Cyclooctatetraene price More Price(8)
Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
---|---|---|---|---|---|---|---|
Sigma-Aldrich(India) | SAB4500410 | Anti-COT antibody produced in rabbit affinity isolated antibody | 629-20-9 | 100μG | ₹50560.5 | 2022-06-14 | Buy |
Sigma-Aldrich(India) | SAB2501715 | Anti-Crot (C-terminal) antibody produced in goat affinity isolated antibody, buffered aqueous solution | 629-20-9 | 100μG | ₹53135.7 | 2022-06-14 | Buy |
Sigma-Aldrich(India) | 138924 | Cyclooctatetraene 98% | 629-20-9 | 1G | ₹5836.2 | 2022-06-14 | Buy |
Sigma-Aldrich(India) | 138924 | Cyclooctatetraene 98% | 629-20-9 | 5G | ₹11795.7 | 2022-06-14 | Buy |
ALFA India | ALF-B22636-14 | 1,3,5,7-Cyclooctatetraene, 98%, stab. with 0.1% Hydroquinone | 629-20-9 | 25g | ₹65417 | 2022-05-26 | Buy |
1,3,5,7-Cyclooctatetraene Chemical Properties,Uses,Production
Chemical Properties
1,3,5,7-Cyclooctatetraene (COT) is an unsaturated derivative of cyclooctane, with the formula C8H8. It is also known as [8]annulene. This polyunsaturated hydrocarbon is a colorless to light yellow flammable liquid at room temperature. Because of its stoichiometric relationship to benzene, COT has been the subject of much research and some controversy.
Uses
1,3,5,7-Cyclooctatetraene is used in the synthesis of highly organic film for silicon surfaces to improve its chemical and physical properties. It is also used in liquid state organic dye lasers, as triplet state quencher to reduce dye blinking.
Definition
ChEBI: An antiaromatic annulene that is cyclooctane having four double bonds at positions 1, 3, 5 and 7.
General Description
A colorless liquid. May irritate skin and eyes. Less dense than water and insoluble in water. Flash point 70°F. Vapors heavier than air. Used to make rubber.
Air & Water Reactions
Highly flammable. Insoluble in water.
Reactivity Profile
1,3,5,7-CYCLOOCTATETRAENE may react vigorously with strong oxidizing agents. May react exothermically with reducing agents to release hydrogen gas.
Health Hazard
Inhalation or contact with material may irritate or burn skin and eyes. Fire may produce irritating, corrosive and/or toxic gases. Vapors may cause dizziness or suffocation. Runoff from fire control or dilution water may cause pollution.
Purification Methods
Purify the triene by shaking 3mL with 20mL of 10% aqueous AgNO3 for 15minutes, then filtering off the AgNO3 complex which precipitates. The precipitate is dissolved in water and added to cold concentrated ammonia to regenerate the cyclooctatetraene which is fractionally distilled under vacuum onto molecular sieves and stored at 0o. It is passed through a dry alumina column before use [Broadley et al. J Chem Soc, Dalton Trans 373 1986]. [Beilstein 5 I 228, 5 IV 1331.]
1,3,5,7-Cyclooctatetraene Preparation Products And Raw materials
Supplier | Tel | Country | ProdList | Advantage | Inquiry |
---|---|---|---|---|---|
Clearsynth Labs | 91-22-45045900 | Maharashtra, India | 3889 | 58 | Inquiry |
TCI Chemicals (India) Pvt. Ltd. | 1800 425 7889 | New Delhi, India | 6778 | 58 | Inquiry |
Alfa Aesar | 1 800 209 7001 | Maharashtra, India | 6913 | 58 | Inquiry |
Henan Fengda Chemical Co., Ltd | +86-371-86557731 +86-13613820652 | China | 20361 | 58 | Inquiry |
SHANGHAI T&W PHARMACEUTICAL CO., LTD. | +86-021-61551413 +8618813727289 | China | 5738 | 58 | Inquiry |
Career Henan Chemica Co | +86-0371-86658258 +8613203830695 | China | 30253 | 58 | Inquiry |
Shaanxi Didu New Materials Co. Ltd | +86-89586680 +86-13289823923 | China | 9003 | 58 | Inquiry |
PT CHEM GROUP LIMITED | +86-85511178 +86-85511178 | China | 35451 | 58 | Inquiry |
LEAPCHEM CO., LTD. | +86-852-30606658 | China | 43348 | 58 | Inquiry |
Aladdin Scientific | +1-+1(833)-552-7181 | United States | 57511 | 58 | Inquiry |
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