(S)-(-)-3-CYCLOHEXENECARBOXYLIC ACID
- CAS No.
- 5708-19-0
- Chemical Name:
- (S)-(-)-3-CYCLOHEXENECARBOXYLIC ACID
- Synonyms
- (S)-cyclohex-3-ene-1-carboxylic acid;(S)-Cyclohex-3-enecarboxylic acid;(S)-3-Cyclohexene-1-carboxylic Acid;(1S)-cyclohex-3-ene-1-carboxylic acid;(S)-(-)-3-CYCLOHEXENEC;(S)-(-)-3-CYCLOHEXENECARBOXYLICA;(S)-(-)-3-Cyclohexenecaboxylic acid;(S)-(-)-3-cyclohexencarboxylic acid;(1S)-cyclohex-3-ene-1-carboxylicaci;(1S)-3-Cyclohexene-1-carboxylic acid
- CBNumber:
- CB7374252
- Molecular Formula:
- C7H10O2
- Molecular Weight:
- 126.15
- MOL File:
- 5708-19-0.mol
- MSDS File:
- SDS
- Modify Date:
- 2024/3/22 17:12:53
| Melting point | 19°C(lit.) |
|---|---|
| Boiling point | 118°C/6mmHg(lit.) |
| Density | 1.126±0.06 g/cm3(Predicted) |
| refractive index | 1.4780 to 1.4820 |
| storage temp. | Keep in dark place,Inert atmosphere,Room temperature |
| form | clear liquid |
| pka | 4.67±0.20(Predicted) |
| color | Colorless to Almost colorless |
| InChI | InChI=1S/C7H10O2/c8-7(9)6-4-2-1-3-5-6/h1-2,6H,3-5H2,(H,8,9)/t6-/m1/s1 |
| InChIKey | VUSWCWPCANWBFG-ZCFIWIBFSA-N |
| SMILES | [C@H]1(C(O)=O)CCC=CC1 |
SAFETY
Risk and Safety Statements
| Symbol(GHS) |  GHS05 |
|||||||||
|---|---|---|---|---|---|---|---|---|---|---|
| Signal word | Danger | |||||||||
| Hazard statements | H314 | |||||||||
| Precautionary statements | P280-P305+P351+P338-P310 | |||||||||
| Hazard Codes | C | |||||||||
| Risk Statements | 34 | |||||||||
| Safety Statements | 26-36/37/39-45 | |||||||||
| RIDADR | UN 3265 8 / PGIII | |||||||||
| HazardClass | 8 | |||||||||
| PackingGroup | III | |||||||||
| HS Code | 2916200090 | |||||||||
| NFPA 704 |
|
(S)-(-)-3-CYCLOHEXENECARBOXYLIC ACID Chemical Properties,Uses,Production
Uses
(S)-(-)-3-CYCLOHEXENECARBOXYLIC ACID can be used as organic synthesis intermediates and pharmaceutical intermediates, mainly used in laboratory research and development processes and chemical production processes.
Synthesis
54.94 g of cyclohex-3-ene-1(S)-carboxylic acid (R)-(+)-methylbenzylamine salt and 18.2 volumes of H2O were charged to a flask at 20-25°C and stirred. To the mixture obtained further 6.7 volumes of H2O and 10 volumes of EtOAc were added. The mixture obtained was stirred for 15 min, the phases were separated and the organic layer was discarded. The aqueous layer was treated with 10 volumes of MTBE and 2.5 equivalents of 6M HCI were added slowly. The mixture obtained was stirred and two layers were formed, separated and the aqueous layer was extracted with MTBE. The organic layers obtained were combined and washed with aqueous, 30percent NaCl solution. The organic phase obtained was dried over Na2S04, filtered, and from the filtrate obtained solvent was removed in vacuo. Cyclohex-3-ene-1(S)-carboxylic acid in the form of a clear oil was obtained. Yield: 26.13 g (93.3percent of theory).
(S)-(-)-3-CYCLOHEXENECARBOXYLIC ACID Preparation Products And Raw materials
| Supplier | Tel | Country | ProdList | Advantage | Inquiry |
|---|---|---|---|---|---|
| CNS CHEMICALS | +91-9381957258 +91-9381957258 | Telangana, India | 354 | 58 | Inquiry |
| CLEARSYNTH LABS LTD. | +91-22-45045900 | Hyderabad, India | 6351 | 58 | Inquiry |
| A.J Chemicals | 91-9810153283 | New Delhi, India | 6124 | 58 | Inquiry |
| TCI Chemicals (India) Pvt. Ltd. | 1800 425 7889 | New Delhi, India | 6778 | 58 | Inquiry |
| ALTAIR ALCHEMY Laboratories | 91--9014276848 | Hyderabad, India | 324 | 58 | Inquiry |
| Cns Chemicals | 08066085913Ext 735 | Hyderabad, India | 262 | 58 | Inquiry |
| Clearsynth Labs | 91-22-45045900 | Maharashtra, India | 3889 | 58 | Inquiry |
| Zhengzhou Anbu Chem Co.,Ltd | +86-0371-88006763; +8615988602810 | China | 3000 | 58 | Inquiry |
| Henan Fengda Chemical Co., Ltd | +86-371-86557731 +86-13613820652 | China | 20296 | 58 | Inquiry |
| Capot Chemical Co.,Ltd. | 571-85586718 +8613336195806 | China | 29798 | 60 | Inquiry |
| Supplier | Advantage |
|---|---|
| CNS CHEMICALS | 58 |
| CLEARSYNTH LABS LTD. | 58 |
| A.J Chemicals | 58 |
| TCI Chemicals (India) Pvt. Ltd. | 58 |
| ALTAIR ALCHEMY Laboratories | 58 |
| Cns Chemicals | 58 |
| Clearsynth Labs | 58 |
| Zhengzhou Anbu Chem Co.,Ltd | 58 |
| Henan Fengda Chemical Co., Ltd | 58 |
| Capot Chemical Co.,Ltd. | 60 |