Bromochloromethane
- CAS No.
- 74-97-5
- Chemical Name:
- Bromochloromethane
- Synonyms
- CH2ClBr;CHLOROBROMOMETHANE;CBM;halon1011;chlorobrom;Halon 1011;halon-1011;BromochL;ai3-15514;MIL-B-4394-B
- CBNumber:
- CB7402908
- Molecular Formula:
- CH2BrCl
- Molecular Weight:
- 129.38
- MOL File:
- 74-97-5.mol
- MSDS File:
- SDS
- Modify Date:
- 2024/3/14 15:18:27
| Melting point | −88 °C(lit.) |
|---|---|
| Boiling point | 68 °C(lit.) |
| Density | 1.991 g/mL at 25 °C(lit.) |
| vapor density | 4.5 (vs air) |
| vapor pressure | 117 mm Hg ( 20 °C) |
| refractive index |
n |
| Flash point | 11 °C |
| storage temp. | 2-8°C |
| solubility | Soluble in acetone, alcohol, benzene, ether (Weast, 1986), and many other solvents, particularly chlorinated hydrocarbons. |
| Specific Gravity | 1.991 |
| Water Solubility | 9 g/L (20 ºC) |
| BRN | 1730801 |
| Henry's Law Constant | (x 10-3 atm?m3/mol): 1.44 at 25 °C (approximate - calculated from water solubility and vapor pressure) |
| Exposure limits | NIOSH REL: TWA 200 ppm (1,050 mg/m3), IDLH 2,000 ppm; OSHA PEL: TWA 200 ppm; ACGIH TLV: TWA 200 ppm (adopted) |
| Dielectric constant | 7.8（Ambient） |
| Stability | Stable, but may discolour in light. Incompatible with aluminium, magnesium, zinc, calcium, strong oxidizing agents. |
| LogP | 1.410 |
| CAS DataBase Reference | 74-97-5(CAS DataBase Reference) |
| NIST Chemistry Reference | Methane, bromochloro-(74-97-5) |
| EPA Substance Registry System | Halon 1011 (74-97-5) |
SAFETY
Risk and Safety Statements
| Symbol(GHS) |   GHS05,GHS07 |
|||||||||
|---|---|---|---|---|---|---|---|---|---|---|
| Signal word | Danger | |||||||||
| Hazard statements | H315-H318-H332-H335-H420 | |||||||||
| Precautionary statements | P261-P280-P305+P351+P338 | |||||||||
| Hazard Codes | Xi,N,Xn,T,F | |||||||||
| Risk Statements | 37/38-41-59-36/37/38-20-39/23/24/25-23/24/25-11-36/38 | |||||||||
| Safety Statements | 26-39-59-37/39-45-36/37-16-7 | |||||||||
| RIDADR | UN 1887 6.1/PG 3 | |||||||||
| OEB | A | |||||||||
| OEL | TWA: 200 ppm (1050 mg/m3) | |||||||||
| WGK Germany | 2 | |||||||||
| RTECS | PA5250000 | |||||||||
| Hazard Note | Irritant | |||||||||
| HazardClass | 6.1(b) | |||||||||
| PackingGroup | III | |||||||||
| HS Code | 29034980 | |||||||||
| Toxicity | LC50 (inhalation) for mice 15,850 mg/m3/8-h, rats 28,800 ppm/15-min (quoted, RTECS, 1985). Acute oral LD50 for rats 5,000 mg/kg, mice 4,300 mg/kg (quoted, RTECS, 1985). | |||||||||
| IDLA | 2,000 ppm | |||||||||
| NFPA 704 |
|
Bromochloromethane Chemical Properties,Uses,Production
Chemical Properties
white to light yellow crystal powder
Physical properties
Clear, colorless liquid with a sweet, chloroform-like odor
Uses
Bromochloromethane is used primarily as an extinguishing agent due to its oxygen-depleting properties.
Definition
ChEBI: A one-carbon compound substituted by a chloro and a bromo group.
General Description
A clear colorless liquid with a sweet chloroform-like odor. Denser than water (density 1.991 g / cm3) and insoluble in water. Hence sinks in water. Boiling point 68°C. Vapors may cause illness if inhaled. Nonflammable. When exposed to high temperatures may emit toxic fumes. Used as a fire extinguishing agent.
Air & Water Reactions
Insoluble in water.
Reactivity Profile
Bromochloromethane is sensitive to light (may discolor). Incompatible with strong bases and strong oxidizing agents. Also incompatible with active metals, calcium, aluminum, magnesium, zinc and their alloys. Attacks some forms of plastics, rubber and coatings. .
Hazard
By inhalation.
Health Hazard
Toxic by ingestion. Vapors may cause dizziness or suffocation. Exposure in an enclosed area may be very harmful. Contact may irritate or burn skin and eyes. Fire may produce irritating and/or toxic gases. Runoff from fire control or dilution water may cause pollution.
Fire Hazard
Some of these materials may burn, but none ignite readily. Most vapors are heavier than air. Air/vapor mixtures may explode when ignited. Container may explode in heat of fire.
Safety Profile
Mildly toxic by ingestion and inhalation. Mutation data reported. This material has a narcotic action of moderate intensity, although of prolonged duration. Animals exposed for several weeks to 1000 pprn had blood bromide levels as high as 350 mgl100 g. Therefore, until further data are available, it should be considered at least as toxic as carbon tetrachloride and more than minimal exposure to its vapors should be avoided. Dangerous; when heated to decomposition it emits highly toxic fumes of Brand Cl-. See also BROMIDES and CHLORINATED HYDROCARBONS, ALIPHATIC.
Potential Exposure
This compound is used in brominated flame retardants; a fire-extinguishing agent; and in organic synthesis
Carcinogenicity
The U.S. EPA classification is D (not classifiable as to human carcinogenicity). Bromochloromethane is structurally similar to dichloromethane (methylene chloride), which is classified B2 (probable human carcinogen). The classification is based on the lack of data regarding the carcinogenicity of bromochloromethane in humans or animals; however, there are data indicative of genotoxic effects and structural relationships to halogenated methanes classified as B2 (probable human carcinogens).
Environmental Fate
Biological. When bromochloromethane (5 and 10 mg/L) was statically incubated in the dark at
25 °C with yeast extract and settled domestic wastewater inoculum for 7 d, 100% biodegradation
with rapid adaptation was observed (Tabak et al., 1981).
Photolytic. The following rate constants were reported for the reaction of bromochloromethane
and OH radicals as measured by both flash photolysis resonance fluorescence and discharge flow
electron paramagnetic resonance techniques (x 10-13 cm3/molecule?sec): 0.91 at 4 °C, 1.11–1.13 at
25 °C, 1.32–1.34 at 40 °C, 1.55–1.58 at 57 °C, 1.76–1.90 at 76 °C, 2.10–2.26 at 97 °C (Orkin et
al., 1997).
Chemical/Physical. Although no products were identified, the estimated hydrolysis half-life in
water at 25 °C and pH 7 is 44 yr (Mabey and Mill, 1978). Bromochloromethane reacts with
bisulfide ion (HS-), produced by microbial reduction of sulfate, forming 1,3,5-trithiane and
dithiomethane. Estimated reaction rate constants at 25 and 35 °C were 7.29 x 10-5 and 2.42 x 10-
4/M?sec, respectively (Roberts et al., 1992).
Shipping
UN1887 Bromochloromethane, Hazard Class: 6.1; Labels: 6.1-Poisonous materials.
Incompatibilities
Incompatible with strong oxidizers (possible explosion), reducing agents, bases, carbonates, furyl alcohol, chemically active metals, such as calcium; base metals in the presence of moisture, powdered aluminum; zinc, magnesium. Liquid attacks some plastics, rubber, and coatings.
Waste Disposal
Incinerate together with flammable solvent in furnace equipped with afterburner and alkali scrubber.
Bromochloromethane Preparation Products And Raw materials
Raw materials
Preparation Products
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