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KADETHRIN

KADETHRIN Structure
CAS No.
58769-20-3
Chemical Name:
KADETHRIN
Synonyms
ru15525;ent29117;spray-tox;KADETHRIN;AI3-29117;Kadethrine;BRN 1605066;cis-kadethrin;1r,cis-ru15525;EINECS 261-433-0
CBNumber:
CB7406047
Molecular Formula:
C23H24O4S
Molecular Weight:
396.5
MOL File:
58769-20-3.mol
Modify Date:
2024/12/18 14:15:30

KADETHRIN Properties

Melting point 31℃
Boiling point 526.2±50.0 °C(Predicted)
Density 1.278±0.06 g/cm3(Predicted)
vapor pressure 5×10-6Pa (20 °C)
Flash point 100 °C
storage temp. 0-6°C
Water Solubility 1mg l-1(20°C)
EPA Substance Registry System Kadethrin (58769-20-3)

SAFETY

Risk and Safety Statements

Symbol(GHS) 
GHS07,GHS09
Signal word  Warning
Hazard statements  H410-H312-H302-H332
Precautionary statements  P264-P270-P301+P312-P330-P501-P273-P391-P501-P280-P302+P352-P312-P322-P363-P501-P261-P271-P304+P340-P312
Hazard Codes  Xn,N
Risk Statements  20/21/22-50/53
Safety Statements  13-60-61
RIDADR  UN 3082 9/PG 3
RTECS  GZ1266550
Hazardous Substances Data 58769-20-3(Hazardous Substances Data)

KADETHRIN Chemical Properties,Uses,Production

Uses

Kadethrin is used to control household pests, particularly houseflies, mosquitoes and cockroaches. It is normally used in combination with other pyrethroid insecticides and synergists.

Metabolic pathway

Kadethrin is used almost wholly indoors and therefore little has been published on its environmental fate. Information on its photodegradation and metabolism in rats has been reported.

Degradation

Kadethrin is unstable to heat and it is rapidly decomposed by light. It is hydrolysed in aqueous alkaline solution to (E)-(1R)-cis-2,2-dimethyl-3- (2-oxothiolan-3-ylidenemethyl)cyclopropanecarboxylic acid (2), 5-benzyl- 3-furylmethanol (3) and its thiolactone ring-opened derivative (5) (Scheme 1).
Products of photodecomposition have been reported by Ohsawa and Casida (1979). Photo-hydrolysis of kadethrin occurs on sunlight irradiation affording 2 and 5 and 5-benzyl-3-furancarboxylic acid (4), presumably via the alcohol (3). cis-trans Isomerisation of the cyclopropane ring and E-Z interconversion about the double bond was also noted. Thus, from the lRcisE isomer (kadethrin), all of the possible isomers were found to varying degrees (ie. 1RScis-trans-E-Z mixtures).
Photo-hydrolysis products (e.g. 2 and 5) were also found aS isomers. The facility of the isomerisation process was considered to be due to resonance stabilisation of a triplet diradical, one form of which (6) is shown in Scheme 1. Kadethrin also yielded a lactone (7) derived from the cyclopropane ring. Photo-oxidation of the alcohol moiety analogous to that reported for resmethrin was also found. The hydroxylactone (8) and the benzyloxylactone (9) were reported (but the hydroxycyclopetenolone [resmethrin, 61) was absent.

KADETHRIN Preparation Products And Raw materials

Raw materials

Preparation Products

KADETHRIN Suppliers

Global( 51)Suppliers
Supplier Tel Country ProdList Advantage Inquiry
Shaanxi Dideu Medichem Co. Ltd +86-29-87569266 15319487004 China 3954 58 Inquiry
TargetMol Chemicals Inc. +1-781-999-5354 +1-00000000000 United States 32251 58 Inquiry
SUZHOU SENFEIDA CHEMICAL CO.,LTD +86-0512-83500002 +8618501500038 China 26362 58 Inquiry
Chongqing Chemdad Co., Ltd +86-023-6139-8061 +86-86-13650506873 China 39927 58 Inquiry
58896805 CHINA 15620 58 Inquiry
4008-099-669 CHINA 73043 58 Inquiry
Absin Bioscience Inc. 021-38015121-8802 CHINA 6208 58 Inquiry
Hebei Zhenjia new material Co., LTD 0319-5925599 13315915972 China 2916 58 Inquiry
Santa Cruz Biotechnology Inc 60936350 China 222068 58 Inquiry
Interchim S.A. (33) 4 70 03 88 55 France 6302 76 Inquiry
[1r-[1alpha,3alpha(e)]]-[5-(phenylmethyl)-3-furanyl]methyl3-[(dihydro-2-ox 1r,cis-ru15525 3-((dihydro-2-oxo-3(2h)-thienylidene)methyl)-2,2-dimethyl-,(5-(phenylmethyl)-3-furanyl)methylester,cyclopropanecarboxylicaci 5-benzyl-3-furylmethyl 5-benzyl-3-furylmethyl(+)-cis-(1r,3s,e)2,2-dimethyl-3-(2-oxo-2,3,4,5-tetrahydrothiophenylidenemethy 5-benzyl-3-furylmethyl(e)-(1r)-cis-2,2-dimethyl-3-(2-oxothiolan-3-ylidenemeth 5-benzyl-3-furylmethyl(e)-(1r,3s)-2,2-dimethyl-3-(2-oxothiolan-3-ylidenemethyl [5-(PHENYLMETHYL)-3-FURANYL]-METHYL-3-[(DIHYDRO-2-OXO-3(2H)-THIENYLIDENE) METHYL]-2,2-DIMETHYLCYCLOPROPANE [5-benzyl-3-furyl]methyl [1R-[1alpha,3alpha(E)]]-3-[(dihydro-2-oxo-3(2H)-thienylidene)methyl]-2,2-dimethylcyclopropanecarboxylate KADETHRIN PESTANAL 250 MG KADETHRIN PESTANAL Kadethrine KADETHRINE STANDARD (1R,3S)-3-[[(E)-4,5-Dihydro-2-oxothiophen-3(2H)-ylidene]methyl]-2,2-dimethylcyclopropanecarboxylic acid (5-benzyl-3-furyl)methyl ester 3-((dihydro-2-oxo-3(2h)-thienylidene)methyl)-2,2-dimethyl-,(5-(phenylmethyl)-3-furanyl) (1R,3S)-3-[(E)-(Dihydro-2-oxo-3(2H)-thienylidene)methyl]-2,2-dimethylcyclopropanecarboxylic acid [5-(phenylmethyl)-3-furanyl]methyl ester (5-(phenylmethyl)-3-furanyl)methylester,(1r-(1-alpha,3-alpha(e)))-imethyl )-cyclopropanecarboxylate cis-kadethrin cyclopropanecarboxylicacid,3-((dihydro-2-oxo-3(2h)-thienylidene)methyl)-2,2-d ent29117 o-3(2h)-thienylidene)methyl]-2,2-dimethylcyclopropanecarboxylate ru15525 spray-tox yl)cyclopropanecarboxylate. KADETHRIN UGWALRUNBSBTGI-ZKMZRDRYSA-N Kadethrine@100 μg/mL in Methanol Cyclopropanecarboxylic acid, 3-[(E)-(dihydro-2-oxo-3(2H)-thienylidene)methyl]-2,2-dimethyl-, [5-(phenylmethyl)-3-furanyl]methyl ester, (1R,3S)- AI3-29117 BRN 1605066 EINECS 261-433-0 Caswell No. 516AA Kadethrin in Acetonitrile Vigabatrin Impurity 12 58769-20-3 C23H24O4S Alpha sort Alphabetic H-MAnalytical Standards K Pesticides&Metabolites