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Ethyl chrysanthemumate

Ethyl chrysanthemumate Structure
CAS No.
97-41-6
Chemical Name:
Ethyl chrysanthemumate
Synonyms
ETHYL CHRYSANTHEMATE;PNP-α-D-Gal;Ethyl chrysant;Cyclopropaneca;TIMTEC-BB SBB007714;Ethyl chrisanthemate;Ethyl chrysanthemat.;Ethyl chrysanthemuma;Ethyl ChrsantheMuMate;ETHYL CHRYSANTHEMUMATE
CBNumber:
CB8400077
Molecular Formula:
C12H20O2
Molecular Weight:
196.29
MOL File:
97-41-6.mol
Modify Date:
2023/6/20 14:22:13

Ethyl chrysanthemumate Properties

Boiling point 112 °C10 mm Hg(lit.)
Density 0.906 g/mL at 25 °C(lit.)
refractive index n20/D 1.461(lit.)
Flash point 184 °F
storage temp. 2-8°C
solubility Chloroform (Slightly), Methanol (Slightly)
form Liquid
color Yellow
Odor at 10.00 % in dipropylene glycol. herbal wine fruity everlasting flower chrysanthemum sweet
Odor Type herbal
BRN 2045740
LogP 4.181 (est)
CAS DataBase Reference 97-41-6(CAS DataBase Reference)
NIST Chemistry Reference Ethyl chrysanthemate(97-41-6)
EPA Substance Registry System Cyclopropanecarboxylic acid, 2,2-dimethyl-3-(2-methyl-1-propenyl)-, ethyl ester (97-41-6)

SAFETY

Risk and Safety Statements

Symbol(GHS) 
GHS07
Signal word  Warning
Hazard statements  H227-H303-H315-H319-H335
Precautionary statements  P210-P280-P370+P378-P403+P235-P501-P210e-P261-P280a-P305+P351+P338-P405-P501a
Safety Statements  24/25
WGK Germany  2
RTECS  GZ1727000
TSCA  Yes
HS Code  29162090
NFPA 704
1
0 0

Ethyl chrysanthemumate price More Price(2)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
TCI Chemicals (India) D2112 Ethyl 2,2-Dimethyl-3-(2-methyl-1-propenyl)cyclopropane-1-carboxylate min. 95.0 %(total of isomers) 97-41-6 25G ₹2100 2022-05-26 Buy
TCI Chemicals (India) D2112 Ethyl 2,2-Dimethyl-3-(2-methyl-1-propenyl)cyclopropane-1-carboxylate min. 95.0 %(total of isomers) 97-41-6 100G ₹5600 2022-05-26 Buy
Product number Packaging Price Buy
D2112 25G ₹2100 Buy
D2112 100G ₹5600 Buy

Ethyl chrysanthemumate Chemical Properties,Uses,Production

Chemical Properties

clear colorless to yellow liquid. Very slightly soluble in water, soluble in alcohol and oils. Powerful, winey-herbaccous, sweet and ethereal, very pleasant odor of intriguing complexity, and with a powerfully lifting minty undertone. The spicy-hcrbaccous, warm and almost green-floral notes resemble certain notes in the Jasmin complex.

Uses

Ethyl Chrysanthemate is an organic building block used in the synthesis of various chemical compounds, such as insecticide, Resmethrin (R144685). It is used in the preparation of trans-norchrysanthemates and trans-norpyrethrates, having insecticidal activity.

Purification Methods

Purify the ester by vacuum distillation. The free trans-acid has m 54o (from EtOAc), and the free cis-acid has m 113-116o (from EtOAc). The 4-nitrophenyl ester has m 44-45o (from pet ether) [Campbell & Harper J Chem Soc 283 1945, IR: Allen et al. J Org Chem 22 1291 1957]. [Beilstein 9 II 45.]

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2,2-DIMETHYL-3-(2-METHYL-1-PROPENYL)CYCLOPROPANE CARBOXYLIC ACID ETHYL ESTER 2,2-DIMETHYL-3-(1-ISOBUTENYL)CYCLOPROPANE-1-CARBOXYLIC ACID ETHYL ESTER ethyl 2,2-dimethyl-3-(2-methylpropenyl)cyclopropanecarboxylate CHRYSANTHEMUM MONOCARBOXYLIC ACID ETHYL ESTER CHRYSANTHEMYLMONOCARBOXYLIC ACID ETHYL ESTER ETHYL CHRYSANTHEMUMATE ETHYL 2,2-DIMETHYL-3-(1-ISOBUTENYL)CYCLOPROPANE-1-CARBOXYLATE ETHYL 2,2-DIMETHYL-3-(2-METHYL-1-PROPENYL)CYCLOPROPANECARBOXYLATE TIMTEC-BB SBB007714 Chrisanthemic acid ethylester Ethyl chrisanthemate (+/-)-ETHYL CHRYSANTHEMUMATE, 95%, MIXTU RE OF CIS AND TRANS ETHYL CHRYSANTHEMUMATE 95+% MIXTURE O& Ethyl Chrysanthemate (Primary) Ethyl chrysanthemumate, cis + trans, 98% Primary ethyl chrysanthemat Ethyl chrysanthemat. Chrysanthemum monocarboxylic acid ethyl ester, 2,2-Dimethyl-3-(1-isobutenyl)cyclopropane-1-carboxylic acid ethyl ester ethyl(±)cis,trans-2,2-dimethyl-3-(2-methyl propenyl cyclopropane carboxylate) 2,2-dimethyl-3-(2-methyl-1-propenyl)-cyclopropanecarboxylicaciethylester 2,2-Dimethyl-3-(2-methylpropenyl)cyclopropanecarboxylic acid ethyl ester 2,2-dimethyl-3-(2-methylpropenyl)cyclopropanecarboxylicacidethylester 2,2-dimethyl-3-(2-methylpropenyl)-cyclopropanecarboxylicaciethylester chrysanthemicacidethylester Chrysanthemum-monocarboxlic acid ethyl ester Cyclopropanecarboxylic acid, 2,2-dimethyl-3-(2-methyl-1-propenyl)-, ethyl ester Cyclopropanecarboxylic acid, 2,2-dimethyl-3-(2-methylpropenyl)-, ethyl ester ethylchrysanthemumate,mixtureofcisandtrans Ethyl 2,2-dimethyl-3-(2-methylprop-1-enyl)cyclopropane-1-carboxylate 2,2-Dimethyl-3-isobutenylcyclopropanecarboxylic acid ethyl ester 3-[2-Methyl-1-propenyl]-2,2-dimethylcyclopropanecarboxylic acid ethyl ester 3-Isobutenyl-2,2-dimethyl-1-cyclopropanecarboxylic acid ethyl ester Ethyl chrysanthemate,95%,mixture of cis and trans 2,2-Dimethyl-3-(2-methylpropenyl)-cyclo Ethyl 2,2-Dimethyl-3-(2-methyl-1-propenyl)cyclopropane-1-carboxylate Ethyl chrysanthemumate (cis/trans mixture) Ethyl chrysanthemuma Ethyl chrysanthemate, mixture of cis and trans, 95% Ethyl chrysantheMate, Mixture of cis and trans, 95% 500GR Chrysanthemylmonocarboxylic Acid Ethyl Ester Ethyl Chrysanthemate Ethyl Chrysanthemumate 2,2-Dimethyl-3-(2-methyl-1-propenyl)cyclopropane-1-carboxylic Acid Ethyl Ester Ethyl ChrsantheMuMate ethyl 2,2-diMethyl-3-(2-Methylprop-1-en-1-yl)cyclopropanecarboxylate Cyclopropanecarboxylicacid, 2,2-diMethyl-3-(2-Methyl-1-propen-1-yl)-, ethyl ester Ethyl chrysant 2,2-dimethyl-3-(2-methylprop-1-enyl)-1-cyclopropanecarboxylic acid ethyl ester 2,2-dimethyl-3-(2-methylprop-1-enyl)cyclopropane-1-carboxylic acid ethyl ester Chrysanthemummonocarboxylic acid, ethyl ester (6CI) Cyclopropaneca (1R,3S)-2,2-dimethyl-3-(2-methylprop-1-enyl)-1-cyclopropanecarboxylic acid ethyl ester L.C. Acid (2,2-Dimethyl-3-Trifloro Propenyl Cyclopropane Carbolic Acid) Ethyl2,2-Dimethyl-3-(2-methyl-1-propenyl)cyclopropane-1-carboxylate> Tetramethrin Related Compound 1 PNP-α-D-Gal ETHYL CHRYSANTHEMATE Ethyl 2,2-Dimethyl-3-(2-methyl-1-propenyl)cyclopropane-1-carboxylate, ≥ 95.0% 97-41-6 C12H20O2C12H20O2C12H20O2C12H20O2C12H20O2 Cyclopropanes