ChemicalBook > Product Catalog >Organic Chemistry >Diazo,azo Or azoxy Compounds >Ethyl diazoacetate

Ethyl diazoacetate

CAS No.: 623-73-4

Chemical Name:: Ethyl diazoacetate

Synonyms: Ethyl 2-diazoacetate;Daae;Diazoacetic ester;Ethyl diazoate;diazoaceticester;diazoacetate soL;ETHYL DIAZOACETATE;Ethyl diazoethanoate;Ethylene Diazo Acetate;Diazoacetic acid ethyl

CBNumber:: CB9241343

Molecular Formula:: C4H6N2O2

Molecular Weight:: 114.1

MOL File:: 623-73-4.mol

MSDS File:: SDS

Modify Date:: 2023/5/15 10:43:57

Request For Quotation

Ethyl diazoacetate Properties

Melting point	-22 °C (lit.)
Boiling point	140-141 °C/720 mmHg (lit.)
Density	1.085 g/mL at 25 °C (lit.)
refractive index	n20/D 1.46(lit.)
Flash point	115 °F
storage temp.	2-8°C
solubility	Chloroform (Slightly), DMSO (Soluble), Hexane (Slightly), Methanol (Slightly)
form	Oil
color	Light Yellow to Orange
Merck	13,3021
BRN	107654
NIST Chemistry Reference	Ethyl diazoacetate(623-73-4)

SAFETY

Risk and Safety Statements

Symbol(GHS)	GHS02,GHS07,GHS08
Signal word	Warning
Hazard statements	H226-H242-H302-H315-H319-H351
Precautionary statements	P210-P301+P312-P303+P361+P353-P308+P313-P370+P378-P403+P235
Hazard Codes	Xn,F
Risk Statements	5-10-22-40-67-65-48/20-38-11-63
Safety Statements	36/37-62-16
RIDADR	UN 1993 3/PG 3
WGK Germany	3
RTECS	AG5775000
HazardClass	3.2
PackingGroup	III
HS Code	29270000

Ethyl diazoacetate price More Price(3)

Manufacturer	Product number	Product description	CAS number	Packaging	Price	Updated	Buy
Sigma-Aldrich(India)	752150	Ethyl diazoacetate solution 15% in toluene	623-73-4	25ML	₹3591	2022-06-14	Buy
Sigma-Aldrich(India)	E22201	Ethyl diazoacetate contains ≥13?wt. % dichloromethane	623-73-4	1KG	₹103378.75	2022-06-14	Buy
Sigma-Aldrich(India)	752150	Ethyl diazoacetate solution 15% in toluene	623-73-4	100ML	₹7594.3	2022-06-14	Buy

Product number	Packaging	Price	Buy
752150	25ML	₹3591	Buy
E22201	1KG	₹103378.75	Buy
752150	100ML	₹7594.3	Buy

Ethyl diazoacetate Chemical Properties,Uses,Production

Chemical Properties

Liquid.

Uses

Reagent for ruthenium-catalyzed asymmetric cyclopropanation of alkenes.1

Hazard

Flammable liquid that explodes when heated.

Safety Profile

Poison by ingestion and intravenous routes. Questionable carcinogen with experimental carcinogenic and tumorigenic data. Can explode. Explodes on contact with tris(dimethy1amino) antimony. When heated to decomposition it emits toxic fumes of NOx. See also ESTERS.

Purification Methods

It is a very volatile yellow oil with a strong pungent odour. EXPLOSIVE [distillation even under reduced pressure is dangerous and may result in an explosion — TAKE ALL THE NECESSARY PRECAUTIONS IF DISTILLATION IS TO BE CARRIED OUT]. It explodes in contact with conc H2SO4-trace acid causes rapid decomposition. It is slightly soluble in H2O, but is miscible with EtOH, *C6H6, pet ether and Et2O. To purify, dissolve it in Et2O [using CH2Cl2 instead of Et2O, protects the ester from acid], wash it with 10% aqueous Na2CO3, dry (MgSO4), filter and repeat as many times as possible until the Et2O layer loses its yellow colour, then remove the solvent below 20o (vacuum). Note that prolonged heating may lead to rapid decomposition and low yields. It can also be purified by steam distillation under reduced pressure but with considerable loss in yield. Place the residual oil in a brown bottle, keep below 10o, and use as soon as possible without distilling. For preparing esters usually the ethereal solution is used directly without purification. [Womack & Nelson Org Synth Coll Vol III 392 1955, UV: Miller & White J Am Chem Soc 79 5974 1957, Fieser 1 367 1967, Beilstein 3 IV 1495.]

Ethyl diazoacetate Preparation Products And Raw materials

Raw materials

Buffer solution, pH 1.00 (±0.01 at 25°C), No Color, Specpure, NIST Traceable Glycine ethyl ester hydrochloride Permethric acid Ethyl acetate

Preparation Products

2,2-Dimethyl-3-(2-methylpropyl)cyclopropanecarboxylic acid p-(methoxymethyl)benzyl ester Ethyl chrysanthemumate ethyl glycinate Ethyl glycolate Benzeneacetic acid, α-(hydroxymethylene)-, ethyl ester, (αZ)-

Heptanoic acid, 2-methyl-3-oxo-, ethyl ester 2-Pentenedioic acid, diethyl ester, (Z)- (9CI) 2-Oxiranecarboxylicacid, 3-(trichloromethyl)-, ethyl ester ETHYL 3-BUTYNOATE ETHYL 3-METHOXYPHENYLACETATE

Ethyl 4-methoxycinnamate 2-HYDROXYMETHYL-CYCLOPROPANECARBOXYLIC ACID ETHYL ESTER Diethyl iminodiacetate ethyl 5-(hydroxymethyl)-1H-pyrazole-3-carboxylate

chevron_left

1of3

chevron_right

Ethyl diazoacetate Suppliers

Global( 170)Suppliers

Supplier	Tel	Country	ProdList	Advantage	Inquiry
REDDY N REDDY PHARMACEUTICALS	+91-9848096759 +91-9848096759	Hyderabad, India	1989	58	Inquiry
JSK Chemicals	+919879767970	Gujarat, India	3756	58	Inquiry
ALS INDIA LIFE SCIENCES	+91-8977036379 +91-8977036379	Hyderabad, India	1879	58	Inquiry
Innovative Labs	+91-9885794886 +91-9885794886	Telangana, India	219	58	Inquiry
HYCHEM SAINOR CHEMICALS PVT LTD	+919391007257	Telangana, India	205	58	Inquiry
Reddy N Reddy Pharmaceuticals	+91 (40) 2307-5686 / +91 98480-96759 / +91 98481-96759	New Delhi, India	254	0	Inquiry
CHEMSWORTH	+91-261-2397244	New Delhi, India	6707	30	Inquiry
CLEARSYNTH LABS LTD.	+91-22-45045900	Hyderabad, India	6351	58	Inquiry
G. M. Fine Chemicals	09000223396	Hyderabad, India	5	58	Inquiry
Quiver Technologies	08048371749Ext 307	Hyderabad, India	169	58	Inquiry

Supplier	Advantage
REDDY N REDDY PHARMACEUTICALS	58
JSK Chemicals	58
ALS INDIA LIFE SCIENCES	58
Innovative Labs	58
HYCHEM SAINOR CHEMICALS PVT LTD	58
Reddy N Reddy Pharmaceuticals	0
CHEMSWORTH	30
CLEARSYNTH LABS LTD.	58
G. M. Fine Chemicals	58
Quiver Technologies	58

Ethyl diazoacetate Spectrum

Ethyl diazoacetate(623-73-4)IR Ethyl diazoacetate(623-73-4)Raman

623-73-4(Ethyl diazoacetate)Related Search:

Ethylparaben Ethyl acrylate Ethyl acetate Ethanol Ethyl propiolate

ISOXADIFEN-ETHYL Trinexapac-ethyl Ethyl cyanoacetate Ethyl Azidoacetate Ethyl phenylacetate

Ethyl bromoacetate Pyridinium dichromate Diazolidinyl Urea bis(methoxycarbonyl)methylidene-imino-azanium ETHYL DIAZOACETOACETATE

TERT-BUTYL DIAZOACETATE AZASERINE Ethyl 2-(4-bromophenyl)-2-diazoacetate

chevron_left

1of4

chevron_right

Acetic acid, diazo-, ethyl ester Daae Diazoacetic acid ethyl ester Diazoacetic ester diazoaceticacid,ethylester diazo-aceticaciethylester diazoaceticester Diazoessigsaeure-aethylester Ethoxycarbonyldiazomethane Ethyl 2-diazoacetate Ethyl diazoethanoate ETHYL DIAZOACETATE Ethylene Diazo Acetate ETHYL DIAZOACETATE ETHYL DIAZOETHANOATE 2-Diazoacetic acid ethyl Diazoacetic acid ethyl Ethyl diazoate Acetic acid, 2-diazo-,ethyl ester Ethyl diazoacetate contains >=13 wt. % dichloroMethane Ethyl diazoacetate solution, 95% 2-Diazoacetic acid ethyl ester solution Ethyl diazoacetate solution,90% wt in dichloromethane (e)-2-diazonio-1-ethoxyethenolate Ethyl 2-diazoacetate (diluted with ~10% dichloromethane, wt/wt) Ethyl diazoacetate, 95%, contains 5% CH2Cl2 diazoacetate soL Ethyl Diazoacetate (> Ethyl diazoacetate ISO 9001：2015 REACH Ethyl Diazoacetate (>90%) Ethyldiazoacetate, contains 15 wt. % dichloromethane Ethyl diazoacetate 15% solution in DCM Cilastatin Impurity 10 Tenofovir Disoproxil Fumarate Impurity 186 Ethyl diazoacetate, 80% solution in DCM 623-73-4 N2CHCOOC2H5 NNCHCOOC2H5 Azo/Diazo Compounds Building Blocks Nitrogen Compounds Organic Building Blocks Azo/Diazo Compounds Building Blocks Chemical Synthesis Nitrogen Compounds Organic Building Blocks Carboxylic Azo/Diazo Compounds Nitrogen Compounds Organic Building Blocks