N-(2-Naphthyl)aniline
- CAS No.
- 135-88-6
- Chemical Name:
- N-(2-Naphthyl)aniline
- Synonyms
- N-PHENYL-2-NAPHTHYLAMINE;N-phenylnaphthalen-2-amine;Nonox D;2-Naphthalenamine, N-phenyl-;N-Phenyl-2-naphthalenamine;Neozone;N-Phenyl-Beta-Naphtylamine;N-PHENYL-BETA-NAPHTHYLAMINE;ak1;nonoxd
- CBNumber:
- CB8140739
- Molecular Formula:
- C16H13N
- Molecular Weight:
- 219.28
- MOL File:
- 135-88-6.mol
- MSDS File:
- SDS
- Modify Date:
- 2023/6/8 17:06:38
| Melting point | 105-108 °C (lit.) |
|---|---|
| Boiling point | 395-395.5 °C (lit.) |
| Density | 1.24 |
| vapor pressure | 0.001Pa at 20℃ |
| refractive index | 1.7020 (estimate) |
| storage temp. | -20°C |
| solubility | Chloroform (Slightly), Methanol (Very Slightly) |
| form | Gray to tan flakes or powder |
| pka | 0.78±0.30(Predicted) |
| color | Pale Beige to Pale Gray |
| Water Solubility | Insoluble. <0.1 g/100 mL at 19 ºC |
| BRN | 2211188 |
| Stability | Stable. Incompatible with oxidizing agents. |
| LogP | 3.2 at 23℃ and pH7.9-8.3 |
| CAS DataBase Reference | 135-88-6(CAS DataBase Reference) |
| IARC | 3 (Vol. 16, Sup 7) 1987 |
| NIST Chemistry Reference | 2-Naphthyl phenyl amine(135-88-6) |
| EPA Substance Registry System | N-Phenyl-2-naphthylamine (135-88-6) |
SAFETY
Risk and Safety Statements
| Symbol(GHS) |    GHS07,GHS08,GHS09 |
|||||||||
|---|---|---|---|---|---|---|---|---|---|---|
| Signal word | Warning | |||||||||
| Hazard statements | H315-H317-H319-H351-H411 | |||||||||
| Precautionary statements | P202-P273-P280-P302+P352-P305+P351+P338-P308+P313 | |||||||||
| Hazard Codes | Xn,N | |||||||||
| Risk Statements | 36/38-40-43-51/53-53-51 | |||||||||
| Safety Statements | 22-24/25-61-36/37-26 | |||||||||
| RIDADR | 3077 | |||||||||
| WGK Germany | 2 | |||||||||
| RTECS | QM4550000 | |||||||||
| HazardClass | 6.1(b) | |||||||||
| PackingGroup | III | |||||||||
| HS Code | 29214500 | |||||||||
| Toxicity | mouse,LD50,oral,1450mg/kg (1450mg/kg),BEHAVIORAL: SOMNOLENCE (GENERAL DEPRESSED ACTIVITY),Hygiene and Sanitation Vol. 31(1-3), Pg. 183, 1966. | |||||||||
| NFPA 704 |
|
N-(2-Naphthyl)aniline price More Price(11)
| Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
|---|---|---|---|---|---|---|---|
| Sigma-Aldrich(India) | SAB1412122 | ANTI-AK1 antibody produced in mouse clone 4C2-1A8, purified immunoglobulin, buffered aqueous solution | 135-88-6 | 100μG | ₹52347.6 | 2022-06-14 | Buy |
| Sigma-Aldrich(India) | SAB1412005 | ANTI-AK1 antibody produced in mouse clone M2, purified immunoglobulin, buffered aqueous solution | 135-88-6 | 100μG | ₹52347.6 | 2022-06-14 | Buy |
| Sigma-Aldrich | 178055 | N-Phenyl-2-naphthylamine 97% | 135-88-6 | 25G | ₹1818.6 | 2022-06-14 | Buy |
| Sigma-Aldrich(India) | 178055 | N-Phenyl-2-naphthylamine 97% | 135-88-6 | 25G | ₹1818.6 | 2022-06-14 | Buy |
| Sigma-Aldrich(India) | SAB1412004 | ANTI-AK1 antibody produced in mouse clone 3G8-1B11, purified immunoglobulin, buffered aqueous solution | 135-88-6 | 100μG | ₹52347.6 | 2022-06-14 | Buy |
N-(2-Naphthyl)aniline Chemical Properties,Uses,Production
Description
Phenyl-naphtylamine is an amine coumpound. Sensitization was reported in patients with hypersensitivity to rubber.
Chemical Properties
light grey powder or crystals
Uses
N-Phenyl-2-naphthylamine is used as an antioxidant in rubber processing; provides oxidation and flex-cracking resistance in natural rubber, synthetic rubbers, and latexes; stabilizer in electrical-insulating silicone enamels; antioxidant in otiJer polymers, greases, lubricating oils, and transformer oils; heat and light stabilizer; vulcanization accelerator; catalyst; polymerization inhibitor; component of rocket fuels, surgical plasters, and tin-electroplating batiJs; chemical intermediate; an inhibitor for butadiene; in the production of seven dyes; in rubber products made of natural rubber, styrene-butadiene, nitrile, butadiene, and chloroprene.
General Description
Light gray to gray powder. Solutions show blue fluorescence.
Air & Water Reactions
Insoluble in water. Napthyl amines can be slowly hydrolyzed, releasing NH3 as a byproduct [N.L. Drake, Org. React. 1, (1942), 105].
Reactivity Profile
N-(2-Naphthyl)aniline may react with strong oxidizing agents . Neutralizes acids in exothermic reactions to form salts plus water. May be incompatible with isocyanates, halogenated organics, peroxides, phenols (acidic), epoxides, anhydrides, and acid halides. Flammable gaseous hydrogen may be generated in combination with strong reducing agents, such as hydrides.
Health Hazard
N-phenyl-b-naphthylamine (PBNA) is carcinogenic to experimental animals in some studies.
Fire Hazard
Literature sources indicate that N-(2-Naphthyl)aniline is combustible.
Contact allergens
Phenyl-beta-naphthylamine is an amine compound. Sensitization was reported in patients with hypersensitivity from rubber.
Safety Profile
Suspected carcinogen with experimental carcinogenic, neoplastigenic, and tumorigenic data. Moderately toxic by ingestion. Human mutation data reported. When heated to decomposition it emits toxic fumes of NOx.
Potential Exposure
Phenyl-β-naphthylamine is used as a rubber antioxidant; as an inhibitor for butadiene; a stabilizer in lubricants and an intermediate in chemical synthesis.
Carcinogenicity
The IARC has concluded that there is limited evidence for carcinogenicity to animals and inadequate evidence for humans.10 ACGIH considers PBNA to be a suspected human carcinogen because b-naphthylamine is both an impurity and a human metabolite of PBNA.
Purification Methods
Crystallise it from EtOH, MeOH, glacial acetic acid or *benzene/hexane. [Beilstein 12 H 1275, 12 I 535, 12 II 716, 12 III 2991.]
Incompatibilities
Move victim to fresh air. Call 911 or emergency medical service. Give artificial respiration if victim is not breathing. Do not use mouth-to-mouth method if victim ingested or inhaled the substance; give artificial respiration with the aid of a pocket mask equipped with a one-way valve or other proper respiratory medical device. Administer oxygen if breathing is difficult. Remove and isolate contaminated clothing and shoes. In case of contact with substance, immediately flush skin or eyes with running water for at least 20 minutes. For minor skin contact, avoid spreading material on unaffected skin. Keep victim warm and quiet. Effects of exposure (inhalation, ingestion or skin contact) to substance may be delayed. Ensure that medical personnel are aware of the material(s) involved and take precautions to protect themselves. Medical observation is recommended for 2448 hours after breathing overexposure, as pulmonary edema may be delayed. As first aid for pulmonary edema, a doctor or authorized paramedic may consider administering a drug or other inhalation therapy.
N-(2-Naphthyl)aniline Preparation Products And Raw materials
Raw materials
Preparation Products
1of2
chevron_right| Supplier | Tel | Country | ProdList | Advantage | Inquiry |
|---|---|---|---|---|---|
| Aceto Chem Pvt Ltd | +91-9825126143 +91-9825469333 | Gujarat, India | 7 | 58 | Inquiry |
| Oceanic Pharmachem Pvt., Ltd. (OPPL) | 91-22-42128600 | Maharashtra, India | 947 | 58 | Inquiry |
| TCI Chemicals (India) Pvt. Ltd. | 1800 425 7889 | New Delhi, India | 6778 | 58 | Inquiry |
| Otto Chemie Pvt. Ltd. | +91 9820041841 | Mumbai, India | 5873 | 58 | Inquiry |
| Alfa Aesar | 1 800 209 7001 | Maharashtra, India | 6913 | 58 | Inquiry |
| Prism Industries Limited | 08048371747Ext 784 | Gujarat, India | 20 | 58 | Inquiry |
| A.J Chemicals | 91-9810153283 | New Delhi, India | 6124 | 58 | Inquiry |
| CHEMSWORTH | +91-261-2397244 | New Delhi, India | 6707 | 30 | Inquiry |
| Bytkam International | 09909829388 | Ahmedabad, India | 94 | 58 | Inquiry |
| Aceto Chem Pvt., Ltd. | 91-261-2890998 | Gujarat, India | 4 | 58 | Inquiry |
| Supplier | Advantage |
|---|---|
| Aceto Chem Pvt Ltd | 58 |
| Oceanic Pharmachem Pvt., Ltd. (OPPL) | 58 |
| TCI Chemicals (India) Pvt. Ltd. | 58 |
| Otto Chemie Pvt. Ltd. | 58 |
| Alfa Aesar | 58 |
| Prism Industries Limited | 58 |
| A.J Chemicals | 58 |
| CHEMSWORTH | 30 |
| Bytkam International | 58 |
| Aceto Chem Pvt., Ltd. | 58 |
135-88-6(N-(2-Naphthyl)aniline)Related Search:
1of4
chevron_right