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METHYLALUMINOXANE

METHYLALUMINOXANE Structure
CAS No.
120144-90-3
Chemical Name:
METHYLALUMINOXANE
Synonyms
MAO;uminoxane;METHYLALUMINOXANE;MAO 10% in Toluene;methylaluminum(2+);dimethylalumanylium;MethylaluminoxaneMAO;Polymethylaluminoxane;Poly[oxy(methylaluminio)];Methylaluminoxane solution
CBNumber:
CB8193937
Molecular Formula:
C3H9Al3O3X2
Molecular Weight:
174.05
MOL File:
120144-90-3.mol
MSDS File:
SDS
Modify Date:
2023/10/21 16:16:55

METHYLALUMINOXANE Properties

Boiling point 111 °C
Density 0.875 g/mL at 25 °C
vapor pressure 0.76 mm Hg ( 60 °C)
storage temp. 2-8°C

SAFETY

Risk and Safety Statements

Symbol(GHS) 
GHS07
Signal word  Danger
Hazard statements  H250-H252-H228
Precautionary statements  P235+P410-P280-P407-P413-P420-P210-P222-P280-P302+P334-P370+P378-P422-P210-P240-P241-P280-P370+P378
Hazard Codes  F,C,Xn
Risk Statements  11-14-17-34-48/20-63-65-67-38
Safety Statements  26-36/37/39-45-62-36/37
RIDADR  UN 3394 4.2/PG 1
WGK Germany  2
HS Code  29310099

METHYLALUMINOXANE Chemical Properties,Uses,Production

Description

Methylaluminoxane (MAO) is by far the industrially most significant aluminoxane. The direct hydrolysis of trimethylaluminum (TMA) with water, however, is extremely exothermic and difficult to control. Thus, small scale, continuous processes, rather than large scale batch processes, are used for the direct hydrolysis of TMA to MAO. MAO can also be produced by reaction of TMA with organic acids, ketones, or carbon dioxide. The synthesis of MAO from TMA and CO2 actually has substantial literature precedent. Carbonation of an organoaluminum compound with carbon dioxide forms an aluminum carboxylate. 

Chemical Properties

Clear colorless solution

Mechanism of action

The role of Methylaluminoxane in metallocene catalyst polymerization is fourfold. First, it alkylates the transition metal. Second, it extracts an alkyl group from the transition metal to generate an active cationic polymerization catalyst. Third, it acts as a bulky, inert anion to the highly reactive transition metal cation. Fourth, it scavenges impurities from the polymerization reactor.

METHYLALUMINOXANE Preparation Products And Raw materials

METHYLALUMINOXANE Suppliers

Global( 50)Suppliers
Supplier Tel Country ProdList Advantage Inquiry
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Methylaluminoxane,10 wt.% (1.5M) solution intoluene MethylaluminoxaneMAO Poly[oxy(methylaluminio)] Methylaluminoxane ,10% Solution in Toluene [10% Solution in Toluene] MAO 10% in Toluene Methylaluminoxane solution 10t. % in toluene Methylaluminoxane, 10 wt.% (1.5M) solution in toluene, AcroSeal Methylaluminoxane, 10 wt.% (1.5M) solution in toluene, AcroSeal§3 ANTI-DANRE MAO (CENTER) antibody produced in rabbit METHYLALUMINOXANE MAO Methylaluminoxane solution METHYLALUMINOXANE, 10 WT. % SOLUTION IN TOLUENE Polymethylaluminoxane poly(oxy(methylaluminio)) (CH3AlO)n dimethylalumanylium methylaluminum(2+) Methylaluminoxane solution 10wt. % in toluene uminoxane METHYLALUMINOXANE ISO 9001:2015 REACH 120144-90-3 CH3AlO CH3AlOnC6H5CH3 CH3AlOn -AlCH3On C5H15Al3O3 Organoaluminum Organometallic Reagents Chemical Synthesis Organoaluminum Metal Compounds Organometallic Reagents