ARSENAZO III DISODIUM SALT

ARSENAZO III DISODIUM SALT Structure
CAS No.
62337-00-2
Chemical Name:
ARSENAZO III DISODIUM SALT
Synonyms
ARSENAZO III DISODIUM SALT;Arsenazo III disodium salt p.a.;ARSENAZO III DISODIUM SALT, REAG.;2,7-BIS(O-ARSONOPHENYLAZO) CHROMOTROPIC ACID;disodium 3,6-bis[(o-arsonophenyl)azo]-4,5-dihydroxynaphthalene-2,7-disulphonate;2,7-BIS(2-ARSENOPHENYLAZO)-1,8-DIHYDROXYNAPHTALENE-3,6-DISULFONIC ACID, DISODIUM SALT;3,6-Bis[(2-arsonophenyl)azo]-4,5-dihydroxy-2,7-naphthalenedisulfonic acid disodium salt;(3E,6E)-3,6-bis[(2-arsonophenyl)hydrazinylidene]-4,5-dioxonaphthalene-2,7-disulfonic acid;3,6-bis(2,2'-arsonophenylazo)-4,5-dihydroxy-2,7-naphthalenedisulfonic acid, disodium salt;3,6-Bis[2-(2-arsonophenyl)diazenyl]-4,5-dihydroxy-2,7-naphthalenedisulfonic Acid SodiuM Salt
CBNumber:
CB8251091
Molecular Formula:
C22H19As2N4NaO14S2
Molecular Weight:
800.36
MOL File:
62337-00-2.mol
Modify Date:
2023/4/23 13:52:06

ARSENAZO III DISODIUM SALT Properties

Melting point >320 °C(lit.)
color Clear pink
Water Solubility Soluble in water.

SAFETY

Risk and Safety Statements

Symbol(GHS) 
GHS06,GHS09
Signal word  Warning
Hazard statements  H301-H331-H400-H410
Precautionary statements  P261-P301+P310a-P304+P340-P311a-P405-P501a
Hazard Codes  T,N
Risk Statements  23/25-50/53
Safety Statements  20/21-28-45-60-61
RIDADR  UN 3465 6.1/PG 2
WGK Germany  3
HazardClass  6.1
PackingGroup  II
NFPA 704
1
3 0

ARSENAZO III DISODIUM SALT price More Price(3)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
ALFA India ALF-A11838-14 Arsenazo III disodium salt 62337-00-2 25g ₹94417 2022-05-26 Buy
ALFA India ALF-A11838-06 Arsenazo III disodium salt 62337-00-2 5g ₹29041 2022-05-26 Buy
ALFA India ALF-A11838-03 Arsenazo III disodium salt 62337-00-2 1g ₹6238 2022-05-26 Buy
Product number Packaging Price Buy
ALF-A11838-14 25g ₹94417 Buy
ALF-A11838-06 5g ₹29041 Buy
ALF-A11838-03 1g ₹6238 Buy

ARSENAZO III DISODIUM SALT Chemical Properties,Uses,Production

Chemical Properties

dark brown to brownish-black crystalline powder

Uses

Arsenazo III disodium salt is a diazo dye reagent used in the spectrophotometric determination of aluminum, gallium and indium. Further, it is used in the complexometric determination of lanthanides, thallium, scandium thorium, uranium and yttrium. In addition to this, it acts as a metal indicator and form specifically colored metal ion complexes in aqueous media.

Purification Methods

Contaminants include monoazo derivatives, starting materials for synthesis and by-products. It is partially purified by precipitation of the dye from aqueous alkali on addition of HCl. More thorough purification is achieved by taking a 2g sample in 15-25mL of 5% aqueous NH3 and filter. Add 10mL HCl (1:1) to the filtrate to precipitate the dye. Repeat the procedure and dissolve the solid dye (0.5g) in 7mL of a 1:1:1 mixture of n-propanol/conc NH3/water at 50o. After cooling, filter the solution and chromatograph the filtrate through a cellulose column using a 3:1:1 mixture of n-propanol/conc NH3/water as eluent. Collect the blue band and evaporate it to 10-15mL below 80o, then add 10mL of conc HCl to precipitate pure Arsenazo III. Wash it with EtOH and dry it in air [Borak et al. Talanta 17 215 1970]. The sodium salt is then obtained by dissolving it in the equivalent amount of dilute NaOH and freeze-drying. The purity of the dye can be checked by paper chromatography using M HCl as eluent. It is used for the estimation of Th, U, Zr, Cd and Zn [Michaylova & Yuroukova Anal Chim Acta 68 73 1974.]

ARSENAZO III DISODIUM SALT Preparation Products And Raw materials

Raw materials

Preparation Products

Global( 59)Suppliers
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Central Drug House(P) Ltd. 91-11-49404040 New Delhi, India 6160 58 Inquiry
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Alfa Chemistry United States 2344 58 Inquiry
LEAPCHEM CO., LTD. +86-852-30606658 China 43348 58 Inquiry
Arsenazo III disodium salt p.a. 3,6-Bis[2-(2-arsonophenyl)diazenyl]-4,5-dihydroxy-2,7-naphthalenedisulfonic Acid SodiuM Salt ARSENAZO III DISODIUM SALT 2,7-BIS(O-ARSONOPHENYLAZO) CHROMOTROPIC ACID 2,7-BIS(2-ARSENOPHENYLAZO)-1,8-DIHYDROXYNAPHTALENE-3,6-DISULFONIC ACID, DISODIUM SALT disodium 3,6-bis[(o-arsonophenyl)azo]-4,5-dihydroxynaphthalene-2,7-disulphonate ARSENAZO III DISODIUM SALT, REAG. 3,6-bis(2,2'-arsonophenylazo)-4,5-dihydroxy-2,7-naphthalenedisulfonic acid, disodium salt 3,6-Bis[(2-arsonophenyl)azo]-4,5-dihydroxy-2,7-naphthalenedisulfonic acid disodium salt (3E,6E)-3,6-bis[(2-arsonophenyl)hydrazinylidene]-4,5-dioxonaphthalene-2,7-disulfonic acid 62337-00-2 C22H18As2N4O14S22Na C22H16As2N4Na2O14S2 C22H16As2N4O14S22Na Aromatics Sulfur & Selenium Compounds