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Naphthalene-2-sulfonic acid

Naphthalene-2-sulfonic acid  Structure
CAS No.
120-18-3
Chemical Name:
Naphthalene-2-sulfonic acid
Synonyms
2-NAPHTHALENESULFONIC ACID;NAPHTHALENE-2-SULPHONIC ACID;Dirinal NSK;2-Sulfonaphthalene;2-Naphthalenesulfoni;β-Naphthalenesulfonic;β-Naphthalenesulfonic;beta-naphthalenesulfonic;beta-naphthylsulfonicacid;2-NAPHTHALENESULFONIC ACI
CBNumber:
CB8118079
Molecular Formula:
C10H8O3S
Molecular Weight:
208.23
MOL File:
120-18-3.mol
Modify Date:
2023/12/25 13:23:17

Naphthalene-2-sulfonic acid Properties

Melting point 124 °C
Boiling point 317.43°C (rough estimate)
Density 1.44 g/cm
vapor pressure 2.33Pa at 20℃
refractive index 1.4998 (estimate)
storage temp. Inert atmosphere,Room Temperature
solubility water: freely soluble(lit.)
form solid
pka 0.27±0.10(Predicted)
color White
Water Solubility Soluble in water.
Sensitive Hygroscopic
Merck 6377
LogP -0.944 at 23℃
CAS DataBase Reference 120-18-3(CAS DataBase Reference)
EPA Substance Registry System 2-Naphthalenesulfonic acid (120-18-3)

SAFETY

Risk and Safety Statements

Symbol(GHS) 
GHS05
Signal word  Danger
Hazard statements  H290-H314
Precautionary statements  P260-P280-P301+P330+P331-P303+P361+P353-P305+P351+P338+P310
Hazard Codes  C,F
Risk Statements  35-34-11
Safety Statements  26-36/37/39-45-16
RIDADR  UN 2583 8/PG 2
WGK Germany  1
RTECS  QK1225000
Hazard Note  Corrosive
TSCA  Yes
HazardClass  8
PackingGroup  III
HS Code  2904100090
NFPA 704
0
3 1

Naphthalene-2-sulfonic acid price More Price(9)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 249548 2-Naphthalenesulfonic acid technical grade, 70% 120-18-3 5G ₹4504.85 2022-06-14 Buy
Sigma-Aldrich(India) 249548 2-Naphthalenesulfonic acid technical grade, 70% 120-18-3 5G ₹4504.85 2022-06-14 Buy
Sigma-Aldrich 249548 2-Naphthalenesulfonic acid technical grade, 70% 120-18-3 100G ₹8830.35 2022-06-14 Buy
Sigma-Aldrich 249548 2-Naphthalenesulfonic acid technical grade, 70% 120-18-3 100G ₹8830.35 2022-06-14 Buy
Sigma-Aldrich(India) 249548 2-Naphthalenesulfonic acid technical grade, 70% 120-18-3 100G ₹8830.35 2022-06-14 Buy
Product number Packaging Price Buy
249548 5G ₹4504.85 Buy
249548 5G ₹4504.85 Buy
249548 100G ₹8830.35 Buy
249548 100G ₹8830.35 Buy
249548 100G ₹8830.35 Buy

Naphthalene-2-sulfonic acid Chemical Properties,Uses,Production

Chemical Properties

Nondeliquescent, white plates.Soluble in water, alcohol, and ether. Combustible.

Uses

Naphthalene-2-sulfonic acid is used in making direct dyes, reactive des and employed as dye and agrochemical intermediates.

Definition

ChEBI: Naphthalene-2-sulfonic acid is a naphthalenesulfonic acid in which the sulfo group is linked to position 2 of the naphthalene ring. It has a role as an environmental contaminant and a xenobiotic.

Preparation

Naphthalene-2-sulfonic acid is prepared by sulfonation of naphthalene.
Step: With naphthalene as raw material, 98% sulfuric acid is used as sulfonating agent, and it is obtained by sulfonation at 160-166 ℃. During the sulfonation process, a small amount of α-naphthalenesulfonic acid by-product is generated. By heating, the unstable α-naphthalenesulfonic acid can be hydrolyzed at 140-150 °C to remove the sulfonic acid group, and become naphthalene and sulfuric acid. Naphthalene can be blown out. During the hydrolysis of naphthalene, a small amount of lye should be added to neutralize part of the sulfuric acid. It also acts with naphthalenesulfonic acid to form β-naphthalenesulfonic acid sodium salt crystals, which can be filtered to obtain the finished product of Naphthalene-2-sulfonic acid.

General Description

The fluorescence of 2-naphthalenesulfonic acid (NSA) is effectively quenched by colloidal silver via photoinduced interfacial electron transfer from the excited singlet of NSA to silver. Adsorption behavior of NSA on a conventional macroporous resin Amberlite XAD4 and hypercrosslinked resins NDA101 and NDA100 has been investigated.

Purification Methods

Crystallise the acid from conc HCl. The S-benzylisothiuronium salt has m 192o (from aqueous EtOH). [Berger Acta Chem Scand 8 432 1954, Beilstein 11 H 171, 11 IV 527.]

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Naphthalene-2-sulfonic acid Spectrum

2-Naphthalenesulfonicacid,tri BETA NAPTHALENE SULPHONATE BETA-NAPHTHALENESULFONIC ACID 2-Naphthalenesulfoni 2-Naphthalenesulfonic Acid  2-Sulfonaphthalene Dirinal NSK 2-Naphthalenesulfonic Acid (β-Naphthalenesulfonic acid) 2-Naphthalenesulfonic acid technical grade, 70% beta-naphthalenesulfonic beta-naphthylsulfonicacid kyselina2-naftalensulfonova β-Naphthalene sulfonic acid Naphthalene-2-sulfonic acid 2-NAPHTHALENESULFONIC ACID, TECH., 70% 2-NAPHTHALENESULFONIC ACID MONOHYDRATE(BETA-) 97+% Naphthalene-2-sulfonic acid hydrate, tech., 70% NAPHTHALENE-2-SULFONICACID,MONOHYDRATE(BETA-) BETA-NAPHTHALENE-SULPHONICACID 2-NAPHTHALENESULFONIC ACID 98% HPLC NAPHTHALENE-2-SULPHONIC ACID (FREE ACID) extrapure β-Naphthalenesulfonic 2-Naphthalenesulfonic Acid Sodium Sal 2-NAPHTHALENESULFONIC ACI naphthalene-2-sulfonicaci Naphthalene-2-sulfonic acid ISO 9001:2015 REACH β-naphthalene sulfonic acid β-Naphthalenesulfonic Naphthalene-2-Sulphonic Acid Monohydrate extrapure, 98% NAPHTHALENE-2-SULPHONIC ACID 2-NAPHTHALENESULFONIC ACID 2-Naphthalenesulfonic acid (8CI, 9CI, ACI) NAPTHELENE SULPHONIC ACID 120-18-3 501-52-5 C10H8O3S2H2O Building Blocks Organic Building Blocks Sulfur Compounds Sulfonic/Sulfinic Acids Intermediates of Dyes and Pigments Imidazoles Organic Building Blocks Sulfonic/Sulfinic Acids Sulfur Compounds