S-3,3'-Bis(triphenylsilyl)-1,1'-binaphthyl-2,2'-diyl hydrogenphosphate

CAS No.: 929097-92-7

Chemical Name:: S-3,3'-Bis(triphenylsilyl)-1,1'-binaphthyl-2,2'-diyl hydrogenphosphate

Synonyms: SF110008;(S)-3,3'-Bis(triphenylsilyl)binaphthyl phosphate;(S)-3,3’-Bis(triphenylsilyl)-1,1’-binaphthyl-2,2’-diyl Hydrogenphosphate;(S)-3,3'-Bis(triphenylsilyl)-1,1'-binaphthyl-2,2'-diyl hydrogenphosphate 96%;(S)-3,3'-Bis(triphenylsilyl)-1,1'-binaphthalene-2,2'-diyl hydrogen phosphate;(S)-3,3′-Bis(triphenylsilyl)-1,1′-binaphthyl-2,2′-diyl hydrogenphosphate;(S)-3,3'-Bis(triphenylsilyl)-1,1'-binaphthyl-2,2'-diyl Hydrogen Phosphate,99%e.e.;(S)-2,2''-Dihydroxy-3,3''-bis(triphenylsilyl)-1,1''-binaphthalene cyclic phosphate;(S)-(+)-3,3'-BIS(TRIPHENYLSILYL)-1,1'-BINAPHTHYL-2,2'-DIYLHYDROGENPHOSPHATE,MIN.98%[(S)-TIPSY];(11bS)-4-Hydroxy-2,6-bis(triphenylsilyl)-4-oxide-dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin

CBNumber:: CB82638520

Molecular Formula:: C56H41O4PSi2

Molecular Weight:: 865.08

MOL File:: 929097-92-7.mol

MSDS File:: SDS

Modify Date:: 2025/1/27 9:38:02

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S-3,3'-Bis(triphenylsilyl)-1,1'-binaphthyl-2,2'-diyl hydrogenphosphate Properties

Melting point	329-335°C
alpha	+210° (c=1.0, CHCl3)
Density	1.32±0.1 g/cm3(Predicted)
storage temp.	under inert gas (nitrogen or Argon) at 2-8°C
pka	1.17±0.20(Predicted)
form	solid
color	white to light-yellow
optical activity	[α]22/D +210°, c = 1 in chloroform

SAFETY

Risk and Safety Statements

Symbol(GHS)	GHS07
Signal word	Warning
Hazard statements	H315-H319-H335
Precautionary statements	P261-P264-P271-P280-P302+P352-P305+P351+P338
Hazard Codes	Xi
Risk Statements	36/37/38
Safety Statements	26-36/37
WGK Germany	3
HS Code	29319090

S-3,3'-Bis(triphenylsilyl)-1,1'-binaphthyl-2,2'-diyl hydrogenphosphate price More Price(1)

Manufacturer	Product number	Product description	CAS number	Packaging	Price	Updated	Buy
Sigma-Aldrich(India)	680184	(S)-3,3′-Bis(triphenylsilyl)-1,1′-binaphthyl-2,2′-diyl hydrogenphosphate 96%	929097-92-7	100MG	₹19853.05	2022-06-14	Buy

Product number	Packaging	Price	Buy
680184	100MG	₹19853.05	Buy

S-3,3'-Bis(triphenylsilyl)-1,1'-binaphthyl-2,2'-diyl hydrogenphosphate Chemical Properties,Uses,Production

Chemical Properties

Solid

Uses

(S)-3,3′-Bis(triphenylsilyl)-1,1′-binaphthyl-2,2′-diyl hydrogenphosphate can be used as a catalyst:

In the synthesis of 1,3-dioxolochroman skeletons by reacting 3-methyl-2-vinylindoles with ortho-quinone methides.
In the exo-selective cyclization of mupirocin methyl ester.
In the kinetic resolution of cyclic aliphatic syn-1,3-diols, which are used as valuable building blocks.

Reactions

Chiral phosphoric acid catalyst used for the highly enantioselective Friedel-Crafts reaction of indoles with imines.
Chiral phosphoric acid catalyst used for the highly enantioselective Friedel-Crafts reaction of pyrrole derivatives with N-acyl imines.
Chiral phosphoric acid catalyst used for the enantioselective transfer hydrogenation of hydroxylactams providing enantioenriched tetrahydro-β-carbolines (in dioxane) at room temperature (up to 94% yield, 90% ee).
[Rh2(OAc)4]/chiral phosphoric acid catalyst used for the enantioselective symmetric, three-component reaction of diazo compounds with imines and water yielding β-amino-α-hydroxy acid derivatives.
Enantioselective desymmetrization of prochiral allenic diols via cooperative catalysis of Pd(OAc)2 and a chiral phosphoric acid.

S-3,3'-Bis(triphenylsilyl)-1,1'-binaphthyl-2,2'-diyl hydrogenphosphate Preparation Products And Raw materials

Raw materials

Preparation Products

S-3,3'-Bis(triphenylsilyl)-1,1'-binaphthyl-2,2'-diyl hydrogenphosphate Suppliers

Global( 48)Suppliers

Supplier	Tel	Country	ProdList	Advantage	Inquiry
Shanghai Daken Advanced Materials Co.,Ltd	+86-371-+86-371-66670886	China	19843	58	Inquiry
CD Chemical Group Limited	+8615986615575	China	20342	58	Inquiry
Hu Bei Jiutian Bio-medical Technology CO.,Ltd	027-88013699 17354350817	China	6000	58	Inquiry
Zibo Hangyu Biotechnology Development Co., Ltd	+86-0533-2185556 +8615965530500	China	10983	58	Inquiry
LEAPCHEM CO., LTD.	+86-852-30606658	China	43340	58	Inquiry
Aladdin Scientific		United States	52924	58	Inquiry
Shanghai Aladdin Biochemical Technology Co.,Ltd.	400-6206333 13167063860	China	48458	58	Inquiry
Shanghai Anyinuo Biomedical Technology Co., Ltd.	021-34625901	China	5843	58	Inquiry
Zhengzhou Acme Chemical Co., Ltd.	0371-63315541 13323832564	China	9997	58	Inquiry
Hubei Guangao Biotechnology Co., Ltd	027-027-59223056 18162699093	China	9888	58	Inquiry

Supplier	Advantage
Shanghai Daken Advanced Materials Co.,Ltd	58
CD Chemical Group Limited	58
Hu Bei Jiutian Bio-medical Technology CO.,Ltd	58
Zibo Hangyu Biotechnology Development Co., Ltd	58
LEAPCHEM CO., LTD.	58
Aladdin Scientific	58
Shanghai Aladdin Biochemical Technology Co.,Ltd.	58
Shanghai Anyinuo Biomedical Technology Co., Ltd.	58
Zhengzhou Acme Chemical Co., Ltd.	58
Hubei Guangao Biotechnology Co., Ltd	58

929097-92-7(S-3,3'-Bis(triphenylsilyl)-1,1'-binaphthyl-2,2'-diyl hydrogenphosphate)Related Search:

(S)-3,3'-Bis(3,5-diphenyl)phenyl-1,1'-binaphthyl-2,2'-diyl Hydrogen Phosphate S-4-oxide-4-hydroxy-2,6-di-1-naphthalenyl-Dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin S-3,3'-Bis(4-(1,1-diMethylethyl)phenyl)-1,1'-binaphthyl-2,2'-diyl hydrogenphosphate (R)-3,3'-BIS(3,5-BIS(TRIFLUOROMETHYL)PH& R-4-oxide-4-hydroxy-2,6-bis[4-(trifluoroMethyl)phenyl]-Dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin

R- 4-oxide-4-hydroxy-2,6-bis([1,1':3',1''-terphenyl]-5'-yl)-Dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin R-3,3'-Bis(4-(1,1-diMethylethyl)phenyl)-1,1'-binaphthyl-2,2'-diyl hydrogenphosphate S-3,3'-Bis(triphenylsilyl)-5,5',6,6',7,7',8,8'-Octahydro-1,1'-bi-2-naphthyl phosphate S-5,5',6,6',7,7',8,8'-octahydro-3,3'-diphenyl-[1,1'-Binaphthalene]-2,2'-diol R-5,5',6,6',7,7',8,8'-Octahydro-1,1'-bi-2-naphthyl phosphate

(S)-(-)-3,3μ-Bis(triphenylsilyl)-1,1μ-bi-2-naphthol (S)-3,3'-Di(anthracen-9-yl)-1,1'-binaphthalene-2,2'-diol (S)-(+)-3,3'-BIS(3,5-BIS(TRIFLUOROMETHYL)PHENYL)-1,1'-BINAPHTHYL-2,2'-DIYL HYDROGENPHOSPHATE, 95% S-3,3'-bis[4-(2-naphthalenyl)phenyl]-1,1'-Binaphthalene]-2,2'-diol S- 4-oxide--hydroxy-2,6-bis[4-(2-naphthalenyl)phenyl]-Dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin

S-3,3'-Bis(9-anthracenyl)-1,1'-binaphthyl-2,2'-diyl hydrogenphosphate (S)-(-)-3,3'-BIS(3,5-BIS(TRIFLUOROMETHY& S-4-oxide-4-hydroxy-2,6-bis(4-nitrophenyl)- Dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin

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(S)-3,3'-Bis(triphenylsilyl)-1,1'-binaphthyl-2,2'-diyl hydrogenphosphate 96% (S)-(+)-3,3'-BIS(TRIPHENYLSILYL)-1,1'-BINAPHTHYL-2,2'-DIYLHYDROGENPHOSPHATE,MIN.98%[(S)-TIPSY] (S)-3,3'-Bis(triphenylsilyl)-1,1'-binaphthyl-2,2'-diyl Hydrogen Phosphate,99%e.e. (S)-3,3'-Bis(triphenylsilyl)-1,1'-binaphthalene-2,2'-diyl hydrogen phosphate (11bS)-4-Hydroxy-2,6-bis(triphenylsilyl)-4-oxide-dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin (S)-2,2''-Dihydroxy-3,3''-bis(triphenylsilyl)-1,1''-binaphthalene cyclic phosphate (11bS)-2,6-Bis(triphenylsilyl)-4-hydroxy-4-oxide-dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin SF110008 Dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin, 4-hydroxy-2,6-bis(triphenylsilyl)-, 4-oxide, (11bS)- (S)-3,3'-Bis(triphenylsilyl)binaphthyl phosphate (13-hydroxy-13-oxo-16-triphenylsilyl-12,14-dioxa-13lambda5-phosphapentacyclo[13.8.0.02,11.03,8.018,23]tricosa-1(15),2(11),3,5,7,9,16,18,20,22-decaen-10-yl)-triphenylsilane (11bS)-4-Hydroxy-2,6-bis(triphenylsilyl)dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepine 4-oxide (S)-3,3’-Bis(triphenylsilyl)-1,1’-binaphthyl-2,2’-diyl Hydrogenphosphate (S)-3,3′-Bis(triphenylsilyl)-1,1′-binaphthyl-2,2′-diyl hydrogenphosphate 929097-92-7