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ChemicalBook >제품 카탈로그 >S-3,3'-비스(트리페닐실릴)-1,1'-비나프틸-2,2'-디일수소인산염

S-3,3'-비스(트리페닐실릴)-1,1'-비나프틸-2,2'-디일수소인산염

S-3,3'-비스(트리페닐실릴)-1,1'-비나프틸-2,2'-디일수소인산염
S-3,3'-비스(트리페닐실릴)-1,1'-비나프틸-2,2'-디일수소인산염 구조식 이미지
카스 번호:
929097-92-7
한글명:
S-3,3'-비스(트리페닐실릴)-1,1'-비나프틸-2,2'-디일수소인산염
동의어(한글):
S-3,3'-비스(트리페닐실릴)-1,1'-비나프틸-2,2'-디일수소인산염
상품명:
S-3,3'-Bis(triphenylsilyl)-1,1'-binaphthyl-2,2'-diyl hydrogenphosphate
동의어(영문):
SF110008;(S)-3,3'-Bis(triphenylsilyl)binaphthyl phosphate;(S)-3,3’-Bis(triphenylsilyl)-1,1’-binaphthyl-2,2’-diyl Hydrogenphosphate;(S)-3,3'-Bis(triphenylsilyl)-1,1'-binaphthyl-2,2'-diyl hydrogenphosphate 96%;(S)-3,3'-Bis(triphenylsilyl)-1,1'-binaphthalene-2,2'-diyl hydrogen phosphate;(S)-3,3'-Bis(triphenylsilyl)-1,1'-binaphthyl-2,2'-diyl Hydrogen Phosphate,99%e.e.;(S)-2,2''-Dihydroxy-3,3''-bis(triphenylsilyl)-1,1''-binaphthalene cyclic phosphate;(S)-(+)-3,3'-BIS(TRIPHENYLSILYL)-1,1'-BINAPHTHYL-2,2'-DIYLHYDROGENPHOSPHATE,MIN.98%[(S)-TIPSY];(11bS)-4-Hydroxy-2,6-bis(triphenylsilyl)-4-oxide-dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin;(11bS)-2,6-Bis(triphenylsilyl)-4-hydroxy-4-oxide-dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin
CBNumber:
CB82638520
분자식:
C56H41O4PSi2
포뮬러 무게:
865.08
MOL 파일:
929097-92-7.mol
MSDS 파일:
SDS

S-3,3'-비스(트리페닐실릴)-1,1'-비나프틸-2,2'-디일수소인산염 속성

녹는점
329-335°C
알파
+210° (c=1.0, CHCl3)
밀도
1.32±0.1 g/cm3(Predicted)
저장 조건
under inert gas (nitrogen or Argon) at 2-8°C
산도 계수 (pKa)
1.17±0.20(Predicted)
물리적 상태
고체
물리적 상태
단단한 모양
색상
흰색에서 밝은 노란색
optical activity
[α]22/D +210°, c = 1 in chloroform
안전
  • 위험 및 안전 성명
  • 위험 및 사전주의 사항 (GHS)
위험품 표기 Xi
위험 카페고리 넘버 36/37/38
안전지침서 26-36/37
WGK 독일 3
HS 번호 29319090
그림문자(GHS): GHS hazard pictograms
신호 어: Warning
유해·위험 문구:
암호 유해·위험 문구 위험 등급 범주 신호 어 그림 문자 P- 코드
H315 피부에 자극을 일으킴 피부부식성 또는 자극성물질 구분 2 경고 GHS hazard pictograms P264, P280, P302+P352, P321,P332+P313, P362
H319 눈에 심한 자극을 일으킴 심한 눈 손상 또는 자극성 물질 구분 2A 경고 GHS hazard pictograms P264, P280, P305+P351+P338,P337+P313P
H335 호흡 자극성을 일으킬 수 있음 특정 표적장기 독성 - 1회 노출;호흡기계 자극 구분 3 경고 GHS hazard pictograms
예방조치문구:
P261 분진·흄·가스·미스트·증기·...·스프레이의 흡입을 피하시오.
P264 취급 후에는 손을 철저히 씻으시오.
P264 취급 후에는 손을 철저히 씻으시오.
P271 옥외 또는 환기가 잘 되는 곳에서만 취급하시오.
P280 보호장갑/보호의/보안경/안면보호구를 착용하시오.
P302+P352 피부에 묻으면 다량의 물로 씻으시오.
P305+P351+P338 눈에 묻으면 몇 분간 물로 조심해서 씻으시오. 가능하면 콘택트렌즈를 제거하시오. 계속 씻으시오.

S-3,3'-비스(트리페닐실릴)-1,1'-비나프틸-2,2'-디일수소인산염 C화학적 특성, 용도, 생산

화학적 성질

Solid

용도

(S)-3,3′-Bis(triphenylsilyl)-1,1′-binaphthyl-2,2′-diyl hydrogenphosphate can be used as a catalyst:

화학 반응

  1. Chiral phosphoric acid catalyst used for the highly enantioselective Friedel-Crafts reaction of indoles with imines.
  2. Chiral phosphoric acid catalyst used for the highly enantioselective Friedel-Crafts reaction of pyrrole derivatives with N-acyl imines.
  3. Chiral phosphoric acid catalyst used for the enantioselective transfer hydrogenation of hydroxylactams providing enantioenriched tetrahydro-β-carbolines (in dioxane) at room temperature (up to 94% yield, 90% ee).
  4. [Rh2(OAc)4]/chiral phosphoric acid catalyst used for the enantioselective symmetric, three-component reaction of diazo compounds with imines and water yielding β-amino-α-hydroxy acid derivatives.
  5. Enantioselective desymmetrization of prochiral allenic diols via cooperative catalysis of Pd(OAc)2 and a chiral phosphoric acid.
Reactions of 929097-92-7_1 Reactions of 929097-92-7_2

S-3,3'-비스(트리페닐실릴)-1,1'-비나프틸-2,2'-디일수소인산염 준비 용품 및 원자재

원자재

준비 용품

S-3,3'-비스(트리페닐실릴)-1,1'-비나프틸-2,2'-디일수소인산염 공급 업체

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S-3,3'-비스(트리페닐실릴)-1,1'-비나프틸-2,2'-디일수소인산염 관련 검색:

(S)-3,3'-Bis(3,5-diphenyl)phenyl-1,1'-binaphthyl-2,2'-diyl Hydrogen Phosphate S-4-oxide-4-hydroxy-2,6-di-1-naphthalenyl-Dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin S-3,3'-Bis(4-(1,1-diMethylethyl)phenyl)-1,1'-binaphthyl-2,2'-diyl hydrogenphosphate (R)-3,3'-BIS(3,5-BIS(TRIFLUOROMETHYL)PH& R-4-oxide-4-hydroxy-2,6-bis[4-(trifluoroMethyl)phenyl]-Dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin R- 4-oxide-4-hydroxy-2,6-bis([1,1':3',1''-terphenyl]-5'-yl)-Dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin R-3,3'-Bis(4-(1,1-diMethylethyl)phenyl)-1,1'-binaphthyl-2,2'-diyl hydrogenphosphate S-3,3'-Bis(triphenylsilyl)-5,5',6,6',7,7',8,8'-Octahydro-1,1'-bi-2-naphthyl phosphate S-5,5',6,6',7,7',8,8'-octahydro-3,3'-diphenyl-[1,1'-Binaphthalene]-2,2'-diol R-5,5',6,6',7,7',8,8'-Octahydro-1,1'-bi-2-naphthyl phosphate (S)-(-)-3,3μ-Bis(triphenylsilyl)-1,1μ-bi-2-naphthol (S)-3,3'-Di(anthracen-9-yl)-1,1'-binaphthalene-2,2'-diol (S)-(+)-3,3'-BIS(3,5-BIS(TRIFLUOROMETHYL)PHENYL)-1,1'-BINAPHTHYL-2,2'-DIYL HYDROGENPHOSPHATE, 95% S-3,3'-bis[4-(2-naphthalenyl)phenyl]-1,1'-Binaphthalene]-2,2'-diol S- 4-oxide--hydroxy-2,6-bis[4-(2-naphthalenyl)phenyl]-Dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin S-3,3'-Bis(9-anthracenyl)-1,1'-binaphthyl-2,2'-diyl hydrogenphosphate (S)-(-)-3,3'-BIS(3,5-BIS(TRIFLUOROMETHY& S-4-oxide-4-hydroxy-2,6-bis(4-nitrophenyl)- Dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin
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