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1,10-Phenanthroline hydrate

CAS No.: 5144-89-8

Chemical Name:: 1,10-Phenanthroline hydrate

Synonyms: 1,10-PHENANTHROLINE MONOHYDRATE;ORTHO-PHENANTHROLINE;Phenanthroline Monohydrate;1,10-PHENANTHROLINE H2O;O-PHENANTHROLINE MONOHYDRATE;10-Phenanthroline monohydrate;1,10-Phenanthroline, ACS, 99%;PHENYLANTHROLINE HYDRATE 1,10-;1,10-PHENANTHROLINE AR;Black bone vine extract

CBNumber:: CB8290304

Molecular Formula:: C12H8N2.H2O

Molecular Weight:: 198.22

MOL File:: 5144-89-8.mol

MSDS File:: SDS

Modify Date:: 2024/7/26 17:49:17

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1,10-Phenanthroline hydrate Properties

Melting point	100-104 °C(lit.)
Density	1.10
vapor density	6.2 (vs air)
storage temp.	Sealed in dry,Room Temperature
solubility	methanol: soluble200MM (Stock solution is stable for months at –20° C.)
form	Needle-Like Crystals
color	Off-white, may become cream-colored during storage
Water Solubility	<0.01 g/100 mL at 21 ºC
Merck	14,7214
BRN	4008096
Stability	Stable. Incompatible with iron, other heavy metals, strong oxidizing agents, strong acids.
CAS DataBase Reference	5144-89-8(CAS DataBase Reference)
EPA Substance Registry System	1,10-Phenanthroline, monohydrate (5144-89-8)

SAFETY

Risk and Safety Statements

Symbol(GHS)

GHS06,GHS09

Signal word

Danger

Hazard statements

H301-H410

Precautionary statements

Hazard Codes

Risk Statements

Safety Statements

RIDADR

UN 2811 6.1/PG 3

WGK Germany

RTECS

SF8437000

TSCA

Yes

HazardClass

6.1

PackingGroup

III

HS Code

29339990

Toxicity

LD50 orally in Rabbit: 132 mg/kg

NFPA 704

	1
2		0

1,10-Phenanthroline hydrate price More Price(40)

Manufacturer	Product number	Product description	CAS number	Packaging	Price	Updated	Buy
Sigma-Aldrich(India)	P9375	1,10-Phenanthroline monohydrate reagent grade	5144-89-8	1G	₹2608.83	2022-06-14	Buy
Sigma-Aldrich(India)	P9375	1,10-Phenanthroline monohydrate reagent grade	5144-89-8	5G	₹3604.73	2022-06-14	Buy
Sigma-Aldrich(India)	P9375	1,10-Phenanthroline monohydrate reagent grade	5144-89-8	25G	₹10337.88	2022-06-14	Buy
Sigma-Aldrich(India)	P9375	1,10-Phenanthroline monohydrate reagent grade	5144-89-8	100G	₹30310	2022-06-14	Buy
Sigma-Aldrich(India)	77500	1,10-Phenanthroline monohydrate for the spectrophotometric determination of Fe, Pd, V, ≥99.0%	5144-89-8	5G	₹5174.35	2022-06-14	Buy

Product number	Packaging	Price	Buy
P9375	1G	₹2608.83	Buy
P9375	5G	₹3604.73	Buy
P9375	25G	₹10337.88	Buy
P9375	100G	₹30310	Buy
77500	5G	₹5174.35	Buy

1,10-Phenanthroline hydrate Chemical Properties,Uses,Production

Chemical Properties

white crystals or powder

General Description

White crystalline powder or solid. Slight odor.

Air & Water Reactions

Insoluble in water.

Reactivity Profile

1,10-Phenanthroline hydrate is incompatible with strong oxidizers. 1,10-Phenanthroline hydrate is also incompatible with strong acids. 1,10-Phenanthroline hydrate forms complex compounds with ferrous ions. .

Fire Hazard

Flash point data for 1,10-Phenanthroline hydrate are not available. 1,10-Phenanthroline hydrate is probably combustible.

Purification Methods

Crystallise its picrate (m 191o) from EtOH; then the free base is liberated with aqueous alkali, dried at 78o/8mm over P2O5 and crystallised from pet ether (b 80-100o). [Cumper et al. J Chem Soc 1188 1962.] It can be purified by zone melting. It has also been crystallised from hexane, *benzene/pet ether (b 40-60o) or sodium-dried *benzene, dried and stored over H2SO4. The monohydrate is obtained by crystallisation from aqueous EtOH or ethyl acetate. It has been crystallised from H2O (300 parts) to give the monohydrate m 102-103o which sublimes at 10-3mm [Fielding & LeFevre J Chem Soc 1811 1951.] The anhydrous compound has m 118o (after drying at high vacuum at 80o) and is also obtained by recrystallisation from pet ether or *C6H6 (70 parts) and drying at 78o/8mm. [UV: Badger et al. J Chem Soc 3199 1951.] IthasapKainH2Oof 4.857 (25o) or 5.02 (20o) and 4.27 in 50% aqueous EtOH (20o). [Albert et al. J Chem Soc 2240 1948]. [Beilstein 23 H 227, 23 II 235, 23/8 V 419.]

1,10-Phenanthroline hydrate Preparation Products And Raw materials

Raw materials

Preparation Products

1 10-PHENANTHROLINE-5 6-DIONE 97 4-Vinylcyclohexene dioxide 2,9-Dichloro-1,10-phenanthroline N,N'-TRIMETHYLENE-1,10-*PHENANTHROLINIUM DIBROMIDE

1,10-Phenanthroline hydrate Suppliers

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DeFINE CHEMICALS	+91-8010769889 +91-9320057099	Maharashtra, India	120	58	Inquiry
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Central Drug House(P) Ltd.	91-11-49404040	New Delhi, India	6160	58	Inquiry
LOBA CHEMIE PVT.LTD.	91-22-6663 6699	Mumbai, India	3077	58	Inquiry

Supplier	Advantage
DeFINE CHEMICALS	58
JSK Chemicals	58
CHEMSWORTH	30
CLEARSYNTH LABS LTD.	58
A.J Chemicals	58
TCI Chemicals (India) Pvt. Ltd.	58
Otto Chemie Pvt. Ltd.	58
Alfa Aesar	58
Central Drug House(P) Ltd.	58
LOBA CHEMIE PVT.LTD.	58

The chemical properties of 1,10-Phenanthroline hydrate
1,10-Phenanthroline hydrate is well known as a bidentate ligand in coordination chemistry.
Sep 5，2022

1,10-Phenanthroline hydrate Spectrum

1,10-Phenanthroline hydrate(5144-89-8)IR

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1,10-PHENANTHROLINE MONOHYDRATE (O-) ORTHOPHENANTHROLINE MONOHYDRATE O-PHENANTHROLINE HYDRATE 1,10-phenanthrollne,monohydrate 4,5-Phenanthrolinemonohydrate 1 10-PHENANTHROLINE MONOHYDRATE 99% & 1,10-PHENANTHROLINE MONOHYDRATE*ACS REAG ENT 1,10-PHENANTHROLINE MONOHYDRATE, 99%, A. C.S. REAGENT 1,10-Phenanthroline(Monohydrate)Gr 1,10-PhenanthrolineGrMonohydrate-RedoxIndicator 1,10-PhenanthrolineGrMonohydrate 1,10-PHENANTHROLINE MONOHYDRATE, 99+% Black bone vine extract HISTOLOGICAL FIXATIVE A.F.A. HISTONORM 1,10-Phenanthroline monohydrate ACS reagent, puriss. p.a., >=99.5% (calc. to the dried substance), for redox titration 1,10-Phenanthroline monohydrate Vetec(TM) reagent grade 1,10-PHENANTHROLINE 1H2O Phenanthroline analytical grade EGG YOLK (6X100ML)+TELLUR.(6X) Y-IRR. 1,10-Phenanthroline monohydrate, reagent ACS 1,10-Phenanthrolinemonhydrate 1,10-Phenanthroline monohydrate, ACS 1,10-PHENANTHROLINE MONOHYDRATE extrapure AR 1,10-Phenanthroline, Monohydrate, Reagent 1,10-Phenanthroline Monohydrate [for Biochemical Research] 1,10-PHENANTHROLINE AR 1,10-PHENANTHROLINE AR (H2O) 1,10-phenanthrolinemonorate 1,10-Phenanthroline hydrate,99+% 1,10-Phenanthroline Monohydrate,98% o-Phenanthroline monohydrate, redox indicator, reagent grade, ACS 1,10-Phenanthroline monohydrate p.a. o-Phenanthroline Monohydrate, GR ACS 1,10-Phenanthroline 1,10-Phenanthroline Monohydrate, 99+% 25GR 1,10-Phenanthroline Monohydrate, 99+% 5GR glaucescent fissistigma root P.E. 1,10-Phenanthroline monohydrate≥ 99.5% (Titration) 1,10-PHENANTHROLINE HYDRATE 1,10-PhenanthrolineMonohydrate[forBiochemicalResearch]> 1,10-Phenanthroline monohydrate, 98%, for analysis 1,10-Phenanthroline monohydrate, 99%, for bio 1,10-Phenanthroline monohydrate, 99%, reagent grade 1,10-PhenanthrolineMonohydrate> 1,10-Phenanthroline monohydrat,≥98% 1,10-Phenanthroline hydrate USP/EP/BP 1,10-Phenanthroline 1-hydrate 1,10-Phenanthroline monohydrate, indicator, AR reagent 1,10-Phenanthroline monohydrate AR 99% 1,10-Phenanthroline, GR 99%+ 5144-89-8 1,10-Phenanthroline hydrate 1,10-Phenanthroline Monohydrate extrapure AR, 99.5% 1,10-Phenanthroline Monohydrate extrapure AR, ACS, ExiPlus, Multi-Compendial, 99.5% 1,10 PHENANTHROLINE MONOHYDRATE AR/ACS 1,10- phenanthroline ferrous indicator O-phenanthroline indicator solution 1,10-Phenanthroline hydrate solution 1,10-Phenanthroline monohydrate, 99%, indicator, ACS reagent