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4-Vinylcyclohexene dioxide

4-Vinylcyclohexene dioxide Structure
CAS No.
106-87-6
Chemical Name:
4-Vinylcyclohexene dioxide
Synonyms
VCD;VCHD;ep-206;ERL 4206;erla-2270;erla-2271;nci-c60135;nci-c60139;ERL(R) 4206;chissonox206
CBNumber:
CB4213606
Molecular Formula:
C8H12O2
Molecular Weight:
140.18
MOL File:
106-87-6.mol
MSDS File:
SDS
Modify Date:
2023/9/6 17:45:48

4-Vinylcyclohexene dioxide Properties

Melting point -55°C
Boiling point 230-232 °C(lit.)
Density 1.094 g/mL at 25 °C(lit.)
refractive index n20/D 1.477(lit.)
Flash point 225 °F
storage temp. under inert gas (nitrogen or Argon) at 2-8°C
form Colorless or pale yellow liquid
Water Solubility 154.7g/L(20 ºC)
BRN 106071
Stability Stable. Combustible. Incompatible with strong oxidizing agents, alcohols, amines and other compounds containg an active hydrogen. Hydrolyzes slowly in water.
CAS DataBase Reference 106-87-6(CAS DataBase Reference)
IARC 2B (Vol. Sup 7, 60) 1994
EPA Substance Registry System 4-Vinylcyclohexene diepoxide (106-87-6)

SAFETY

Risk and Safety Statements

Symbol(GHS) 
GHS06,GHS08
Signal word  Danger
Hazard statements  H301+H311+H331-H351
Precautionary statements  P201-P280-P301+P310+P330-P302+P352+P312-P304+P340+P311
Hazard Codes  T
Risk Statements  23/24/25-68/20/21/22-68
Safety Statements  23-24-45
RIDADR  UN 2810 6.1/PG 3
OEB A
OEL TWA: 10 ppm (60 mg/m3) [skin]
WGK Germany  1
RTECS  RN8640000
HazardClass  6.1(b)
PackingGroup  III

4-Vinylcyclohexene dioxide price More Price(2)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich(India) 94956 Vinylcyclohexene dioxide purum, suitable for electron microscopy, mixture of isomers, ≥96.0% (GC) 106-87-6 100ML ₹22158.78 2022-06-14 Buy
Sigma-Aldrich(India) 94956 Vinylcyclohexene dioxide purum, suitable for electron microscopy, mixture of isomers, ≥96.0% (GC) 106-87-6 250ML ₹51808.45 2022-06-14 Buy
Product number Packaging Price Buy
94956 100ML ₹22158.78 Buy
94956 250ML ₹51808.45 Buy

4-Vinylcyclohexene dioxide Chemical Properties,Uses,Production

Chemical Properties

colourless liquid. Combustible.

Uses

Vinylcyclohexene dioxide (VCD) is used to study toxicity as an ovotoxin,and it's also used to understand its mechanisms of toxicity towards ovarian follicles and effects on epithelial differentiation.

Production Methods

VCHD is manufactured by epoxidation of 4-vinylcyclohexene with peroxyacetic acid .

Definition

ChEBI: The diepoxide of 4-vinylcyclohexene.

General Description

Clear colorless liquid. Sets to glass at -67°F. Faint olefinic odor.

Air & Water Reactions

Water soluble. Hydrolyzes slowly in water.

Reactivity Profile

4-VINYLCYCLOHEXENE DIOXIDE reacts with active hydrogen compounds (such as alcohols and amines). . Epoxides are highly reactive. They polymerize in the presence of catalysts or when heated. These polymerization reactions can be violent. Compounds in this group react with acids, bases, and oxidizing and reducing agents. They react, possibly violently with water in the presence of acid and other catalysts.

Hazard

Toxic by ingestion and skin absorption, strong irritant to skin and tissue. Female and male reproductive damage. Possible carcinogen.

Health Hazard

Vinyl cyclohexene dioxide (VCD) is an irritant to the skin, eyes, and respiratory system. It is ovotoxic and carcinogenic in experimental animals.

Safety Profile

Confirmed carcinogen with experimental carcinogenic and tumorigenic data. Poison by unspecified route. Moderately toxic by ingestion and skin contact. Mildly toxic by inhalation. Experimental reproductive effects. Mutation data reported. A severe skin irritant.Combustible when exposed to heat or flame. To fight fire, use water, foam, dry chemical. When heated to decomposition it emits acrid smoke and irritating fumes.

Potential Exposure

This material is used as a monomer in the production of epoxy resins for coatings and adhesives; as a chemical intermediate and as a reactive diluent.

Carcinogenicity

4-Vinyl-1-cyclohexene diepoxide is reasonably anticipated to be a human carcinogen based on sufficient evidence of carcinogenicity fromstudies in experimental animals.

Shipping

UN2810 Toxic liquids, organic, n.o.s., Hazard Class: 6.1; Labels: 6.1-Poisonous materials, Technical Name Required.

Incompatibilities

When heated or in contact with catalysts, epoxides may cause violent polymerization. Epoxides are incompatible with reducing agents and oxidizers (chlorates, nitrates, peroxides, permanganates, perchlorates, chlorine, bromine, fluorine, etc.); contact may cause fires or explosions. Keep away from alkaline materials, strong bases, strong acids, oxoacids, epoxides. May react, possibly violently, with water in the presence of acid and other catalysts. Reacts with alcohols, amines and other active hydrogen compounds. Slowly hydrolyzes in water.

Waste Disposal

Concentrated waste containing no peroxides: discharge liquid at a controlled rate near a pilot flame. Concentrated waste containing peroxides: perforation of a container of the waste from a safe distance followed by open burning.

Global( 158)Suppliers
Supplier Tel Country ProdList Advantage Inquiry
CLEARSYNTH LABS LTD. +91-22-45045900 Hyderabad, India 6351 58 Inquiry
Hebei Yanxi Chemical Co., Ltd. +86-17531190177; +8617531190177 China 6011 58 Inquiry
Shanghai Daken Advanced Materials Co.,Ltd +86-371-66670886 China 16209 58 Inquiry
Henan Tianfu Chemical Co.,Ltd. +86-0371-55170693 +86-19937530512 China 21675 55 Inquiry
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BEYOND INDUSTRIES (CHINA) LIMITED +86-21-52699951; +8613917686115 China 699 58 Inquiry
Fuxin Pharmaceutical +86-021-021-50872116 +8613122107989 China 10297 58 Inquiry
Neostar United (Changzhou) Industrial Co., Ltd. +86-519-519-85557386 China 12330 58 Inquiry
ERL(R) 4206 ERL 4206 4-VINYLCYCLOHEXENE DIOXIDE 4-VINYL-1-CYCLOHEXENE DIEPOXIDE 4-VINYL-1-CYCLOHEXENE DIOXIDE 3-EPOXYETHYL-7-OXABICYCLO [4.1.0] HEPTANE VINYL-4-CYCLOHEXENE DIOXIDE VINYLCYCLOHEXENE DIOXIDE VCHD 1,0]heptane,3-oxiranyl-7-Oxabicyclo[4 1,2-epoxy-4-(epoxyethyl)cyclohexane 1-ethyleneoxy-3,4-epoxycyclohexane 1-vinyl-3-cyclohexenedioxide 3-(1,2-epoxyethyl)-7-oxabicyclo(4.1.0)heptane unoxepoxide206 vinylcyclohexanediepoxide vinylcyclohexanedioxide vinylcyclohexenediepoxide 4-VINYLCYCLOHEXENE DIOXIDE MIXTURE OF & VINYLCYCLOHEXENE DIOXIDE, MIXTURE OF ISOMERS 3-EPOXYETHYL-7-OXABICYCLO[4.1]HEPTANE 99% VINYLCYCLOHEXENE-7,8-EPOXIDE 4-VINYLCYCLOHEXENE DIOXIDE 99% 1,2-epoxy-4-epoxyethylcyclohexane vinylcyclohexane diepoxide 1,2-Epoxy-4-epoxyethylcyclohexane, 3-Epoxyethyl-7-oxabicyclo[4.1.0]heptane 7-oxa-3-oxiranylbicyclo[4.1.0]heptane 1,2-epoxy-2-(epoxyethyl)cyclohexane 3-(Oxiran-2-yl)-7-oxabicyclo[4.1.0]heptane Vinylcyclohexene dioxide ,96% Vinylcyclohexene dioxide,>=96.0% (GC),mixture of iso mers 1-EPOXYETHYL-3.4-EPOXYCYCLOHEXANE 3-(epoxyethyl)-7-oxabicyclo(4.1.0)heptan 3-epoxyethyl-7-oxabicycloheptane 3-oxiranyl-7-oxabicyclo(4.1.0)heptan 3-oxiranyl-7-oxabicyclo(4.1.0)heptane 3-oxiranyl-7-oxabicyclo(4.1.0)heptene 3-oxiranyl-7-oxabicyclo[4.1.0]heptan Vinylcyclohexene dioxid 4-(1,2-epoxyethyl)-7-oxabicyclo(4.1.0)heptane 4-(epoxyethyl)-7-oxabicyclo(4.1.0)heptane 4-vinlycyclohexenedioxide 4-vinyl-1,2-cyclohexenediepoxide 4-vinylcyclohexenediepoxide 7-oxabicyclo[4.1.0]heptane,3-oxiranyl- chissonox206 cyclohexane,1,2-epoxy-4(epoxyethyl) ep-206 erla-2270 erla-2271 nci-c60135 nci-c60139 ucettextilefinish11-74(obs.) 7-Oxabicyclo[4.1.0]heptane,3-(2-oxiranyl)- VINYLCYCLOHEXENE DIOXIDE, MIXTURE OF 4-Vinylcyclohexene dioxide in stock Factory 1-Epoxyethyl-3,4-epoxy-cyclohexan Vinylcyclohexene dioxide purum, for electron microscopy, mixture of isomers, >=96.0% (GC) VCD