Cuprous oxide
- CAS No.
- 1317-39-1
- Chemical Name:
- Cuprous oxide
- Synonyms
- COPPER OXIDE;COPPER(I) OXIDE;Cupper oxide;dicopper oxide;Copper oxide (Cu2O);Copox;Cu2-O;Cuprox;Nordox;Perecot
- CBNumber:
- CB9853041
- Molecular Formula:
- Cu2O
- Molecular Weight:
- 143.09
- MOL File:
- 1317-39-1.mol
- MSDS File:
- SDS
- Modify Date:
- 2024/7/17 16:57:19
| Melting point | 1232 °C |
|---|---|
| Boiling point | 1800 °C |
| Density | 6 g/mL at 25 °C (lit.) |
| refractive index | 2.705 |
| Flash point | 1800°C |
| storage temp. | Inert atmosphere,Room Temperature |
| solubility | insoluble in H2O |
| form | powder |
| color | red |
| Specific Gravity | 6. |
| Water Solubility | practically insoluble |
| Sensitive | Air & Moisture Sensitive |
| Merck | 14,2664 |
| Exposure limits |
ACGIH: TWA 1 mg/m3 NIOSH: IDLH 100 mg/m3; TWA 1 mg/m3 |
| Dielectric constant | 18.1（Ambient） |
| Stability | Stable. May be air or light sensitive. |
| CAS DataBase Reference | 1317-39-1(CAS DataBase Reference) |
| NIST Chemistry Reference | Copper(i) oxide(1317-39-1) |
| EPA Substance Registry System | Cuprous oxide (1317-39-1) |
SAFETY
Risk and Safety Statements
| Symbol(GHS) |    GHS02,GHS07,GHS09 |
|||||||||
|---|---|---|---|---|---|---|---|---|---|---|
| Signal word | Danger | |||||||||
| Hazard statements | H225-H319-H410 | |||||||||
| Precautionary statements | P210-P233-P240-P241-P273-P305+P351+P338 | |||||||||
| Hazard Codes | Xn,N,F | |||||||||
| Risk Statements | 22-50/53-51/53-11 | |||||||||
| Safety Statements | 22-60-61-16-7 | |||||||||
| RIDADR | UN 3077 9/PG 3 | |||||||||
| WGK Germany | 3 | |||||||||
| RTECS | GL8050000 | |||||||||
| TSCA | Yes | |||||||||
| HazardClass | 9 | |||||||||
| PackingGroup | III | |||||||||
| HS Code | 28255000 | |||||||||
| Toxicity | LD50 orally in rats: 0.47 g/kg (Smyth) | |||||||||
| NFPA 704 |
|
Cuprous oxide price More Price(24)
| Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
|---|---|---|---|---|---|---|---|
| Sigma-Aldrich(India) | 566284 | Copper(I) oxide ≥99.99% trace metals basis, anhydrous | 1317-39-1 | 5G | ₹4849.6 | 2022-06-14 | Buy |
| Sigma-Aldrich(India) | 678945 | Copper(I) oxide nanospheres, dispersion, <350?nm particle size, 1.5?% (w/v) in ethanol | 1317-39-1 | 25ML | ₹26240.9 | 2022-06-14 | Buy |
| Sigma-Aldrich(India) | 566284 | Copper(I) oxide ≥99.99% trace metals basis, anhydrous | 1317-39-1 | 25G | ₹15869.45 | 2022-06-14 | Buy |
| Sigma-Aldrich(India) | 208825 | Copper(I) oxide powder, ≤7?μm, 97% | 1317-39-1 | 25G | ₹3236.68 | 2022-06-14 | Buy |
| Sigma-Aldrich(India) | 208825 | Copper(I) oxide powder, ≤7?μm, 97% | 1317-39-1 | 500G | ₹4481.55 | 2022-06-14 | Buy |
Cuprous oxide Chemical Properties,Uses,Production
Chemical Properties
Copper(I) oxide, Cu2O, occurs in nature as the red or reddish brown mineral cuprite in a cubic or octahedral crystalline morphology. Synthetic materials variously appear as yellow (somewhat pyrophoric), orange, red, or purple powders, depending on particle size. Copper(I) oxide is stable in dry air, but slowly oxidizes to copper(II) oxide, [1317-38-0], in moist air. It is virtually insoluble in water but dissolves in complexing acids such as HCl and in aqueous ammonia to form copper(I) complexes. In dilute sulfuric and nitric acids, disproportionation to the soluble copper(II) salts and copper powder obtains.
Uses
Fungicide; antiseptic for fishnets; in antifouling paints for marine use; in photoelectric cells; as red pigment for glass, ceramic glazes; in brazing pastes; in rectifiers; as catalyst.
Preparation
Copper(I) oxide decomposes above 1800°C but can be prepared by heating copper metal in air above 1030°C. To prevent further oxidation, the material must be cooled in an inert atmosphere. Lower temperatures may be used to produce the oxide if the material is blended with a reducing agent such as carbon and heated to 750°C in an inert atmosphere. The product must be stabilized with isophthalic acid or pine oil (Ayers, 1953). A particularly stable copper(I) oxide can be prepared by blending copper powder and cupric oxide in stoichiometric amounts and heating to 800-900°C. Lower temperatures can be used if ammonia or certain ammonium salts are added to the blend (Day, 1969; Drapeau and Johnson, 1956; Drapeau and Johnson, 1959).
Definition
For the native ore see cuprite.
General Description
Copper(I) oxide is a weak inorganic base that can be used to activate halides for nucleophilic substitution reaction. It is also used in decarboxylation and cyclo condensation reactions.
Hazard
Toxic by ingestion.
Safety Profile
Moderately toxic by ingestion. Experimental reproductive effects. A fungicide. Violent, potentially explosive reaction with concentrated peroxyformic acid. Violent reaction when heated with aluminum. See also COPPER COMPOUNDS.
Cuprous oxide Preparation Products And Raw materials
Raw materials
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chevron_right| Supplier | Tel | Country | ProdList | Advantage | Inquiry |
|---|---|---|---|---|---|
| Yogi Dye Chem Industries | +91-9821098577 +91-9821098577 | Mumbai, India | 124 | 58 | Inquiry |
| Parikh Enterprises Pvt Ltd | +91-7922871471 +91-9925000571 | Gujarat, India | 10 | 58 | Inquiry |
| Perry Chem | +91-9898110710 +91-9374177467 | Gujarat, India | 3 | 58 | Inquiry |
| Hemal Impex | +91-2646220650 +91-9824111508 | Maharashtra, India | 14 | 58 | Inquiry |
| Eastmen Chemicals | +91-2228727766 +91-2228730294 | Maharashtra, India | 19 | 58 | Inquiry |
| The Metal Powder Company Limited | +91-4549280595 +91-4549280599 | Tamil Nadu, India | 16 | 58 | Inquiry |
| Otto Chemie Pvt. Ltd. | +91 9820041841 | Mumbai, India | 5873 | 58 | Inquiry |
| Alfa Aesar | 1 800 209 7001 | Maharashtra, India | 6913 | 58 | Inquiry |
| Sisco Research Laboratories Pvt. Ltd. | +91-22-4268 5800 | Mumbai, India | 4317 | 58 | Inquiry |
| Vishnupriya Chemicals Private Limited | +91-8046041737 | Telangana, India | 220 | 58 | Inquiry |
| Supplier | Advantage |
|---|---|
| Yogi Dye Chem Industries | 58 |
| Parikh Enterprises Pvt Ltd | 58 |
| Perry Chem | 58 |
| Hemal Impex | 58 |
| Eastmen Chemicals | 58 |
| The Metal Powder Company Limited | 58 |
| Otto Chemie Pvt. Ltd. | 58 |
| Alfa Aesar | 58 |
| Sisco Research Laboratories Pvt. Ltd. | 58 |
| Vishnupriya Chemicals Private Limited | 58 |
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