4-Formylmorpholine
- CAS No.
- 4394-85-8
- Chemical Name:
- 4-Formylmorpholine
- Synonyms
- 4-FORMYLMORPHOLINE;4-Morpholinecarbaldehyde;Formmorpholime;N-Formylmorphol;N-Formylmorfolin;N-Formyl Morpholin;N-FORMYLMORPHOLINE;TIMTEC-BB SBB007670;Morpholine, 4-formyl-;4-Formylmorpholine>
- CBNumber:
- CB8684608
- Molecular Formula:
- C5H9NO2
- Molecular Weight:
- 115.13
- MOL File:
- 4394-85-8.mol
- MSDS File:
- SDS
- Modify Date:
- 2024/8/21 22:41:43
| Melting point | 20-23 °C (lit.) |
|---|---|
| Boiling point | 236-237 °C (lit.) |
| Density | 1.145 g/mL at 25 °C (lit.) |
| vapor pressure | 0.03 hPa (20 °C) |
| refractive index |
n |
| Flash point | >230 °F |
| storage temp. | Store below +30°C. |
| solubility | SOLUBLE |
| pka | -0.75±0.20(Predicted) |
| form | Liquid |
| color | Clear yellow |
| PH | 10 (250g/l, H2O, 20℃) |
| explosive limit | 1.2-8.2%(V) |
| Water Solubility | SOLUBLE |
| Sensitive | Hygroscopic |
| BRN | 110293 |
| LogP | -1.2 at 23℃ |
| CAS DataBase Reference | 4394-85-8(CAS DataBase Reference) |
| NIST Chemistry Reference | N-Formylmorpholine(4394-85-8) |
| EPA Substance Registry System | 4-Morpholinecarboxaldehyde (4394-85-8) |
SAFETY
Risk and Safety Statements
| Symbol(GHS) |  GHS07 |
|||||||||
|---|---|---|---|---|---|---|---|---|---|---|
| Signal word | Warning | |||||||||
| Hazard statements | H317 | |||||||||
| Precautionary statements | P261-P272-P280-P302+P352-P333+P313-P362+P364 | |||||||||
| Risk Statements | 36/37/38 | |||||||||
| Safety Statements | 23-24/25 | |||||||||
| WGK Germany | 3 | |||||||||
| RTECS | QD9694000 | |||||||||
| Autoignition Temperature | 345 °C DIN 51794 | |||||||||
| TSCA | Yes | |||||||||
| HS Code | 29349990 | |||||||||
| Toxicity | LD50 orally in Rabbit: > 7360 mg/kg LD50 dermal Rabbit > 18400 mg/kg | |||||||||
| NFPA 704 |
|
4-Formylmorpholine price More Price(6)
| Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
|---|---|---|---|---|---|---|---|
| Sigma-Aldrich | 250376 | 4-Formylmorpholine 99% | 4394-85-8 | 100G | ₹2305.73 | 2022-06-14 | Buy |
| Sigma-Aldrich(India) | 250376 | 4-Formylmorpholine 99% | 4394-85-8 | 100G | ₹2305.73 | 2022-06-14 | Buy |
| Sigma-Aldrich | 250376 | 4-Formylmorpholine 99% | 4394-85-8 | 500G | ₹7285.23 | 2022-06-14 | Buy |
| Sigma-Aldrich(India) | 250376 | 4-Formylmorpholine 99% | 4394-85-8 | 500G | ₹7285.23 | 2022-06-14 | Buy |
| TCI Chemicals (India) | F0157 | 4-Formylmorpholine min. 99.0 % | 4394-85-8 | 25G | ₹2000 | 2022-05-26 | Buy |
4-Formylmorpholine Chemical Properties,Uses,Production
Description
4-Formylmorpholine is an excellent non-protonic solvent. It is widely used as a solvent and extractant for aromatics. It is used as a detergent for acid gases. In the field of organic synthesis, it can be used to prepare labelled 14C, 4-(trifluoromethyl)morpholine, 3-alkyl-2-chloro-5,6-dihydrobenzaldehyde, triple-biphenyldialdehyde and phenylpropargyl aldehyde. It plays an important role in the desulphurisation of natural gas, syngas, flue gas and petrol.
Chemical Properties
CLEAR YELLOW LIQUID
N-formylmorpholine is a colourless transparent liquid soluble in water. It is chemically stable, non-toxic, and non-corrosive but can also dissolve aliphatic hydrocarbons, aromatic hydrocarbons, and water because of its unique structure. N-formylmorpholine would largely reduce the volatility of aromatic hydrocarbon when dissolving the latter. Thus, it can extract, distill and recycle aromatic hydrocarbon. Besides, this compound is also applied in C4 (LNG) cracking projects for desulfuration and solvent extraction, which can increase the yield (relative to DMF, ACN, and NMP processes). At present, this application has been adopted in China. It should be stored in sealed containers in a cool, ventilated warehouse. Keep away from fire and heat. Avoid the use of mechanical equipment that would produce sparks. Handle gently, avoiding damage to the packaging and containers.
Uses
4-Formylmorpholine is widely used as a solvent and extracting agent for aromatics. It is used as a scrubbing agent for acidic gases. It is employed in the preparation of adenine hydrochloride labeled with 14C, 4-(trifluoromethyl)morpholine, 3-alkyl-2-chloro-5,6-dihydrobenzaldehyde and terphenyl dialdehyde. It plays an important role in the desulfurization of natural gas, synthetic gas, flue gas and gasoline.
General Description
Treatment of 4-formylmorpholine with sulphur tetrafluoride in the presence of potassium fluoride gives 4-(trifluoromethyl)morpholine in excellent yields. 4-Formylmorpholine reacts with series of 2-alkyl-2-cyclohexen-1-ones in the presence of POCl3 to give the corresponding 3-alkyl-2-chloro-5,6-dihydrobenzaldehydes and allylic alcohols (by-product).
4-Formylmorpholine Preparation Products And Raw materials
Raw materials
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chevron_rightPreparation Products
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chevron_right| Supplier | Tel | Country | ProdList | Advantage | Inquiry |
|---|---|---|---|---|---|
| AMINES AND PLASTICIZERS LTD. | +91-22-24935282 +91-9167680626 | Mumbai, India | 26 | 58 | Inquiry |
| Indo Amines Ltd | +91-7045592702 +91-7045592702 | Mumbai, India | 42 | 58 | Inquiry |
| JSK Chemicals | +919879767970 | Gujarat, India | 3756 | 58 | Inquiry |
| SPD CHEMICALS | +91-7075800742 +91-7075800742 | Hyderabad, India | 214 | 58 | Inquiry |
| VDL ORGANICS PVT LTD | +91-9246335727 +91-8328068806 | Telangana, India | 50 | 58 | Inquiry |
| ALS INDIA LIFE SCIENCES | +91-8977036379 +91-8977036379 | Hyderabad, India | 1879 | 58 | Inquiry |
| Amines & Plasticizers Limited | 08048372484Ext 604 | Mumbai, India | 18 | 58 | Inquiry |
| OCEAN TRADING CORPORATION | +91(22) 24921669 | New Delhi, India | 6211 | 58 | Inquiry |
| CHEMSWORTH | +91-261-2397244 | New Delhi, India | 6707 | 30 | Inquiry |
| A.J Chemicals | 91-9810153283 | New Delhi, India | 6124 | 58 | Inquiry |
| Supplier | Advantage |
|---|---|
| AMINES AND PLASTICIZERS LTD. | 58 |
| Indo Amines Ltd | 58 |
| JSK Chemicals | 58 |
| SPD CHEMICALS | 58 |
| VDL ORGANICS PVT LTD | 58 |
| ALS INDIA LIFE SCIENCES | 58 |
| Amines & Plasticizers Limited | 58 |
| OCEAN TRADING CORPORATION | 58 |
| CHEMSWORTH | 30 |
| A.J Chemicals | 58 |