2-Amino-4-methylbenzothiazole

2-Amino-4-methylbenzothiazole Structure
CAS No.
1477-42-5
Chemical Name:
2-Amino-4-methylbenzothiazole
Synonyms
4-METHYLBENZO[D]THIAZOL-2-AMINE;2-Benzothiazolamine, 4-methyl-;AURORA 18742;2-Amino-4-methylbenz;LABOTEST-BB LT00080789;4-methyl-2-benzothiazolamin;4-Methyl-2-benzothiazolamine;4-methyl-2-amimobenzothiazol;4-methyl-2-amimobenzothiagol;4-Methylbenzothiazol-2-amine
CBNumber:
CB8686910
Molecular Formula:
C8H8N2S
Molecular Weight:
164.23
MOL File:
1477-42-5.mol
MSDS File:
SDS
Modify Date:
2023/4/23 13:52:06

2-Amino-4-methylbenzothiazole Properties

Melting point 137-139 °C (lit.)
Boiling point 322.0±35.0 °C(Predicted)
Density 1.1724 (rough estimate)
vapor pressure 0.053Pa at 25℃
refractive index 1.5700 (estimate)
storage temp. Keep in dark place,Sealed in dry,Room Temperature
form Solid:particulate/powder
pka pK1: 4.7(+1) (25°C)
color White to Light yellow
Water Solubility <0.1 g/100 mL at 24 ºC
Sensitive Moisture Sensitive
BRN 129346
LogP 0.981-1.65 at 25℃ and pH7.2
CAS DataBase Reference 1477-42-5(CAS DataBase Reference)
NIST Chemistry Reference 2-Benzothiazolamine, 4-methyl-(1477-42-5)
EPA Substance Registry System 2-Amino-4-methylbenzothiazole (1477-42-5)

SAFETY

Risk and Safety Statements

Symbol(GHS) 
GHS07
Signal word  Warning
Hazard statements  H302
Precautionary statements  P264-P270-P301+P312+P330-P501-P301+P312a-P330-P501a
Hazard Codes  Xn
Risk Statements  22
Safety Statements  26-28-36/37/39-24/25
WGK Germany  3
RTECS  DL2275000
TSCA  Yes
HS Code  29342000
NFPA 704
1
2 1

2-Amino-4-methylbenzothiazole price More Price(2)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich(India) 193224 2-Amino-4-methylbenzothiazole 97% 1477-42-5 25G ₹5044.45 2022-06-14 Buy
TCI Chemicals (India) A1344 2-Amino-4-methylbenzothiazole 1477-42-5 25G ₹6200 2022-05-26 Buy
Product number Packaging Price Buy
193224 25G ₹5044.45 Buy
A1344 25G ₹6200 Buy

2-Amino-4-methylbenzothiazole Chemical Properties,Uses,Production

Chemical Properties

OFF-WHITE TO SLIGHTLY BEIGE CRYSTALLINE POWDER

Uses

2-Amino-4-methylbenzothiazole was used in the synthesis of N-(4-methyl-1,3-benzothiazol-yl)-N-[(1,4,5,8-tetramethoxy-2-napthyl)methylidene]amine and Schiff′s base via condensation with 2-acetonaphthone.

General Description

White powder.

Air & Water Reactions

2-Amino-4-methylbenzothiazole is sensitive to moisture. Insoluble in water.

Reactivity Profile

An amine, organosulfide. Organosulfides are incompatible with acids, diazo and azo compounds, halocarbons, isocyanates, aldehydes, alkali metals, nitrides, hydrides, and other strong reducing agents. Reactions with these materials generate heat and in many cases hydrogen gas. Many of these compounds may liberate hydrogen sulfide upon decomposition or reaction with an acid. Amines are chemical bases. They neutralize acids to form salts plus water. These acid-base reactions are exothermic. The amount of heat that is evolved per mole of amine in a neutralization is largely independent of the strength of the amine as a base. Amines may be incompatible with isocyanates, halogenated organics, peroxides, phenols (acidic), epoxides, anhydrides, and acid halides. Flammable gaseous hydrogen is generated by amines in combination with strong reducing agents, such as hydrides.

Health Hazard

ACUTE/CHRONIC HAZARDS: When heated to decomposition 2-Amino-4-methylbenzothiazole emits very toxic fumes of SOx and NOx.

Fire Hazard

Flash point data for 2-Amino-4-methylbenzothiazole are not available. 2-Amino-4-methylbenzothiazole is probably combustible.

Global( 294)Suppliers
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Bhuvaneshwari Organic Pvt., Ltd. 91-9825023325 Gujarat, India 9 58 Inquiry
2-Amino-4-methylbenz 2-amino-4-methyl-benzothiazol 4-Methyl-2-aminobenzothiazole 4-methyl-2-benzothiazolamin 4-Methyl-2-benzothiazolamine Benzothiazole, 2-amino-4-methyl- AURORA 18742 LABOTEST-BB LT00080789 4-METHYL-1,3-BENZOTHIAZOL-2-AMINE 4-methylbenzothiazol-2-ylamine 2-AMINO-4-METHYLBENZOTHIAZOLE 2-Benzothiazolamine,4-methyl-(9CI) 4-methyl-2-amimobenzothiazol 4-methyl-2-amimobenzothiagol 2-Imino-4-methyl-2,3-dihydrobenzothiazole 4-Methylbenzothiazol-2-amine 2-Amino-4-methylbenzothiazole,98% 2-Amino-4-methylbenzothiazole > JR-8891, 2-Amino-4-methylbenzothiazole, 97% 4-Methylbenzothiazol-2-ylamin 4-METHYLBENZO[D]THIAZOL-2-AMINE 2-Benzothiazolamine, 4-methyl- 2-Amino-4-methylbenzothiazole, ≥ 98.0% 1477-42-5 C8H8N2S C8H8NS Thiazoles Building Blocks Heterocyclic Building Blocks Building Blocks Heterocyclic Building Blocks Thiazoles BENZOTHIAZOLE melting point: 137°C-139°C